Quantitative assessment of alkali-reactive aggregate mineral content through XRD using polished sections as a supplementary tool to RILEM AAR-1 (petrographic method)

The mineral content of 5 aggregate samples from 4 different countries, including reactive and non-reactive aggregate types, was assessed quantitatively by X-ray diffraction (XRD) using polished sections. Additionally, electron probe microanalyzer (EPMA) mapping and cathodoluminescence (CL) were used...

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Veröffentlicht in:Cement and concrete research 2012-11, Vol.42 (11), p.1428-1437
Hauptverfasser: Castro, Nélia, Sorensen, Bjørn E., Broekmans, Maarten A.T.M.
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container_end_page 1437
container_issue 11
container_start_page 1428
container_title Cement and concrete research
container_volume 42
creator Castro, Nélia
Sorensen, Bjørn E.
Broekmans, Maarten A.T.M.
description The mineral content of 5 aggregate samples from 4 different countries, including reactive and non-reactive aggregate types, was assessed quantitatively by X-ray diffraction (XRD) using polished sections. Additionally, electron probe microanalyzer (EPMA) mapping and cathodoluminescence (CL) were used to characterize the opal-CT identified in one of the aggregate samples. Critical review of results from polished sections against traditionally powdered specimen has demonstrated that for fine-grained rocks without preferred orientation the assessment of mineral content by XRD using polished sections may represent an advantage over traditional powder specimens. Comparison of data on mineral content and silica speciation with expansion data from PARTNER project confirmed that the presence of opal-CT plays an important role in the reactivity of one of the studied aggregates. Used as a complementary tool to RILEM AAR-1, the methodology suggested in this paper has the potential to improve the strength of the petrographic method.
doi_str_mv 10.1016/j.cemconres.2012.08.004
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subjects Aggregate (D)
Aggregates and other concrete constituents
Alkali-aggregate reaction (C)
Applied sciences
Buildings. Public works
CATHODOLUMINESCENCE
Cement concrete constituents
ELECTRON MICROPROBE ANALYSIS
ELECTRON PROBES
Exact sciences and technology
GRAIN ORIENTATION
Materials
MATERIALS SCIENCE
Opaline silica
OPALS
PETROGRAPHY
Petrography (B)
REACTIVITY
ROCKS
X-RAY DIFFRACTION
X-ray diffraction (B)
title Quantitative assessment of alkali-reactive aggregate mineral content through XRD using polished sections as a supplementary tool to RILEM AAR-1 (petrographic method)
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