Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy

Impedance Spectroscopy (IS) proves to be a powerful tool for the determination of carrier lifetime and majority carrier mobility in colloidal quantum dot films. We employ IS to determine the carrier lifetime in PbS quantum dot Schottky solar cells with Al and we verify the validity of the technique...

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Veröffentlicht in:Applied physics letters 2014-02, Vol.104 (6)
Hauptverfasser: Rath, Arup K., Lasanta, Tania, Bernechea, Maria, Diedenhofen, Silke L., Konstantatos, Gerasimos
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container_issue 6
container_start_page
container_title Applied physics letters
container_volume 104
creator Rath, Arup K.
Lasanta, Tania
Bernechea, Maria
Diedenhofen, Silke L.
Konstantatos, Gerasimos
description Impedance Spectroscopy (IS) proves to be a powerful tool for the determination of carrier lifetime and majority carrier mobility in colloidal quantum dot films. We employ IS to determine the carrier lifetime in PbS quantum dot Schottky solar cells with Al and we verify the validity of the technique via transient photovoltage. We also present a simple approach based on an RC model that allows the determination of carrier mobility in PbS quantum dot films and we corroborate the results via comparison with space charge limited measurements. In summary, we demonstrate the potential of IS to characterize key-to-photovoltaics optoelectronic properties, carrier lifetime, and mobility, in a facile way.
doi_str_mv 10.1063/1.4865089
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source American Institute of Physics (AIP) Journals; Alma/SFX Local Collection
subjects Applied physics
CARRIER LIFETIME
CARRIER MOBILITY
COLLOIDS
COMPARATIVE EVALUATIONS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Electrons
IMPEDANCE
Impedance spectroscopy
LEAD SULFIDES
Majority carriers
NANOSCIENCE AND NANOTECHNOLOGY
Optoelectronics
Photovoltaic cells
PHOTOVOLTAIC EFFECT
QUANTUM DOTS
SOLAR CELLS
SPACE CHARGE
SPECTROSCOPY
Spectrum analysis
THIN FILMS
Transient photovoltage
TRANSIENTS
title Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy
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