The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests

We report the growth of multi-walled carbon nanotube forests employing an active-active bimetallic Fe-Co catalyst. Using this catalyst system, we observe a synergistic effect by which—in comparison to pure Fe or Co—the height of the forests increases significantly. The homogeneity in the as-grown na...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of applied physics 2015-01, Vol.117 (4)
Hauptverfasser: Hardeman, D., Esconjauregui, S., Cartwright, R., Bhardwaj, S., D'Arsié, L., Oakes, D., Clark, J., Cepek, C., Ducati, C., Robertson, J.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue 4
container_start_page
container_title Journal of applied physics
container_volume 117
creator Hardeman, D.
Esconjauregui, S.
Cartwright, R.
Bhardwaj, S.
D'Arsié, L.
Oakes, D.
Clark, J.
Cepek, C.
Ducati, C.
Robertson, J.
description We report the growth of multi-walled carbon nanotube forests employing an active-active bimetallic Fe-Co catalyst. Using this catalyst system, we observe a synergistic effect by which—in comparison to pure Fe or Co—the height of the forests increases significantly. The homogeneity in the as-grown nanotubes is also improved. By both energy dispersive spectroscopy and in-situ x-ray photoelectron spectroscopy, we show that the catalyst particles consist of Fe and Co, and this dramatically increases the growth rate of the tubes. Bimetallic catalysts are thus potentially useful for synthesising nanotube forests more efficiently.
doi_str_mv 10.1063/1.4906846
format Article
fullrecord <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_22413002</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2124936707</sourcerecordid><originalsourceid>FETCH-LOGICAL-c285t-fe39bbfa9dd08aaae6ac32e433c9c36bce230087ab49ccec1453fee240fbbba3</originalsourceid><addsrcrecordid>eNpFkEtLQzEQhYMoWKsL_0HAlYtb87qPLOViVSi46T4k6aT3ljapSYr035vagqsZON8ZzhyEHimZUdLwFzoTkjSdaK7QhJJOVm1dk2s0IYTRqpOtvEV3KW0IobTjcoKG5QA4HT3E9ZjyaDE4Bzbj0eNclDlUfcBm3EHW222RrS7LMeXiSRl22IX4B65j-MkDDq4Q0QSPvfYhHwycCEg53aMbp7cJHi5zipbzt2X_US2-3j_710VlWVfnygGXxjgtVyvSaa2h0ZYzEJxbaXljLDBOSNdqI6S1YKmouQNggjhjjOZT9HQ-G8o3Ktkxgx1s8L48pRgTtLjZP7WP4ftQ4qlNOERfcilGmZC8aUlbqOczZWNIKYJT-zjudDwqStSpbUXVpW3-CzGMcuo</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2124936707</pqid></control><display><type>article</type><title>The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Hardeman, D. ; Esconjauregui, S. ; Cartwright, R. ; Bhardwaj, S. ; D'Arsié, L. ; Oakes, D. ; Clark, J. ; Cepek, C. ; Ducati, C. ; Robertson, J.</creator><creatorcontrib>Hardeman, D. ; Esconjauregui, S. ; Cartwright, R. ; Bhardwaj, S. ; D'Arsié, L. ; Oakes, D. ; Clark, J. ; Cepek, C. ; Ducati, C. ; Robertson, J.</creatorcontrib><description>We report the growth of multi-walled carbon nanotube forests employing an active-active bimetallic Fe-Co catalyst. Using this catalyst system, we observe a synergistic effect by which—in comparison to pure Fe or Co—the height of the forests increases significantly. The homogeneity in the as-grown nanotubes is also improved. By both energy dispersive spectroscopy and in-situ x-ray photoelectron spectroscopy, we show that the catalyst particles consist of Fe and Co, and this dramatically increases the growth rate of the tubes. Bimetallic catalysts are thus potentially useful for synthesising nanotube forests more efficiently.