Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1)
The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.70...
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| Veröffentlicht in: | Crystallography reports 2010-05, Vol.55 (3) |
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| container_title | Crystallography reports |
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| creator | Serezhkina, L. B. Peresypkina, E. V. Virovets, A. V. Pushkin, D. V. Verevkin, A. G. |
| description | The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.706(1){sup o}, space group P2{sub 1}/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) A, b = 11.5358(3) A, c = 9.5565(2) A, {beta} = 113.273(1){sup o}, space group P2{sub 1}/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO{sub 2}(SeO{sub 4})(OH)]{sup -} layers which belong to the AT{sup 3}M{sup 2} crystal chemical group of uranyl complexes (A = UO{sub 2}{sup 2+}, T{sup 3} = SeO{sub 4}{sup 2-}, and M{sup 2} = OH{sup -}). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands. |
| doi_str_mv | 10.1134/S1063774510030041 |
| format | Article |
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G.</creator><creatorcontrib>Serezhkina, L. B. ; Peresypkina, E. V. ; Virovets, A. V. ; Pushkin, D. V. ; Verevkin, A. G.</creatorcontrib><description>The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.706(1){sup o}, space group P2{sub 1}/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) A, b = 11.5358(3) A, c = 9.5565(2) A, {beta} = 113.273(1){sup o}, space group P2{sub 1}/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO{sub 2}(SeO{sub 4})(OH)]{sup -} layers which belong to the AT{sup 3}M{sup 2} crystal chemical group of uranyl complexes (A = UO{sub 2}{sup 2+}, T{sup 3} = SeO{sub 4}{sup 2-}, and M{sup 2} = OH{sup -}). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands.</description><identifier>ISSN: 1063-7745</identifier><identifier>EISSN: 1562-689X</identifier><identifier>DOI: 10.1134/S1063774510030041</identifier><language>eng</language><publisher>United States</publisher><subject>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ; ISOMERS ; LAYERS ; LIGANDS ; MONOCLINIC LATTICES ; MONOCRYSTALS ; SELENATES ; SPACE GROUPS ; SULFATE MINERALS ; SYNTHESIS ; TOPOLOGY ; URANIUM MINERALS ; URANYL COMPLEXES ; WATER ; X-RAY DIFFRACTION</subject><ispartof>Crystallography reports, 2010-05, Vol.55 (3)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/22051209$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Serezhkina, L. B.</creatorcontrib><creatorcontrib>Peresypkina, E. V.</creatorcontrib><creatorcontrib>Virovets, A. V.</creatorcontrib><creatorcontrib>Pushkin, D. V.</creatorcontrib><creatorcontrib>Verevkin, A. G.</creatorcontrib><title>Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1)</title><title>Crystallography reports</title><description>The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.706(1){sup o}, space group P2{sub 1}/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) A, b = 11.5358(3) A, c = 9.5565(2) A, {beta} = 113.273(1){sup o}, space group P2{sub 1}/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO{sub 2}(SeO{sub 4})(OH)]{sup -} layers which belong to the AT{sup 3}M{sup 2} crystal chemical group of uranyl complexes (A = UO{sub 2}{sup 2+}, T{sup 3} = SeO{sub 4}{sup 2-}, and M{sup 2} = OH{sup -}). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands.</description><subject>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</subject><subject>ISOMERS</subject><subject>LAYERS</subject><subject>LIGANDS</subject><subject>MONOCLINIC LATTICES</subject><subject>MONOCRYSTALS</subject><subject>SELENATES</subject><subject>SPACE GROUPS</subject><subject>SULFATE MINERALS</subject><subject>SYNTHESIS</subject><subject>TOPOLOGY</subject><subject>URANIUM MINERALS</subject><subject>URANYL COMPLEXES</subject><subject>WATER</subject><subject>X-RAY DIFFRACTION</subject><issn>1063-7745</issn><issn>1562-689X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqNyrGKwkAUheFhcWF19QHsLtgkRbL3TiYxFlaipEsRFxZkkThOMCITyJ0UIr67ij6A1fnhO0KMCUOiSP0UhEk0naqYECNERR-iT3EigySd_fXufefg4V9iwHxExDQl1Rfr4mzdwXDNUNo9sGs77brWQFPBgje_-YW7HcirV5hnqqvv5Zn_DyHY7IU5eBbmQGEMTQvkD8VnVZ7YjF77LSar5XqRBQ27esu6dkYfdGOt0W4rJcYkcRa997oBfmdDEQ</recordid><startdate>20100515</startdate><enddate>20100515</enddate><creator>Serezhkina, L. B.</creator><creator>Peresypkina, E. V.</creator><creator>Virovets, A. V.</creator><creator>Pushkin, D. V.</creator><creator>Verevkin, A. G.</creator><scope>OTOTI</scope></search><sort><creationdate>20100515</creationdate><title>Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1)</title><author>Serezhkina, L. B. ; Peresypkina, E. V. ; Virovets, A. V. ; Pushkin, D. V. ; Verevkin, A. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_220512093</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</topic><topic>ISOMERS</topic><topic>LAYERS</topic><topic>LIGANDS</topic><topic>MONOCLINIC LATTICES</topic><topic>MONOCRYSTALS</topic><topic>SELENATES</topic><topic>SPACE GROUPS</topic><topic>SULFATE MINERALS</topic><topic>SYNTHESIS</topic><topic>TOPOLOGY</topic><topic>URANIUM MINERALS</topic><topic>URANYL COMPLEXES</topic><topic>WATER</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Serezhkina, L. B.</creatorcontrib><creatorcontrib>Peresypkina, E. V.</creatorcontrib><creatorcontrib>Virovets, A. V.</creatorcontrib><creatorcontrib>Pushkin, D. V.</creatorcontrib><creatorcontrib>Verevkin, A. G.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Serezhkina, L. B.</au><au>Peresypkina, E. V.</au><au>Virovets, A. V.</au><au>Pushkin, D. V.</au><au>Verevkin, A. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1)</atitle><jtitle>Crystallography reports</jtitle><date>2010-05-15</date><risdate>2010</risdate><volume>55</volume><issue>3</issue><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.706(1){sup o}, space group P2{sub 1}/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) A, b = 11.5358(3) A, c = 9.5565(2) A, {beta} = 113.273(1){sup o}, space group P2{sub 1}/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO{sub 2}(SeO{sub 4})(OH)]{sup -} layers which belong to the AT{sup 3}M{sup 2} crystal chemical group of uranyl complexes (A = UO{sub 2}{sup 2+}, T{sup 3} = SeO{sub 4}{sup 2-}, and M{sup 2} = OH{sup -}). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands.</abstract><cop>United States</cop><doi>10.1134/S1063774510030041</doi></addata></record> |
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| subjects | CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ISOMERS LAYERS LIGANDS MONOCLINIC LATTICES MONOCRYSTALS SELENATES SPACE GROUPS SULFATE MINERALS SYNTHESIS TOPOLOGY URANIUM MINERALS URANYL COMPLEXES WATER X-RAY DIFFRACTION |
| title | Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1) |
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