Interfacial energy level bending in a crystalline p/p-type organic heterostructure

A conduction channel was observed at the heterointerface of the crystalline p-type organic films copper phthalocyanine (CuPc) and 2,5-bis(4-biphenylyl) bithiophene (BP2T). Energy level bending at the interface is confirmed by photoemission spectroscopy, which verifies a charge transfer between CuPc...

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Veröffentlicht in:Applied physics letters 2011-05, Vol.98 (20), p.203303-203303-3
Hauptverfasser: Zhu, Feng, Grobosch, Mandy, Treske, Uwe, Knupfer, Martin, Huang, Lizhen, Ji, Shiliang, Yan, Donghang
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container_end_page 203303-3
container_issue 20
container_start_page 203303
container_title Applied physics letters
container_volume 98
creator Zhu, Feng
Grobosch, Mandy
Treske, Uwe
Knupfer, Martin
Huang, Lizhen
Ji, Shiliang
Yan, Donghang
description A conduction channel was observed at the heterointerface of the crystalline p-type organic films copper phthalocyanine (CuPc) and 2,5-bis(4-biphenylyl) bithiophene (BP2T). Energy level bending at the interface is confirmed by photoemission spectroscopy, which verifies a charge transfer between CuPc and BP2T. This provides a further route to utilize interfacial electronic properties in functional devices and also documents the importance of reconsidering the interfacial electronic structure of organic heterostructures.
doi_str_mv 10.1063/1.3592994
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subjects BENDING
CHARGE EXCHANGE
COMPLEXES
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
COPPER COMPLEXES
DEFORMATION
DYES
ELECTRONIC STRUCTURE
EMISSION
ENERGY
ENERGY LEVELS
FREE ENERGY
HETEROCYCLIC COMPOUNDS
HETEROJUNCTIONS
INTERFACES
MATERIALS
MATERIALS SCIENCE
ORGANIC COMPOUNDS
ORGANIC SEMICONDUCTORS
PHOTOEMISSION
PHTHALOCYANINES
PHYSICAL PROPERTIES
SECONDARY EMISSION
SEMICONDUCTOR JUNCTIONS
SEMICONDUCTOR MATERIALS
SPECTROSCOPY
SURFACE ENERGY
SURFACE PROPERTIES
THERMODYNAMIC PROPERTIES
THIN FILMS
TRANSITION ELEMENT COMPLEXES
title Interfacial energy level bending in a crystalline p/p-type organic heterostructure
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