Surfactant enhanced solid phase epitaxy of Ge/CaF{sub 2}/Si(111): Synchrotron x-ray characterization of structure and morphology

The structure and morphology of CaF{sub 2}/Si(111) and Ge/CaF{sub 2}/Si(111) layered structures with film thicknesses in the range of very few nanometers has been studied with synchrotron-based radiation. While the CaF{sub 2} film is grown via molecular beam epitaxy, the Ge film is fabricated by sur...

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Veröffentlicht in:Journal of applied physics 2011-11, Vol.110 (10)
Hauptverfasser: Wollschlaeger, J., Deiter, C., Wang, C. R., Mueller, B. H., Hofmann, K. R.
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Deiter, C.
Wang, C. R.
Mueller, B. H.
Hofmann, K. R.
description The structure and morphology of CaF{sub 2}/Si(111) and Ge/CaF{sub 2}/Si(111) layered structures with film thicknesses in the range of very few nanometers has been studied with synchrotron-based radiation. While the CaF{sub 2} film is grown via molecular beam epitaxy, the Ge film is fabricated by surfactant enhanced solid phase epitaxy with Sb as surfactant. The CaF{sub 2} film forms two laterally separated phases of relaxed CaF{sub 2} and pseudomorphic CaF{sub 2}, respectively, although the film thickness is very homogeneous. The Ge film is completely relaxed and forms A-oriented parts as well as B-oriented parts, due to twinning. In spite of the large surface roughness of the Ge film, it completely wets CaF{sub 2}/Si(111) also after annealing at 600 deg. C, due to the application of Sb during the annealing process.
doi_str_mv 10.1063/1.3661174
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subjects ANNEALING
ANTIMONY
CALCIUM
CALCIUM FLUORIDES
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
GERMANIUM
INTERFACES
MATERIALS SCIENCE
MOLECULAR BEAM EPITAXY
MOLECULAR STRUCTURE
MORPHOLOGY
REFLECTION
ROUGHNESS
SEMICONDUCTOR MATERIALS
SILICON
SOLIDS
SURFACES
SYNCHROTRON RADIATION
THIN FILMS
TWINNING
X-RAY DIFFRACTION
title Surfactant enhanced solid phase epitaxy of Ge/CaF{sub 2}/Si(111): Synchrotron x-ray characterization of structure and morphology
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