Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media
In this communication, we carried out the systematic investigation of nonlinear absorption and scattering properties of Aluminium nanoparticles (Al NPs) in various polar and non-polar solvents. Al NPs were synthesized with pulsed Nd:YAG laser operated at 1064 nm by ablating Al target in polar and no...
Gespeichert in:
Veröffentlicht in: | Journal of applied physics 2013-12, Vol.114 (24) |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | |
---|---|
container_issue | 24 |
container_start_page | |
container_title | Journal of applied physics |
container_volume | 114 |
creator | Kuladeep, Rajamudili Jyothi, L. Prakash, P. Mayank Shekhar, S. Durga Prasad, M. Narayana Rao, D. |
description | In this communication, we carried out the systematic investigation of nonlinear absorption and scattering properties of Aluminium nanoparticles (Al NPs) in various polar and non-polar solvents. Al NPs were synthesized with pulsed Nd:YAG laser operated at 1064 nm by ablating Al target in polar and non-polar liquid environment like chloroform, chlorobenzene, toluene, benzene, and carbon tetrachloride. Synthesized Al NPs colloids of various solvents differ in appearance and UV-Vis extinction spectra exhibit absorption in the UV region. The characterization of Al NPs performed by Transmission electron microscopy (TEM) studies reveal that NPs are made up of a well crystallized Al inner part (bright zone) embedded with an amorphous metal Al shell (dark region). Growth, aggregation, and precipitation mechanisms which influence the optical properties and stability of NPs are found to be related to the dipole moment of the surrounding liquid environment. The nonlinear absorption and scattering studies are performed by open aperture Z-scan technique with 532 nm under nanosecond pulse excitation. The Z-scan measurements are fitted theoretically to estimate both two-photon absorption (TPA) and nonlinear scattering (NLS) coefficients. In polar solvents like chlorobenzene, chloroform synthesized Al NPs exhibited higher TPA, NLS coefficient values, and lower optical limiting threshold values in comparison with partially polar solvent like toluene and non-polar solvents like benzene and carbontetrachloride. These results indicate the potential use of Al NPs as a versatile optical limiting material. |
doi_str_mv | 10.1063/1.4852976 |
format | Article |
fullrecord | <record><control><sourceid>proquest_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_22217719</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2127763121</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-daac5b96b0010c557f4ce3984463b5b662081b4fbad646ee6aaf914eecb1d78c3</originalsourceid><addsrcrecordid>eNpFkU9vFiEQxonRxNfqwW9A4kUPWxlY2OXYNP5p0sSLngmws5WGhRVYk9794NK8jZ4Y8vzmyTwzhLwFdglMiY9wOc6S60k9Iydgsx4mKdlzcmKMwzDrSb8kr2q9ZwxgFvpE_tyk31hbuLMt5ETzSvPegreRxrCFFtId3UvesbSA9VG-iscWUjg2mmzKu-2Cj13aC_YPLtQ90P2ItVfRVizUunj2DokuYV2xYGrU21JCVzdcgn1NXqy2t7x5ei_Ij8-fvl9_HW6_fbm5vrodvIC5DYu1XjqtXJ-eeSmndfQo9DyOSjjplOJsBjeuzi5qVIjK2lXDiOgdLNPsxQV5d_bNPbGpPjT0P31OCX0znHOYJtCden-mevBfR1-O2UL1GKNNmI9qQPZFK6G1_G_4D73PR0k9g-HAp0kJ4NCpD2fKl1xrwdXsJWy2PBhg5vFqBszT1cRfWIWLow</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2127763121</pqid></control><display><type>article</type><title>Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media</title><source>AIP Journals Complete</source><source>AIP Digital Archive</source><source>Alma/SFX Local Collection</source><creator>Kuladeep, Rajamudili ; Jyothi, L. ; Prakash, P. ; Mayank Shekhar, S. ; Durga Prasad, M. ; Narayana Rao, D.</creator><creatorcontrib>Kuladeep, Rajamudili ; Jyothi, L. ; Prakash, P. ; Mayank Shekhar, S. ; Durga Prasad, M. ; Narayana Rao, D.