Modulated crystal structures of phases VII and V in (NH{sub 4}){sub 3}H(SO{sub 4}){sub 2}. Neutron Laue diffraction

A study of the crystal structure of the phases VII and V of (NH{sub 4}){sub 3}H(SO{sub 4}){sub 2} by mean of neutron Laue diffraction was carried out at temperatures from 5 to 300 K. It is found that the crystal structures of phases VII and V are incommensurately modulated with different periods, an...

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Veröffentlicht in:Crystallography reports 2013-01, Vol.58 (1)
Hauptverfasser: McIntyre, G. J., Smirnov, L. S., Baranov, A. I., Dolbinina, V. V., Frontasyeva, M. V., Pavlov, S. S., Pankratova, Yu. S.
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container_title Crystallography reports
container_volume 58
creator McIntyre, G. J.
Smirnov, L. S.
Baranov, A. I.
Dolbinina, V. V.
Frontasyeva, M. V.
Pavlov, S. S.
Pankratova, Yu. S.
description A study of the crystal structure of the phases VII and V of (NH{sub 4}){sub 3}H(SO{sub 4}){sub 2} by mean of neutron Laue diffraction was carried out at temperatures from 5 to 300 K. It is found that the crystal structures of phases VII and V are incommensurately modulated with different periods, and that the phase transition from phase VII to phase V is of first order.
doi_str_mv 10.1134/S1063774513010239
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subjects CRYSTAL STRUCTURE
DIFFRACTION
MATERIALS SCIENCE
NEUTRONS
PHASE TRANSFORMATIONS
SULFATES
title Modulated crystal structures of phases VII and V in (NH{sub 4}){sub 3}H(SO{sub 4}){sub 2}. Neutron Laue diffraction
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