Gas-phase photodissociation of CH{sub 3}COCN at 308 nm by time-resolved Fourier-transform infrared emission spectroscopy

By using time-resolved Fourier-transform infrared emission spectroscopy, the fragments of HCN(v= 1, 2) and CO(v= 1-3) are detected in one-photon dissociation of acetyl cyanide (CH{sub 3}COCN) at 308 nm. The S{sub 1}(A'), {sup 1}(n{sub O}, {pi}*{sub CO}) state at 308 nm has a radiative lifetime...

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Veröffentlicht in:	The Journal of chemical physics 2012-01, Vol.136 (4)
Hauptverfasser:	Yeh, Yu-Ying, Chao, Meng-Hsuan, Tsai, Po-Yu, Chang, Yuan-Bin, Tsai, Ming-Tsang, Lin, King-Chuen
Format:	Artikel
Sprache:	eng
Schlagworte:	ATOMIC AND MOLECULAR PHYSICS DISSOCIATION EMISSION SPECTROSCOPY FOURIER TRANSFORMATION GROUND STATES INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERNAL CONVERSION ORGANIC COMPOUNDS PHOTOLYSIS PHOTON-MOLECULE COLLISIONS REACTION KINETICS SECONDARY REACTIONS SIGNAL-TO-NOISE RATIO VIBRATIONAL STATES
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