Electron-ion dissociative recombination rate constants relevant to the Titan atmosphere and the Interstellar Medium
Following the arrival of Cassini at Titan in 2004, the Titan atmosphere has been shown to contain large complex polycyclic-aromatic hydrocarbons. Since Cassini has provided a great deal of data, there exists a need for kinetic rate data to help with modeling this atmosphere. One type of kinetic data...
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| Veröffentlicht in: | The Journal of chemical physics 2014-01, Vol.140 (3), p.034311-034311 |
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| container_title | The Journal of chemical physics |
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| creator | Osborne, Jr, David Lawson, Patrick Adams, Nigel |
| description | Following the arrival of Cassini at Titan in 2004, the Titan atmosphere has been shown to contain large complex polycyclic-aromatic hydrocarbons. Since Cassini has provided a great deal of data, there exists a need for kinetic rate data to help with modeling this atmosphere. One type of kinetic data needed is electron-ion dissociative recombination (e-IDR) rate constants. These data are not readily available for larger compounds, such as naphthalene, or oxygen containing compounds, such as 1,4 dioxane or furan. Here, the rate constants for naphthalene, 1,4 dioxane, and furan have been measured and their temperature dependencies are determined when possible, using the University of Georgia's Variable Temperature Flowing Afterglow. The rate constants are compared with those previously published for other compounds; these show trends which illustrate the effects which multi-rings and oxygen heteroatoms substitutions have upon e-IDR rate constants. |
| doi_str_mv | 10.1063/1.4858431 |
| format | Article |
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Since Cassini has provided a great deal of data, there exists a need for kinetic rate data to help with modeling this atmosphere. One type of kinetic data needed is electron-ion dissociative recombination (e-IDR) rate constants. These data are not readily available for larger compounds, such as naphthalene, or oxygen containing compounds, such as 1,4 dioxane or furan. Here, the rate constants for naphthalene, 1,4 dioxane, and furan have been measured and their temperature dependencies are determined when possible, using the University of Georgia's Variable Temperature Flowing Afterglow. 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| ispartof | The Journal of chemical physics, 2014-01, Vol.140 (3), p.034311-034311 |
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| source | AIP Journals Complete; Alma/SFX Local Collection |
| subjects | Atmospheric models Cassini mission DIOXANE FURANS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Interstellar matter Ion recombination NAPHTHALENE OXYGEN POLYCYCLIC AROMATIC HYDROCARBONS Rate constants REACTION KINETICS Saturn satellites Titan |
| title | Electron-ion dissociative recombination rate constants relevant to the Titan atmosphere and the Interstellar Medium |
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