Adsorption of PTCDA on Si(001) - 2 × 1 surface
Adsorption structures of the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule on the clean Si(001) - 2 × 1 surface were investigated using scanning tunneling microscopy (STM) experiments in conjunction with first principles theoretical calculations. Four dominant adsorption structures w...
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| Veröffentlicht in: | The Journal of chemical physics 2015-03, Vol.142 (10), p.101904-101904 |
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| container_end_page | 101904 |
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| container_issue | 10 |
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| container_title | The Journal of chemical physics |
| container_volume | 142 |
| creator | Suzuki, Takayuki Yoshimoto, Yoshihide Yagyu, Kazuma Tochihara, Hiroshi |
| description | Adsorption structures of the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule on the clean Si(001) - 2 × 1 surface were investigated using scanning tunneling microscopy (STM) experiments in conjunction with first principles theoretical calculations. Four dominant adsorption structures were observed in the STM experiments and their atomic coordinates on the Si(001) surface were determined by comparison between the experimental STM images and the theoretical simulations. Maximizing the number of the Si-O bonds is more crucial than that of the Si-C bonds in the PTCDA adsorption. |
| doi_str_mv | 10.1063/1.4906118 |
| format | Article |
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Four dominant adsorption structures were observed in the STM experiments and their atomic coordinates on the Si(001) surface were determined by comparison between the experimental STM images and the theoretical simulations. Maximizing the number of the Si-O bonds is more crucial than that of the Si-C bonds in the PTCDA adsorption.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.4906118</identifier><identifier>PMID: 25770493</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>ADSORPTION ; ANHYDRIDES ; CARBON ; COMPARATIVE EVALUATIONS ; COMPUTERIZED SIMULATION ; CRYSTAL STRUCTURE ; Dianhydrides ; First principles ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MOLECULES ; PERYLENE ; SCANNING TUNNELING MICROSCOPY ; SILICON ; Surface chemistry ; SURFACES</subject><ispartof>The Journal of chemical physics, 2015-03, Vol.142 (10), p.101904-101904</ispartof><rights>2015 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c322t-7e392ce821bb4f719ae6ff03a6914675a136558853daa3cb42770bf2d98e80c3</citedby><cites>FETCH-LOGICAL-c322t-7e392ce821bb4f719ae6ff03a6914675a136558853daa3cb42770bf2d98e80c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25770493$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/22415474$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Suzuki, Takayuki</creatorcontrib><creatorcontrib>Yoshimoto, Yoshihide</creatorcontrib><creatorcontrib>Yagyu, Kazuma</creatorcontrib><creatorcontrib>Tochihara, Hiroshi</creatorcontrib><title>Adsorption of PTCDA on Si(001) - 2 × 1 surface</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>Adsorption structures of the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule on the clean Si(001) - 2 × 1 surface were investigated using scanning tunneling microscopy (STM) experiments in conjunction with first principles theoretical calculations. Four dominant adsorption structures were observed in the STM experiments and their atomic coordinates on the Si(001) surface were determined by comparison between the experimental STM images and the theoretical simulations. Maximizing the number of the Si-O bonds is more crucial than that of the Si-C bonds in the PTCDA adsorption.</description><subject>ADSORPTION</subject><subject>ANHYDRIDES</subject><subject>CARBON</subject><subject>COMPARATIVE EVALUATIONS</subject><subject>COMPUTERIZED SIMULATION</subject><subject>CRYSTAL STRUCTURE</subject><subject>Dianhydrides</subject><subject>First principles</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MOLECULES</subject><subject>PERYLENE</subject><subject>SCANNING TUNNELING MICROSCOPY</subject><subject>SILICON</subject><subject>Surface chemistry</subject><subject>SURFACES</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpF0M9KAzEQBvAgiq3Vgy8gAS_tYdtMkk02x1L_QkHB3kM2m-CWdlM3uwefxAfyxYy01tPM4cfHzIfQNZApEMFmMOWKCIDiBA2BFCqTQpFTNCSEQqYEEQN0EeOaEAKS8nM0oLmUhCs2RLN5FUO76-rQ4ODx62pxN8dpf6vHSU9whin-_sKAY996Y90lOvNmE93VYY7Q6uF-tXjKli-Pz4v5MrOM0i6TjilqXUGhLLmXoIwT3hNmhAIuZG6AiTwvipxVxjBbcpoOKj2tVOEKYtkI3e5jQ-xqHW3dOftuQ9M422lKOeRc8qTGe7Vrw0fvYqe3dbRuszGNC33UIAQHpbjM_wOPdB36tkkvaAqUJ1MwmtRkr2wbYmyd17u23pr2UwPRv1Vr0Ieqk705JPbl1lVH-dct-wECbnHx</recordid><startdate>20150314</startdate><enddate>20150314</enddate><creator>Suzuki, Takayuki</creator><creator>Yoshimoto, Yoshihide</creator><creator>Yagyu, Kazuma</creator><creator>Tochihara, Hiroshi</creator><general>American Institute of Physics</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20150314</creationdate><title>Adsorption of PTCDA on Si(001) - 2 × 1 surface</title><author>Suzuki, Takayuki ; Yoshimoto, Yoshihide ; Yagyu, Kazuma ; Tochihara, Hiroshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c322t-7e392ce821bb4f719ae6ff03a6914675a136558853daa3cb42770bf2d98e80c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>ADSORPTION</topic><topic>ANHYDRIDES</topic><topic>CARBON</topic><topic>COMPARATIVE EVALUATIONS</topic><topic>COMPUTERIZED SIMULATION</topic><topic>CRYSTAL STRUCTURE</topic><topic>Dianhydrides</topic><topic>First principles</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MOLECULES</topic><topic>PERYLENE</topic><topic>SCANNING TUNNELING MICROSCOPY</topic><topic>SILICON</topic><topic>Surface chemistry</topic><topic>SURFACES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Suzuki, Takayuki</creatorcontrib><creatorcontrib>Yoshimoto, Yoshihide</creatorcontrib><creatorcontrib>Yagyu, Kazuma</creatorcontrib><creatorcontrib>Tochihara, Hiroshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Suzuki, Takayuki</au><au>Yoshimoto, Yoshihide</au><au>Yagyu, Kazuma</au><au>Tochihara, Hiroshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption of PTCDA on Si(001) - 2 × 1 surface</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2015-03-14</date><risdate>2015</risdate><volume>142</volume><issue>10</issue><spage>101904</spage><epage>101904</epage><pages>101904-101904</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>Adsorption structures of the 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) molecule on the clean Si(001) - 2 × 1 surface were investigated using scanning tunneling microscopy (STM) experiments in conjunction with first principles theoretical calculations. Four dominant adsorption structures were observed in the STM experiments and their atomic coordinates on the Si(001) surface were determined by comparison between the experimental STM images and the theoretical simulations. Maximizing the number of the Si-O bonds is more crucial than that of the Si-C bonds in the PTCDA adsorption.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>25770493</pmid><doi>10.1063/1.4906118</doi><tpages>1</tpages></addata></record> |
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| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 2015-03, Vol.142 (10), p.101904-101904 |
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| language | eng |
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| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | ADSORPTION ANHYDRIDES CARBON COMPARATIVE EVALUATIONS COMPUTERIZED SIMULATION CRYSTAL STRUCTURE Dianhydrides First principles INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MOLECULES PERYLENE SCANNING TUNNELING MICROSCOPY SILICON Surface chemistry SURFACES |
| title | Adsorption of PTCDA on Si(001) - 2 × 1 surface |
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