</creatorcontrib><description>In this communication, we carried out the systematic investigation of nonlinear absorption and scattering properties of Aluminium nanoparticles (Al NPs) in various polar and non-polar solvents. Al NPs were synthesized with pulsed Nd:YAG laser operated at 1064 nm by ablating Al target in polar and non-polar liquid environment like chloroform, chlorobenzene, toluene, benzene, and carbon tetrachloride. Synthesized Al NPs colloids of various solvents differ in appearance and UV-Vis extinction spectra exhibit absorption in the UV region. The characterization of Al NPs performed by Transmission electron microscopy (TEM) studies reveal that NPs are made up of a well crystallized Al inner part (bright zone) embedded with an amorphous metal Al shell (dark region). Growth, aggregation, and precipitation mechanisms which influence the optical properties and stability of NPs are found to be related to the dipole moment of the surrounding liquid environment. The nonlinear absorption and scattering studies are performed by open aperture Z-scan technique with 532 nm under nanosecond pulse excitation. The Z-scan measurements are fitted theoretically to estimate both two-photon absorption (TPA) and nonlinear scattering (NLS) coefficients. In polar solvents like chlorobenzene, chloroform synthesized Al NPs exhibited higher TPA, NLS coefficient values, and lower optical limiting threshold values in comparison with partially polar solvent like toluene and non-polar solvents like benzene and carbontetrachloride. These results indicate the potential use of Al NPs as a versatile optical limiting material.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.4852976</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>ABSORPTION ; ALUMINIUM ; Aluminum ; Applied physics ; BENZENE ; CARBON TETRACHLORIDE ; Chlorobenzene ; CHLOROFORM ; Constraining ; Crystallization ; Dipole moments ; Hydrocarbons ; Laser ablation ; MATERIALS SCIENCE ; Nanoparticles ; NANOSCIENCE AND NANOTECHNOLOGY ; Nanosecond pulses ; NANOSTRUCTURES ; NEODYMIUM ; NEODYMIUM LASERS ; OPTICAL PROPERTIES ; Photon absorption ; Pulsed lasers ; Scattering ; Semiconductor lasers ; SOLVENTS ; Synthesis ; TOLUENE ; TRANSMISSION ELECTRON MICROSCOPY ; ULTRAVIOLET SPECTRA ; YAG lasers</subject><ispartof>Journal of applied physics, 2013-12, Vol.114 (24)</ispartof><rights>2013 AIP Publishing LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-daac5b96b0010c557f4ce3984463b5b662081b4fbad646ee6aaf914eecb1d78c3</citedby><cites>FETCH-LOGICAL-c318t-daac5b96b0010c557f4ce3984463b5b662081b4fbad646ee6aaf914eecb1d78c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22217719$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Kuladeep, Rajamudili</creatorcontrib><creatorcontrib>Jyothi, L.</creatorcontrib><creatorcontrib>Prakash, P.</creatorcontrib><creatorcontrib>Mayank Shekhar, S.</creatorcontrib><creatorcontrib>Durga Prasad, M.</creatorcontrib><creatorcontrib>Narayana Rao, D.</creatorcontrib><title>Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media</title><title>Journal of applied physics</title><description>In this communication, we carried out the systematic investigation of nonlinear absorption and scattering properties of Aluminium nanoparticles (Al NPs) in various polar and non-polar solvents. Al NPs were synthesized with pulsed Nd:YAG laser operated at 1064 nm by ablating Al target in polar and non-polar liquid environment like chloroform, chlorobenzene, toluene, benzene, and carbon tetrachloride. Synthesized Al NPs colloids of various solvents differ in appearance and UV-Vis extinction spectra exhibit absorption in the UV region. The characterization of Al NPs performed by Transmission electron microscopy (TEM) studies reveal that NPs are made up of a well crystallized Al inner part (bright zone) embedded with an amorphous metal Al shell (dark region). Growth, aggregation, and precipitation mechanisms which influence the optical properties and stability of NPs are found to be related to the dipole moment of the surrounding liquid environment. The nonlinear absorption and scattering studies are performed by open aperture Z-scan technique with 532 nm under nanosecond pulse excitation. The Z-scan measurements are fitted theoretically to estimate both two-photon absorption (TPA) and nonlinear scattering (NLS) coefficients. In polar solvents like chlorobenzene, chloroform synthesized Al NPs exhibited higher TPA, NLS coefficient values, and lower optical limiting threshold values in comparison with partially polar solvent like toluene and non-polar solvents like benzene and carbontetrachloride. These results indicate the potential use of Al NPs as a versatile optical limiting material.