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.4906846</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Bimetals ; CARBON NANOTUBES ; Catalysis ; CATALYSTS ; COBALT ; COMPARATIVE EVALUATIONS ; CRYSTAL GROWTH ; IRON ; Multi wall carbon nanotubes ; NANOSCIENCE AND NANOTECHNOLOGY ; PARTICLES ; POTENTIALS ; Spectroscopy ; Spectrum analysis ; Synergistic effect ; SYNTHESIS ; Tubes ; X ray spectra ; X-RAY PHOTOELECTRON SPECTROSCOPY</subject><ispartof>Journal of applied physics, 2015-01, Vol.117 (4)</ispartof><rights>2015 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c285t-fe39bbfa9dd08aaae6ac32e433c9c36bce230087ab49ccec1453fee240fbbba3</citedby><cites>FETCH-LOGICAL-c285t-fe39bbfa9dd08aaae6ac32e433c9c36bce230087ab49ccec1453fee240fbbba3</cites><orcidid>0000-0002-0284-3568 ; 0000-0002-9195-7611</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,778,782,883,27907,27908</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22413002$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Hardeman, D.</creatorcontrib><creatorcontrib>Esconjauregui, S.</creatorcontrib><creatorcontrib>Cartwright, R.</creatorcontrib><creatorcontrib>Bhardwaj, S.</creatorcontrib><creatorcontrib>D'Arsié, L.</creatorcontrib><creatorcontrib>Oakes, D.</creatorcontrib><creatorcontrib>Clark, J.</creatorcontrib><creatorcontrib>Cepek, C.</creatorcontrib><creatorcontrib>Ducati, C.</creatorcontrib><creatorcontrib>Robertson, J.</creatorcontrib><title>The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests</title><title>Journal of applied physics</title><description>We report the growth of multi-walled carbon nanotube forests employing an active-active bimetallic Fe-Co catalyst. Using this catalyst system, we observe a synergistic effect by which—in comparison to pure Fe or Co—the height of the forests increases significantly. The homogeneity in the as-grown nanotubes is also improved. By both energy dispersive spectroscopy and in-situ x-ray photoelectron spectroscopy, we show that the catalyst particles consist of Fe and Co, and this dramatically increases the growth rate of the tubes. Bimetallic catalysts are thus potentially useful for synthesising nanotube forests more efficiently.</description><subject>Bimetals</subject><subject>CARBON NANOTUBES</subject><subject>Catalysis</subject><subject>CATALYSTS</subject><subject>COBALT</subject><subject>COMPARATIVE EVALUATIONS</subject><subject>CRYSTAL GROWTH</subject><subject>IRON</subject><subject>Multi wall carbon nanotubes</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>PARTICLES</subject><subject>POTENTIALS</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Synergistic effect</subject><subject>SYNTHESIS</subject><subject>Tubes</subject><subject>X ray spectra</subject><subject>X-RAY PHOTOELECTRON SPECTROSCOPY</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLQzEQhYMoWKsL_0HAlYtb87qPLOViVSi46T4k6aT3ljapSYr035vagqsZON8ZzhyEHimZUdLwFzoTkjSdaK7QhJJOVm1dk2s0IYTRqpOtvEV3KW0IobTjcoKG5QA4HT3E9ZjyaDE4Bzbj0eNclDlUfcBm3EHW222RrS7LMeXiSRl22IX4B65j-MkDDq4Q0QSPvfYhHwycCEg53aMbp7cJHi5zipbzt2X_US2-3j_710VlWVfnygGXxjgtVyvSaa2h0ZYzEJxbaXljLDBOSNdqI6S1YKmouQNggjhjjOZT9HQ-G8o3Ktkxgx1s8L48pRgTtLjZP7WP4ftQ4qlNOERfcilGmZC8aUlbqOczZWNIKYJT-zjudDwqStSpbUXVpW3-CzGMcuo</recordid><startdate>20150128</startdate><enddate>20150128</enddate><creator>Hardeman, D.</creator><creator>Esconjauregui, S.</creator><creator>Cartwright, R.</creator><creator>Bhardwaj, S.</creator><creator>D'Arsié, L.</creator><creator>Oakes, D.</creator><creator>Clark, J.</creator><creator>Cepek, C.</creator><creator>Ducati, C.</creator><creator>Robertson, J.