Vibronic coupling in asymmetric bichromophores: experimental investigation of diphenylmethane-d

Vibrationally and rotationally resolved electronic spectra of diphenylmethane-d5 (DPM-d5) are reported in the isolated-molecule environment of a supersonic expansion. While small, the asymmetry induced by deuteration of one of the aromatic rings is sufficient to cause several important effects that...

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Veröffentlicht in:	The Journal of chemical physics 2014-08, Vol.141 (6), p.064316-064316
Hauptverfasser:	Pillsbury, Nathan R, Kidwell, Nathanael M, Nebgen, Benjamin, Slipchenko, Lyudmila V, Douglass, Kevin O, Cable, John R, Plusquellic, David F, Zwier, Timothy S
Format:	Artikel
Sprache:	eng
Schlagworte:	COUPLING DEUTERATION DIPOLE MOMENTS FLUORESCENCE FLUORESCENCE SPECTROSCOPY HAMILTONIANS HYBRIDIZATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MIXING MOLECULES RESONANCE SPECTRA
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