</description><subject>ABSORPTION</subject><subject>ALUMINIUM</subject><subject>Aluminum</subject><subject>Applied physics</subject><subject>BENZENE</subject><subject>CARBON TETRACHLORIDE</subject><subject>Chlorobenzene</subject><subject>CHLOROFORM</subject><subject>Constraining</subject><subject>Crystallization</subject><subject>Dipole moments</subject><subject>Hydrocarbons</subject><subject>Laser ablation</subject><subject>MATERIALS SCIENCE</subject><subject>Nanoparticles</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>Nanosecond pulses</subject><subject>NANOSTRUCTURES</subject><subject>NEODYMIUM</subject><subject>NEODYMIUM LASERS</subject><subject>OPTICAL PROPERTIES</subject><subject>Photon absorption</subject><subject>Pulsed lasers</subject><subject>Scattering</subject><subject>Semiconductor lasers</subject><subject>SOLVENTS</subject><subject>Synthesis</subject><subject>TOLUENE</subject><subject>TRANSMISSION ELECTRON MICROSCOPY</subject><subject>ULTRAVIOLET SPECTRA</subject><subject>YAG lasers</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNpFkU9vFiEQxonRxNfqwW9A4kUPWxlY2OXYNP5p0sSLngmws5WGhRVYk9794NK8jZ4Y8vzmyTwzhLwFdglMiY9wOc6S60k9Iydgsx4mKdlzcmKMwzDrSb8kr2q9ZwxgFvpE_tyk31hbuLMt5ETzSvPegreRxrCFFtId3UvesbSA9VG-iscWUjg2mmzKu-2Cj13aC_YPLtQ90P2ItVfRVizUunj2DokuYV2xYGrU21JCVzdcgn1NXqy2t7x5ei_Ij8-fvl9_HW6_fbm5vrodvIC5DYu1XjqtXJ-eeSmndfQo9DyOSjjplOJsBjeuzi5qVIjK2lXDiOgdLNPsxQV5d_bNPbGpPjT0P31OCX0znHOYJtCden-mevBfR1-O2UL1GKNNmI9qQPZFK6G1_G_4D73PR0k9g-HAp0kJ4NCpD2fKl1xrwdXsJWy2PBhg5vFqBszT1cRfWIWLow</recordid><startdate>20131228</startdate><enddate>20131228</enddate><creator>Kuladeep, Rajamudili</creator><creator>Jyothi, L.</creator><creator>Prakash, P.</creator><creator>Mayank Shekhar, S.</creator><creator>Durga Prasad, M.</creator><creator>Narayana Rao, D.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7QF</scope><scope>7SP</scope><scope>7U5</scope><scope>JG9</scope><scope>OTOTI</scope></search><sort><creationdate>20131228</creationdate><title>Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media</title><author>Kuladeep, Rajamudili ; Jyothi, L. ; Prakash, P. ; Mayank Shekhar, S. ; Durga Prasad, M. ; Narayana Rao, D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-daac5b96b0010c557f4ce3984463b5b662081b4fbad646ee6aaf914eecb1d78c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>ABSORPTION</topic><topic>ALUMINIUM</topic><topic>Aluminum</topic><topic>Applied physics</topic><topic>BENZENE</topic><topic>CARBON TETRACHLORIDE</topic><topic>Chlorobenzene</topic><topic>CHLOROFORM</topic><topic>Constraining</topic><topic>Crystallization</topic><topic>Dipole moments</topic><topic>Hydrocarbons</topic><topic>Laser ablation</topic><topic>MATERIALS SCIENCE</topic><topic>Nanoparticles</topic><topic>NANOSCIENCE AND NANOTECHNOLOGY</topic><topic>Nanosecond pulses</topic><topic>NANOSTRUCTURES</topic><topic>NEODYMIUM</topic><topic>NEODYMIUM LASERS</topic><topic>OPTICAL PROPERTIES</topic><topic>Photon absorption</topic><topic>Pulsed lasers</topic><topic>Scattering</topic><topic>Semiconductor lasers</topic><topic>SOLVENTS</topic><topic>Synthesis</topic><topic>TOLUENE</topic><topic>TRANSMISSION ELECTRON MICROSCOPY</topic><topic>ULTRAVIOLET SPECTRA</topic><topic>YAG lasers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kuladeep, Rajamudili</creatorcontrib><creatorcontrib>Jyothi, L.</creatorcontrib><creatorcontrib>Prakash, P.