Single crystal to single crystal transition in (10, 3)-d framework with pyrazine-2-carboxylate ligand: Synthesis, structures and magnetism

Assembling of pyrazine-2-carboxylate (Pzc) acid with nickel chlorine under solvothermal condition with MeOH as solvent gave a porous complex 1 {[Ni(Pzc)ClH2O]·MeOH}n with 1D channels. In 1 the ligands and metal ions are connected by three of each other and a rare (10,3)-d topology net is gained. The...

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Veröffentlicht in:	Journal of solid state chemistry 2012-12, Vol.196, p.52-57
Hauptverfasser:	Yang, Qian, Zhao, Jiong-Peng, Liu, Zhong-Yi
Format:	Artikel
Sprache:	eng
Schlagworte:	(10,3)-d topology ANTIFERROMAGNETISM CHEMICAL PREPARATION CHLORINE Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Exact sciences and technology Growth from solutions INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERACTIONS LIGANDS Magnetism MATERIALS SCIENCE Methods of crystal growth physics of crystal growth MONOCRYSTALS NICKEL Other materials Physics POROUS MATERIALS SC–SC transformation Solvothermal synthesis Specific materials Structure of solids and liquids crystallography
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