Valorisation of forestry waste by pyrolysis in an auger reactor
Pyrolysis of forestry waste has been carried out in an auger reactor to study the influence of operational variables on the reactor performance and the properties of the related products. Pine woodchips were used for the first time as raw material and fed continuously into the reactor. Ten experimen...
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creator | Puy, Neus Murillo, Ramón Navarro, María V. López, José M. Rieradevall, Joan Fowler, G. Aranguren, Ignacio García, Tomás Bartrolí, Jordi Mastral, Ana M. |
description | Pyrolysis of forestry waste has been carried out in an auger reactor to study the influence of operational variables on the reactor performance and the properties of the related products. Pine woodchips were used for the first time as raw material and fed continuously into the reactor. Ten experiments were carried out under inert atmosphere at: (i) different reaction temperature (1073, 973, 873, 823 and 773
K); (ii) different solid residence time (5, 3, 2 and 1.5
min); and (iii) different biomass flow rate (3.9, 4.8 and 6.9
kg/h). Results show that the greatest yields for liquid production (59%) and optimum product characterisation were obtained at the lowest temperature studied (773
K) and applying solid residence times longer than 2
min. Regarding bio-oil properties, GC/MS qualitative identification show that the most abundant compounds are volatile polar compounds, phenols and benzenediols; and very few differences can be observed among the samples regardless of the pyrolysis operating conditions. On the whole, experimental results demonstrate that complete reaction of forest woodchips can be achieved in an auger reactor in most of the experimental conditions tested. Moreover, this study presents the initial steps for the future scaling up of the auger reactor with the aim of converting it into a mobile plant which will be able to remotely process biomass such as energy crops, forestry and agricultural wastes to obtain bio-oil that, in turn, can be used as energy vector to avoid high transport costs. |
doi_str_mv | 10.1016/j.wasman.2011.01.020 |
format | Article |
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K); (ii) different solid residence time (5, 3, 2 and 1.5
min); and (iii) different biomass flow rate (3.9, 4.8 and 6.9
kg/h). Results show that the greatest yields for liquid production (59%) and optimum product characterisation were obtained at the lowest temperature studied (773
K) and applying solid residence times longer than 2
min. Regarding bio-oil properties, GC/MS qualitative identification show that the most abundant compounds are volatile polar compounds, phenols and benzenediols; and very few differences can be observed among the samples regardless of the pyrolysis operating conditions. On the whole, experimental results demonstrate that complete reaction of forest woodchips can be achieved in an auger reactor in most of the experimental conditions tested. Moreover, this study presents the initial steps for the future scaling up of the auger reactor with the aim of converting it into a mobile plant which will be able to remotely process biomass such as energy crops, forestry and agricultural wastes to obtain bio-oil that, in turn, can be used as energy vector to avoid high transport costs.</description><identifier>ISSN: 0956-053X</identifier><identifier>EISSN: 1879-2456</identifier><identifier>DOI: 10.1016/j.wasman.2011.01.020</identifier><identifier>PMID: 21333517</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>09 BIOMASS FUELS ; AGRICULTURAL WASTES ; Agriculture, rearing and food industries wastes ; ALTERNATIVE FUELS ; Applied sciences ; AROMATICS ; ATMOSPHERES ; Augers ; Benzene Derivatives - analysis ; BIOFUELS ; BIOMASS ; CHEMICAL REACTIONS ; CHEMICAL REACTORS ; CHROMATOGRAPHY ; CONIFERS ; CONTROLLED ATMOSPHERES ; COST ; CROPS ; DECOMPOSITION ; Direct power generation ; ENERGY SOURCES ; Energy use ; Exact sciences and technology ; FLOW RATE ; FLUIDS ; Forestry ; FORESTS ; FUELS ; GAS CHROMATOGRAPHY ; Gas Chromatography-Mass Spectrometry ; HYDROXY COMPOUNDS ; Incineration ; INERT ATMOSPHERE ; LIQUIDS ; MASS SPECTROSCOPY ; MATERIALS ; ORGANIC COMPOUNDS ; ORGANIC WASTES ; Other wastes and particular components of wastes ; PHENOL ; PHENOLS ; Phenols - analysis ; PINES ; PINOPHYTA ; PLANTS ; POLAR COMPOUNDS ; Pollution ; PYROLYSIS ; RAW MATERIALS ; Reactors ; Refuse Disposal - instrumentation ; Refuse Disposal - methods ; RENEWABLE ENERGY SOURCES ; SEPARATION PROCESSES ; SOLID WASTES ; SPECTROSCOPY ; Temperature ; THERMOCHEMICAL PROCESSES ; Thermogravimetry ; Time Factors ; TRANSPORT ; TREES ; VOLATILITY ; Waste Products - analysis ; WASTES ; WOOD WASTES</subject><ispartof>Waste management (Elmsford), 2011-06, Vol.31 (6), p.1339-1349</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2011 Elsevier Ltd. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c484t-61494449656dd8890ecb3514c77b18b84debaeaddeb77919cd3064986e53746f3</citedby><cites>FETCH-LOGICAL-c484t-61494449656dd8890ecb3514c77b18b84debaeaddeb77919cd3064986e53746f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0956053X11000523$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24166335$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21333517$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/21550375$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Puy, Neus</creatorcontrib><creatorcontrib>Murillo, Ramón</creatorcontrib><creatorcontrib>Navarro, María V.</creatorcontrib><creatorcontrib>López, José M.</creatorcontrib><creatorcontrib>Rieradevall, Joan</creatorcontrib><creatorcontrib>Fowler, G.</creatorcontrib><creatorcontrib>Aranguren, Ignacio</creatorcontrib><creatorcontrib>García, Tomás</creatorcontrib><creatorcontrib>Bartrolí, Jordi</creatorcontrib><creatorcontrib>Mastral, Ana M.</creatorcontrib><title>Valorisation of forestry waste by pyrolysis in an auger reactor</title><title>Waste management (Elmsford)</title><addtitle>Waste Manag</addtitle><description>Pyrolysis of forestry waste has been carried out in an auger reactor to study the influence of operational variables on the reactor performance and the properties of the related products. Pine woodchips were used for the first time as raw material and fed continuously into the reactor. Ten experiments were carried out under inert atmosphere at: (i) different reaction temperature (1073, 973, 873, 823 and 773
K); (ii) different solid residence time (5, 3, 2 and 1.5
min); and (iii) different biomass flow rate (3.9, 4.8 and 6.9
kg/h). Results show that the greatest yields for liquid production (59%) and optimum product characterisation were obtained at the lowest temperature studied (773
K) and applying solid residence times longer than 2
min. Regarding bio-oil properties, GC/MS qualitative identification show that the most abundant compounds are volatile polar compounds, phenols and benzenediols; and very few differences can be observed among the samples regardless of the pyrolysis operating conditions. On the whole, experimental results demonstrate that complete reaction of forest woodchips can be achieved in an auger reactor in most of the experimental conditions tested. Moreover, this study presents the initial steps for the future scaling up of the auger reactor with the aim of converting it into a mobile plant which will be able to remotely process biomass such as energy crops, forestry and agricultural wastes to obtain bio-oil that, in turn, can be used as energy vector to avoid high transport costs.</description><subject>09 BIOMASS FUELS</subject><subject>AGRICULTURAL WASTES</subject><subject>Agriculture, rearing and food industries wastes</subject><subject>ALTERNATIVE FUELS</subject><subject>Applied sciences</subject><subject>AROMATICS</subject><subject>ATMOSPHERES</subject><subject>Augers</subject><subject>Benzene Derivatives - analysis</subject><subject>BIOFUELS</subject><subject>BIOMASS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMICAL REACTORS</subject><subject>CHROMATOGRAPHY</subject><subject>CONIFERS</subject><subject>CONTROLLED ATMOSPHERES</subject><subject>COST</subject><subject>CROPS</subject><subject>DECOMPOSITION</subject><subject>Direct power generation</subject><subject>ENERGY SOURCES</subject><subject>Energy use</subject><subject>Exact sciences and technology</subject><subject>FLOW RATE</subject><subject>FLUIDS</subject><subject>Forestry</subject><subject>FORESTS</subject><subject>FUELS</subject><subject>GAS CHROMATOGRAPHY</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>HYDROXY COMPOUNDS</subject><subject>Incineration</subject><subject>INERT ATMOSPHERE</subject><subject>LIQUIDS</subject><subject>MASS SPECTROSCOPY</subject><subject>MATERIALS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC WASTES</subject><subject>Other wastes and particular components of wastes</subject><subject>PHENOL</subject><subject>PHENOLS</subject><subject>Phenols - analysis</subject><subject>PINES</subject><subject>PINOPHYTA</subject><subject>PLANTS</subject><subject>POLAR COMPOUNDS</subject><subject>Pollution</subject><subject>PYROLYSIS</subject><subject>RAW MATERIALS</subject><subject>Reactors</subject><subject>Refuse Disposal - instrumentation</subject><subject>Refuse Disposal - methods</subject><subject>RENEWABLE ENERGY SOURCES</subject><subject>SEPARATION PROCESSES</subject><subject>SOLID WASTES</subject><subject>SPECTROSCOPY</subject><subject>Temperature</subject><subject>THERMOCHEMICAL PROCESSES</subject><subject>Thermogravimetry</subject><subject>Time Factors</subject><subject>TRANSPORT</subject><subject>TREES</subject><subject>VOLATILITY</subject><subject>Waste Products - analysis</subject><subject>WASTES</subject><subject>WOOD WASTES</subject><issn>0956-053X</issn><issn>1879-2456</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqN0U2LFDEQBuAgijuu_gORBhG99JjKdy4rsvgFC15UvIV0uloz9HTGpEfpf2-GHvW2CAW5PKlU6iXkMdAtUFAvd9tfvuz9tGUUYEtrMXqHbMBo2zIh1V2yoVaqlkr-9YI8KGVHKQgD9D65YMA5l6A35NUXP6Yci59jmpo0NEPKWOa8NLX7jE23NIclp3EpsTRxanyt4zfMTUYf5pQfknuDHws-Op-X5PPbN5-u37c3H999uH590wZhxNwqEFYIYZVUfW-MpRi6OoAIWndgOiN67Dz6vh5aW7Ch51QJaxRKroUa-CV5uvZNZY6uhDhj-B7SNGGYHQMpKdeyquerOuT041j_4faxBBxHP2E6Fme0qqux7D-kYtpyQW2VL26VoLUGKpmFSsVKQ06lZBzcIce9z4sD6k6huZ1bQ3On0BytxWi99uT8wrHbY__30p-UKnh2Br4EPw7ZTyGWf06AUlVWd7U6rEn8jJhPi8IpYB_zaU99irdP8hvKV7TF</recordid><startdate>20110601</startdate><enddate>20110601</enddate><creator>Puy, Neus</creator><creator>Murillo, Ramón</creator><creator>Navarro, María V.</creator><creator>López, José M.</creator><creator>Rieradevall, Joan</creator><creator>Fowler, G.</creator><creator>Aranguren, Ignacio</creator><creator>García, Tomás</creator><creator>Bartrolí, Jordi</creator><creator>Mastral, Ana M.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SU</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>7X8</scope><scope>7ST</scope><scope>7TV</scope><scope>SOI</scope><scope>OTOTI</scope></search><sort><creationdate>20110601</creationdate><title>Valorisation of forestry waste by pyrolysis in an auger reactor</title><author>Puy, Neus ; Murillo, Ramón ; Navarro, María V. ; López, José M. ; Rieradevall, Joan ; Fowler, G. ; Aranguren, Ignacio ; García, Tomás ; Bartrolí, Jordi ; Mastral, Ana M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c484t-61494449656dd8890ecb3514c77b18b84debaeaddeb77919cd3064986e53746f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>09 BIOMASS FUELS</topic><topic>AGRICULTURAL WASTES</topic><topic>Agriculture, rearing and food industries wastes</topic><topic>ALTERNATIVE FUELS</topic><topic>Applied sciences</topic><topic>AROMATICS</topic><topic>ATMOSPHERES</topic><topic>Augers</topic><topic>Benzene Derivatives - analysis</topic><topic>BIOFUELS</topic><topic>BIOMASS</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMICAL REACTORS</topic><topic>CHROMATOGRAPHY</topic><topic>CONIFERS</topic><topic>CONTROLLED ATMOSPHERES</topic><topic>COST</topic><topic>CROPS</topic><topic>DECOMPOSITION</topic><topic>Direct power generation</topic><topic>ENERGY SOURCES</topic><topic>Energy use</topic><topic>Exact sciences and technology</topic><topic>FLOW RATE</topic><topic>FLUIDS</topic><topic>Forestry</topic><topic>FORESTS</topic><topic>FUELS</topic><topic>GAS CHROMATOGRAPHY</topic><topic>Gas Chromatography-Mass Spectrometry</topic><topic>HYDROXY COMPOUNDS</topic><topic>Incineration</topic><topic>INERT ATMOSPHERE</topic><topic>LIQUIDS</topic><topic>MASS SPECTROSCOPY</topic><topic>MATERIALS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC WASTES</topic><topic>Other wastes and particular components of wastes</topic><topic>PHENOL</topic><topic>PHENOLS</topic><topic>Phenols - analysis</topic><topic>PINES</topic><topic>PINOPHYTA</topic><topic>PLANTS</topic><topic>POLAR COMPOUNDS</topic><topic>Pollution</topic><topic>PYROLYSIS</topic><topic>RAW MATERIALS</topic><topic>Reactors</topic><topic>Refuse Disposal - instrumentation</topic><topic>Refuse Disposal - methods</topic><topic>RENEWABLE ENERGY SOURCES</topic><topic>SEPARATION PROCESSES</topic><topic>SOLID WASTES</topic><topic>SPECTROSCOPY</topic><topic>Temperature</topic><topic>THERMOCHEMICAL PROCESSES</topic><topic>Thermogravimetry</topic><topic>Time Factors</topic><topic>TRANSPORT</topic><topic>TREES</topic><topic>VOLATILITY</topic><topic>Waste Products - analysis</topic><topic>WASTES</topic><topic>WOOD WASTES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Puy, Neus</creatorcontrib><creatorcontrib>Murillo, Ramón</creatorcontrib><creatorcontrib>Navarro, María V.