</creatorcontrib><creatorcontrib>Mayank Shekhar, S.</creatorcontrib><creatorcontrib>Durga Prasad, M.</creatorcontrib><creatorcontrib>Narayana Rao, D.</creatorcontrib><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Aluminium Industry Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Materials Research Database</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuladeep, Rajamudili</au><au>Jyothi, L.</au><au>Prakash, P.</au><au>Mayank Shekhar, S.</au><au>Durga Prasad, M.</au><au>Narayana Rao, D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media</atitle><jtitle>Journal of applied physics</jtitle><date>2013-12-28</date><risdate>2013</risdate><volume>114</volume><issue>24</issue><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>In this communication, we carried out the systematic investigation of nonlinear absorption and scattering properties of Aluminium nanoparticles (Al NPs) in various polar and non-polar solvents. Al NPs were synthesized with pulsed Nd:YAG laser operated at 1064 nm by ablating Al target in polar and non-polar liquid environment like chloroform, chlorobenzene, toluene, benzene, and carbon tetrachloride. Synthesized Al NPs colloids of various solvents differ in appearance and UV-Vis extinction spectra exhibit absorption in the UV region. The characterization of Al NPs performed by Transmission electron microscopy (TEM) studies reveal that NPs are made up of a well crystallized Al inner part (bright zone) embedded with an amorphous metal Al shell (dark region). Growth, aggregation, and precipitation mechanisms which influence the optical properties and stability of NPs are found to be related to the dipole moment of the surrounding liquid environment. The nonlinear absorption and scattering studies are performed by open aperture Z-scan technique with 532 nm under nanosecond pulse excitation. The Z-scan measurements are fitted theoretically to estimate both two-photon absorption (TPA) and nonlinear scattering (NLS) coefficients. In polar solvents like chlorobenzene, chloroform synthesized Al NPs exhibited higher TPA, NLS coefficient values, and lower optical limiting threshold values in comparison with partially polar solvent like toluene and non-polar solvents like benzene and carbontetrachloride. These results indicate the potential use of Al NPs as a versatile optical limiting material.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.4852976</doi></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0021-8979 |
ispartof | Journal of applied physics, 2013-12, Vol.114 (24) |
issn | 0021-8979 1089-7550 |
language | eng |
recordid | cdi_osti_scitechconnect_22217719 |
source | AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection |
subjects | ABSORPTION ALUMINIUM Aluminum Applied physics BENZENE CARBON TETRACHLORIDE Chlorobenzene CHLOROFORM Constraining Crystallization Dipole moments Hydrocarbons Laser ablation MATERIALS SCIENCE Nanoparticles NANOSCIENCE AND NANOTECHNOLOGY Nanosecond pulses NANOSTRUCTURES NEODYMIUM NEODYMIUM LASERS OPTICAL PROPERTIES Photon absorption Pulsed lasers Scattering Semiconductor lasers SOLVENTS Synthesis TOLUENE TRANSMISSION ELECTRON MICROSCOPY ULTRAVIOLET SPECTRA YAG lasers |
title | Investigation of optical limiting properties of Aluminium nanoparticles prepared by pulsed laser ablation in different carrier media |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T06%3A27%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigation%20of%20optical%20limiting%20properties%20of%20Aluminium%20nanoparticles%20prepared%20by%20pulsed%20laser%20ablation%20in%20different%20carrier%20media&rft.jtitle=Journal%20of%20applied%20physics&rft.au=Kuladeep,%20Rajamudili&rft.date=2013-12-28&rft.volume=114&rft.issue=24&rft.issn=0021-8979&rft.eissn=1089-7550&rft_id=info:doi/10.1063/1.4852976&rft_dat=%3Cproquest_osti_%3E2127763121%3C/proquest_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2127763121&rft_id=info:pmid/&rfr_iscdi=true |