THE REST-FRAME SUBMILLIMETER SPECTRUM OF HIGH-REDSHIFT, DUSTY, STAR-FORMING GALAXIES

We present the average rest-frame spectrum of high-redshift dusty, star-forming galaxies from 250 to 770 GHz. This spectrum was constructed by stacking Atacama Large Millimeter/submillimeter Array (ALMA) 3 mm spectra of 22 such sources discovered by the South Pole Telescope and spanning z = 2.0-5.7. In addition to multiple bright spectral features of super(12)CO, [CI], and H sub(2)O, we also detect several faint transitions of super(13)CO, HCN, HNC, HCO super(+), and CN, and use the observed line strengths to characterize the typical properties of the interstellar medium of these high-redshift starburst galaxies. We find that the super(13)CO brightness in these objects is comparable to that of the only other z > 2 star-forming galaxy in which super(13)CO has been observed. We show that the emission from the high-critical density molecules HCN, HNC, HCO super(+), and CN is consistent with a warm, dense medium with T sub(kin) ~ 55 K and n sub(H2), [gap] 10 super(5.5) cm super(-3). High molecular hydrogen densities are required to reproduce the observed line ratios, and we demonstrate that alternatives to purely collisional excitation are unlikely to be significant for the bulk of these systems. We quantify the average emission from several species with no individually detected transitions, and find emission from the hydride CH and the linear molecule CCH for the first time at high redshift, indicating that these molecules may be powerful probes of interstellar chemistry in high-redshift systems. These observations represent the first constraints on many molecular species with rest-frame transitions from 0.4 to 1.2 mm in star-forming systems at high redshift, and will be invaluable in making effective use of ALMA in full science operations.