</creatorcontrib><creatorcontrib>López, José M.</creatorcontrib><creatorcontrib>Rieradevall, Joan</creatorcontrib><creatorcontrib>Fowler, G.</creatorcontrib><creatorcontrib>Aranguren, Ignacio</creatorcontrib><creatorcontrib>García, Tomás</creatorcontrib><creatorcontrib>Bartrolí, Jordi</creatorcontrib><creatorcontrib>Mastral, Ana M.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Environment Abstracts</collection><collection>OSTI.GOV</collection><jtitle>Waste management (Elmsford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Puy, Neus</au><au>Murillo, Ramón</au><au>Navarro, María V.</au><au>López, José M.</au><au>Rieradevall, Joan</au><au>Fowler, G.</au><au>Aranguren, Ignacio</au><au>García, Tomás</au><au>Bartrolí, Jordi</au><au>Mastral, Ana M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Valorisation of forestry waste by pyrolysis in an auger reactor</atitle><jtitle>Waste management (Elmsford)</jtitle><addtitle>Waste Manag</addtitle><date>2011-06-01</date><risdate>2011</risdate><volume>31</volume><issue>6</issue><spage>1339</spage><epage>1349</epage><pages>1339-1349</pages><issn>0956-053X</issn><eissn>1879-2456</eissn><abstract>Pyrolysis of forestry waste has been carried out in an auger reactor to study the influence of operational variables on the reactor performance and the properties of the related products. Pine woodchips were used for the first time as raw material and fed continuously into the reactor. Ten experiments were carried out under inert atmosphere at: (i) different reaction temperature (1073, 973, 873, 823 and 773
K); (ii) different solid residence time (5, 3, 2 and 1.5
min); and (iii) different biomass flow rate (3.9, 4.8 and 6.9
kg/h). Results show that the greatest yields for liquid production (59%) and optimum product characterisation were obtained at the lowest temperature studied (773
K) and applying solid residence times longer than 2
min. Regarding bio-oil properties, GC/MS qualitative identification show that the most abundant compounds are volatile polar compounds, phenols and benzenediols; and very few differences can be observed among the samples regardless of the pyrolysis operating conditions. On the whole, experimental results demonstrate that complete reaction of forest woodchips can be achieved in an auger reactor in most of the experimental conditions tested. Moreover, this study presents the initial steps for the future scaling up of the auger reactor with the aim of converting it into a mobile plant which will be able to remotely process biomass such as energy crops, forestry and agricultural wastes to obtain bio-oil that, in turn, can be used as energy vector to avoid high transport costs.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>21333517</pmid><doi>10.1016/j.wasman.2011.01.020</doi><tpages>11</tpages></addata></record> |
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subjects | 09 BIOMASS FUELS AGRICULTURAL WASTES Agriculture, rearing and food industries wastes ALTERNATIVE FUELS Applied sciences AROMATICS ATMOSPHERES Augers Benzene Derivatives - analysis BIOFUELS BIOMASS CHEMICAL REACTIONS CHEMICAL REACTORS CHROMATOGRAPHY CONIFERS CONTROLLED ATMOSPHERES COST CROPS DECOMPOSITION Direct power generation ENERGY SOURCES Energy use Exact sciences and technology FLOW RATE FLUIDS Forestry FORESTS FUELS GAS CHROMATOGRAPHY Gas Chromatography-Mass Spectrometry HYDROXY COMPOUNDS Incineration INERT ATMOSPHERE LIQUIDS MASS SPECTROSCOPY MATERIALS ORGANIC COMPOUNDS ORGANIC WASTES Other wastes and particular components of wastes PHENOL PHENOLS Phenols - analysis PINES PINOPHYTA PLANTS POLAR COMPOUNDS Pollution PYROLYSIS RAW MATERIALS Reactors Refuse Disposal - instrumentation Refuse Disposal - methods RENEWABLE ENERGY SOURCES SEPARATION PROCESSES SOLID WASTES SPECTROSCOPY Temperature THERMOCHEMICAL PROCESSES Thermogravimetry Time Factors TRANSPORT TREES VOLATILITY Waste Products - analysis WASTES WOOD WASTES |
title | Valorisation of forestry waste by pyrolysis in an auger reactor |
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