Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids
The structure of three complexes of bivalent metals (cobalt, nickel, and cadmium) with anions of benzoic (H L 1 ) and 2-(acetylamino)-5-nitrobenzoic (H L 2 ) acids, namely, [Co 2 1 (H 2 O) 2 (μ-C 4 H 4 N 2 )] n ( I ), [NiL 2 (H 2 O) 5 ]L 2 · 2H 2 O ( II ), and [Cd(μ- L 2 ) 2 (H 2 O) 2 ] n · 2 n H 2...
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| Veröffentlicht in: | Crystallography reports 2012-03, Vol.57 (2), p.208-212 |
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| container_title | Crystallography reports |
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| creator | Rzaeva, M. F. Askerov, R. K. Movsumov, E. M. Sergienko, V. S. Ilyukhin, A. B. |
| description | The structure of three complexes of bivalent metals (cobalt, nickel, and cadmium) with anions of benzoic (H
L
1
) and 2-(acetylamino)-5-nitrobenzoic (H
L
2
) acids, namely, [Co
2
1
(H
2
O)
2
(μ-C
4
H
4
N
2
)]
n
(
I
), [NiL
2
(H
2
O)
5
]L
2
· 2H
2
O (
II
), and [Cd(μ-
L
2
)
2
(H
2
O)
2
]
n
· 2
n
H
2
O (
III
), is determined. In chainlike structure
I
, cobalt atoms are connected by bridging pyrazine molecules; structure
II
contains isolated complexes. In structure
III
, centrosymmetric (CdOCO)
2
cycles and polymeric ribbons are formed due to the coordination of the carboxylate group of the
L
2
ligand to two cadmium atoms. |
| doi_str_mv | 10.1134/S1063774512010117 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_22054188</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1134_S1063774512010117</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-38d28b6bb2da9da0129b80ccc535f75986403f02c8e0f3d17170b804a69956013</originalsourceid><addsrcrecordid>eNp9kE9LxDAQxYMouK5-AG8FLwobzaRNmx6l-A8WPajgraRp6mbpJkuSVeunN2vFi-Bp3vB-b2AeQsdAzgHS7OIRSJ4WRcaAEiAAxQ6aAMspznn5sht1tPHW30cH3i8JIZxDNkFD5QYfRJ_44DYybJxKbJdIu1r36kP57dLoN9ErE5LKzpJ7PUuEaZOqTd51WEStrRkxZT6tlt8uxadCqjD0YqWNPcMMGx2c_UWkbv0h2utE79XRz5yi5-urp-oWzx9u7qrLOZY05wGnvKW8yZuGtqJsBQFaNpxIKVnKuoKVPM9I2hEquSJd2kIBBYlAJvKyZDmBdIpOxrvWB117qYOSC2mNUTLUlBKWAeeRgpGSznrvVFevnV4JN9RA6m3D9Z-GY4aOGR9Z86pcvbQbZ-Iz_4S-AEfCfBg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids</title><source>SpringerLink Journals</source><creator>Rzaeva, M. F. ; Askerov, R. K. ; Movsumov, E. M. ; Sergienko, V. S. ; Ilyukhin, A. B.</creator><creatorcontrib>Rzaeva, M. F. ; Askerov, R. K. ; Movsumov, E. M. ; Sergienko, V. S. ; Ilyukhin, A. B.</creatorcontrib><description>The structure of three complexes of bivalent metals (cobalt, nickel, and cadmium) with anions of benzoic (H
L
1
) and 2-(acetylamino)-5-nitrobenzoic (H
L
2
) acids, namely, [Co
2
1
(H
2
O)
2
(μ-C
4
H
4
N
2
)]
n
(
I
), [NiL
2
(H
2
O)
5
]L
2
· 2H
2
O (
II
), and [Cd(μ-
L
2
)
2
(H
2
O)
2
]
n
· 2
n
H
2
O (
III
), is determined. In chainlike structure
I
, cobalt atoms are connected by bridging pyrazine molecules; structure
II
contains isolated complexes. In structure
III
, centrosymmetric (CdOCO)
2
cycles and polymeric ribbons are formed due to the coordination of the carboxylate group of the
L
2
ligand to two cadmium atoms.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774512010117</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>ANIONS ; CADMIUM COMPLEXES ; COBALT COMPLEXES ; CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ; CRYSTAL STRUCTURE ; Crystallography and Scattering Methods ; LIGANDS ; NICKEL COMPLEXES ; Physics ; Physics and Astronomy ; Structure of Organic Compounds ; WATER</subject><ispartof>Crystallography reports, 2012-03, Vol.57 (2), p.208-212</ispartof><rights>Pleiades Publishing, Ltd. 2012</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-38d28b6bb2da9da0129b80ccc535f75986403f02c8e0f3d17170b804a69956013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1063774512010117$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1063774512010117$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22054188$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Rzaeva, M. F.</creatorcontrib><creatorcontrib>Askerov, R. K.</creatorcontrib><creatorcontrib>Movsumov, E. M.</creatorcontrib><creatorcontrib>Sergienko, V. S.</creatorcontrib><creatorcontrib>Ilyukhin, A. B.</creatorcontrib><title>Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids</title><title>Crystallography reports</title><addtitle>Crystallogr. Rep</addtitle><description>The structure of three complexes of bivalent metals (cobalt, nickel, and cadmium) with anions of benzoic (H
L
1
) and 2-(acetylamino)-5-nitrobenzoic (H
