Atomic-scale structural evolution and stability of supercooled liquid of a Zr-based bulk metallic glass

In this Letter, direct experimental evidence is provided for understanding the thermal stability with respect to crystallization in the Zr(41.2)Ti(13.8)Cu(12.5)Ni(10)Be(22.5) glass-forming liquid. Through high-resolution transmission electron microscopy, the atomic-structure evolution in the glass-forming liquid during the isothermal annealing process is clearly revealed. In contrast with the existing theoretical models, our results reveal that, prior to nanocrystallization, there exists a metastable state prone to forming icosahedralike atomic clusters, which impede the subsequent crystallization and hence stabilize the supercooled liquid. The outcome of the current research underpins the topological origin for the excellent thermal stability displayed by the Zr-based bulk metallic glass.