Features of vanadium impurity states in lead telluride

Temperature dependences of resistivity, magnetic susceptibility, and charge-carrier concentration and mobility in single-crystalline PbTe:V samples with a varied impurity content are investigated. It is shown that vanadium forms a donor level located ∼20 meV below the conduction-band bottom. The ele...

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Veröffentlicht in:Semiconductors (Woodbury, N.Y.) N.Y.), 2010-12, Vol.44 (12), p.1543-1547
Hauptverfasser: Artamkin, A. I., Dobrovolsky, A. A., Vinokurov, A. A., Zlomanov, V. P., Gavrilkin, S. Y., Ivanenko, O. M., Mitzen, K. V., Ryabova, L. I., Khokhlov, D. R.
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container_end_page 1547
container_issue 12
container_start_page 1543
container_title Semiconductors (Woodbury, N.Y.)
container_volume 44
creator Artamkin, A. I.
Dobrovolsky, A. A.
Vinokurov, A. A.
Zlomanov, V. P.
Gavrilkin, S. Y.
Ivanenko, O. M.
Mitzen, K. V.
Ryabova, L. I.
Khokhlov, D. R.
description Temperature dependences of resistivity, magnetic susceptibility, and charge-carrier concentration and mobility in single-crystalline PbTe:V samples with a varied impurity content are investigated. It is shown that vanadium forms a donor level located ∼20 meV below the conduction-band bottom. The electron mobility is as high as 10 5 cm 2 V −1 s −1 in the samples with N V ≤ 0.21 at % and proves to be more than an order of magnitude higher in the samples with the highest vanadium content N V = 0.26 at %. In the same samples, the real part of the conductivity is characterized by a pronounced frequency dependence. An increase in vanadium concentration is accompanied by a decrease in the effective magnetic moment of impurity atoms. The features of electron transport in PbTe:V may be caused by a variable vanadium valence and by the effect of interimpurity correlations.
doi_str_mv 10.1134/S106378261012002X
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subjects ATOMS
CHALCOGENIDES
CHARGE CARRIERS
CORRELATIONS
CRYSTALS
Electric properties
Electrical and Optical Properties of Semiconductors
ELECTRON MOBILITY
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
FERMIONS
FREQUENCY DEPENDENCE
IMPURITIES
LEAD COMPOUNDS
LEAD TELLURIDES
LEPTONS
Magnetic Materials
MAGNETIC MOMENTS
MAGNETIC PROPERTIES
MAGNETIC SUSCEPTIBILITY
Magnetism
MATERIALS SCIENCE
METALS
MOBILITY
MONOCRYSTALS
PARTICLE MOBILITY
PHYSICAL PROPERTIES
Physics
Physics and Astronomy
TELLURIDES
TELLURIUM COMPOUNDS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENTS
VANADIUM
title Features of vanadium impurity states in lead telluride
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