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>OTOTI</scope><orcidid>https://orcid.org/0000-0002-0284-3568</orcidid><orcidid>https://orcid.org/0000-0002-9195-7611</orcidid></search><sort><creationdate>20150128</creationdate><title>The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests</title><author>Hardeman, D. ; Esconjauregui, S. ; Cartwright, R. ; Bhardwaj, S. ; D'Arsié, L. ; Oakes, D. ; Clark, J. ; Cepek, C. ; Ducati, C. ; Robertson, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c285t-fe39bbfa9dd08aaae6ac32e433c9c36bce230087ab49ccec1453fee240fbbba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Bimetals</topic><topic>CARBON NANOTUBES</topic><topic>Catalysis</topic><topic>CATALYSTS</topic><topic>COBALT</topic><topic>COMPARATIVE EVALUATIONS</topic><topic>CRYSTAL GROWTH</topic><topic>IRON</topic><topic>Multi wall carbon nanotubes</topic><topic>NANOSCIENCE AND NANOTECHNOLOGY</topic><topic>PARTICLES</topic><topic>POTENTIALS</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Synergistic effect</topic><topic>SYNTHESIS</topic><topic>Tubes</topic><topic>X ray spectra</topic><topic>X-RAY PHOTOELECTRON SPECTROSCOPY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hardeman, D.</creatorcontrib><creatorcontrib>Esconjauregui, S.</creatorcontrib><creatorcontrib>Cartwright, R.</creatorcontrib><creatorcontrib>Bhardwaj, S.</creatorcontrib><creatorcontrib>D'Arsié, L.</creatorcontrib><creatorcontrib>Oakes, D.</creatorcontrib><creatorcontrib>Clark, J.</creatorcontrib><creatorcontrib>Cepek, C.</creatorcontrib><creatorcontrib>Ducati, C.</creatorcontrib><creatorcontrib>Robertson, J.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hardeman, D.</au><au>Esconjauregui, S.</au><au>Cartwright, R.</au><au>Bhardwaj, S.</au><au>D'Arsié, L.</au><au>Oakes, D.</au><au>Clark, J.</au><au>Cepek, C.</au><au>Ducati, C.</au><au>Robertson, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests</atitle><jtitle>Journal of applied physics</jtitle><date>2015-01-28</date><risdate>2015</risdate><volume>117</volume><issue>4</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>We report the growth of multi-walled carbon nanotube forests employing an active-active bimetallic Fe-Co catalyst. Using this catalyst system, we observe a synergistic effect by which—in comparison to pure Fe or Co—the height of the forests increases significantly. The homogeneity in the as-grown nanotubes is also improved. By both energy dispersive spectroscopy and in-situ x-ray photoelectron spectroscopy, we show that the catalyst particles consist of Fe and Co, and this dramatically increases the growth rate of the tubes. Bimetallic catalysts are thus potentially useful for synthesising nanotube forests more efficiently.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4906846</doi><orcidid>https://orcid.org/0000-0002-0284-3568</orcidid><orcidid>https://orcid.org/0000-0002-9195-7611</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0021-8979
ispartof Journal of applied physics, 2015-01, Vol.117 (4)
issn 0021-8979
1089-7550
language eng
recordid cdi_osti_scitechconnect_22413002
source AIP Journals Complete; Alma/SFX Local Collection
subjects Bimetals
CARBON NANOTUBES
Catalysis
CATALYSTS
COBALT
COMPARATIVE EVALUATIONS
CRYSTAL GROWTH
IRON
Multi wall carbon nanotubes
NANOSCIENCE AND NANOTECHNOLOGY
PARTICLES
POTENTIALS
Spectroscopy
Spectrum analysis
Synergistic effect
SYNTHESIS
Tubes
X ray spectra
X-RAY PHOTOELECTRON SPECTROSCOPY
title The synergistic effect in the Fe-Co bimetallic catalyst system for the growth of carbon nanotube forests
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T20%3A14%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20synergistic%20effect%20in%20the%20Fe-Co%20bimetallic%20catalyst%20system%20for%20the%20growth%20of%20carbon%20nanotube%20forests&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Hardeman,%20D.&rft.date=2015-01-28&rft.volume=117&rft.issue=4&rft.issn=0021-8979&rft.eissn=1089-7550&rft_id=info:doi/10.1063/1.4906846&rft_dat=%3Cproquest_osti_%3E2124936707%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2124936707&rft_id=info:pmid/&rfr_iscdi=true