L
2
) acids, namely, [Co
2
1
(H
2
O)
2
(μ-C
4
H
4
N
2
)]
n
(
I
), [NiL
2
(H
2
O)
5
]L
2
· 2H
2
O (
II
), and [Cd(μ-
L
2
)
2
(H
2
O)
2
]
n
· 2
n
H
2
O (
III
), is determined. In chainlike structure
I
, cobalt atoms are connected by bridging pyrazine molecules; structure
II
contains isolated complexes. In structure
III
, centrosymmetric (CdOCO)
2
cycles and polymeric ribbons are formed due to the coordination of the carboxylate group of the
L
2
ligand to two cadmium atoms.</description><subject>ANIONS</subject><subject>CADMIUM COMPLEXES</subject><subject>COBALT COMPLEXES</subject><subject>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</subject><subject>CRYSTAL STRUCTURE</subject><subject>Crystallography and Scattering Methods</subject><subject>LIGANDS</subject><subject>NICKEL COMPLEXES</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Structure of Organic Compounds</subject><subject>WATER</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AG8FLwobzaRNmx6l-A8WPajgraRp6mbpJkuSVeunN2vFi-Bp3vB-b2AeQsdAzgHS7OIRSJ4WRcaAEiAAxQ6aAMspznn5sht1tPHW30cH3i8JIZxDNkFD5QYfRJ_44DYybJxKbJdIu1r36kP57dLoN9ErE5LKzpJ7PUuEaZOqTd51WEStrRkxZT6tlt8uxadCqjD0YqWNPcMMGx2c_UWkbv0h2utE79XRz5yi5-urp-oWzx9u7qrLOZY05wGnvKW8yZuGtqJsBQFaNpxIKVnKuoKVPM9I2hEquSJd2kIBBYlAJvKyZDmBdIpOxrvWB117qYOSC2mNUTLUlBKWAeeRgpGSznrvVFevnV4JN9RA6m3D9Z-GY4aOGR9Z86pcvbQbZ-Iz_4S-AEfCfBg</recordid><startdate>20120301</startdate><enddate>20120301</enddate><creator>Rzaeva, M. F.</creator><creator>Askerov, R. K.</creator><creator>Movsumov, E. M.</creator><creator>Sergienko, V. S.</creator><creator>Ilyukhin, A. B.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20120301</creationdate><title>Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids</title><author>Rzaeva, M. F. ; Askerov, R. K. ; Movsumov, E. M. ; Sergienko, V. S. ; Ilyukhin, A. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-38d28b6bb2da9da0129b80ccc535f75986403f02c8e0f3d17170b804a69956013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>ANIONS</topic><topic>CADMIUM COMPLEXES</topic><topic>COBALT COMPLEXES</topic><topic>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</topic><topic>CRYSTAL STRUCTURE</topic><topic>Crystallography and Scattering Methods</topic><topic>LIGANDS</topic><topic>NICKEL COMPLEXES</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Structure of Organic Compounds</topic><topic>WATER</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rzaeva, M. F.</creatorcontrib><creatorcontrib>Askerov, R. K.</creatorcontrib><creatorcontrib>Movsumov, E. M.</creatorcontrib><creatorcontrib>Sergienko, V. S.</creatorcontrib><creatorcontrib>Ilyukhin, A. B.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rzaeva, M. F.</au><au>Askerov, R. K.</au><au>Movsumov, E. M.</au><au>Sergienko, V. S.</au><au>Ilyukhin, A. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids</atitle><jtitle>Crystallography reports</jtitle><stitle>Crystallogr. Rep</stitle><date>2012-03-01</date><risdate>2012</risdate><volume>57</volume><issue>2</issue><spage>208</spage><epage>212</epage><pages>208-212</pages><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>The structure of three complexes of bivalent metals (cobalt, nickel, and cadmium) with anions of benzoic (H
L
1
) and 2-(acetylamino)-5-nitrobenzoic (H
L
2
) acids, namely, [Co
2
1
(H
2
O)
2
(μ-C
4
H
4
N
2
)]
n
(
I
), [NiL
2
(H
2
O)
5
]L
2
· 2H
2
O (
II
), and [Cd(μ-
L
2
)
2
(H
2
O)
2
]
n
· 2
n
H
2
O (
III
), is determined. In chainlike structure
I
, cobalt atoms are connected by bridging pyrazine molecules; structure
II
contains isolated complexes. In structure
III
, centrosymmetric (CdOCO)
2
cycles and polymeric ribbons are formed due to the coordination of the carboxylate group of the
L
2
ligand to two cadmium atoms.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1063774512010117</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Crystallography reports, 2012-03, Vol.57 (2), p.208-212 |
| issn | 1063-7745 1562-689X |
| language | eng |
| recordid | cdi_osti_scitechconnect_22054188 |
| source | SpringerLink Journals |
| subjects | ANIONS CADMIUM COMPLEXES COBALT COMPLEXES CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY CRYSTAL STRUCTURE Crystallography and Scattering Methods LIGANDS NICKEL COMPLEXES Physics Physics and Astronomy Structure of Organic Compounds WATER |
| title | Crystal structure of complexes of bivalent Co, Ni, and Cd with anions of benzoic and 2-(acetylamino)-5-nitrobenzoic acids |
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