Extreme ultraviolet induced defects on few-layer graphene

We use Raman spectroscopy to show that exposing few-layer graphene to extreme ultraviolet (EUV, 13.5 nm) radiation, i.e., relatively low photon energy, results in an increasing density of defects. Furthermore, exposure to EUV radiation in a H2 background increases the graphene dosage sensitivity, du...

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Veröffentlicht in:Journal of applied physics 2013-07, Vol.114 (4)
Hauptverfasser: Gao, A., Rizo, P. J., Zoethout, E., Scaccabarozzi, L., Lee, C. J., Banine, V., Bijkerk, F.
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container_issue 4
container_start_page
container_title Journal of applied physics
container_volume 114
creator Gao, A.
Rizo, P. J.
Zoethout, E.
Scaccabarozzi, L.
Lee, C. J.
Banine, V.
Bijkerk, F.
description We use Raman spectroscopy to show that exposing few-layer graphene to extreme ultraviolet (EUV, 13.5 nm) radiation, i.e., relatively low photon energy, results in an increasing density of defects. Furthermore, exposure to EUV radiation in a H2 background increases the graphene dosage sensitivity, due to reactions caused by the EUV induced hydrogen plasma. X-ray photoelectron spectroscopy results show that the sp2 bonded carbon fraction decreases while the sp3 bonded carbon and oxide fraction increases with exposure dose. Our experimental results confirm that even in reducing environment oxidation is still one of the main source of inducing defects.
doi_str_mv 10.1063/1.4817082
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source AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection
subjects Background radiation
Bonding
Carbon
CHEMICAL BONDS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Defects
DENSITY
DOSES
EXTREME ULTRAVIOLET RADIATION
GRAPHENE
HYDROGEN
Hydrogen plasma
LAYERS
MATERIALS SCIENCE
OXIDATION
OXIDES
PHOTONS
RAMAN SPECTRA
RAMAN SPECTROSCOPY
Ultraviolet
X-RAY PHOTOELECTRON SPECTROSCOPY
title Extreme ultraviolet induced defects on few-layer graphene
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