Preparation, crystal structures and rapid hydration of P2- and P3-type sodium chromium antimony oxides

Two new Na x [Cr (1+ x)/2 Sb (1− x)/2 ]O 2 compounds have been prepared by solid-state reactions in argon. Their structures have been determined by the X-ray Rietveld method. Both new phases together with NaCrO 2-based solid solution comprise brucite-like layers of edge-shared (Cr,Sb)O 6 octahedra b...

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Veröffentlicht in:	Journal of solid state chemistry 2011-05, Vol.184 (5), p.1043-1047
Hauptverfasser:	Pospelov, A.A., Nalbandyan, V.B.
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKALI METAL COMPOUNDS Antimonate ANTIMONY COMPOUNDS ANTIMONY OXIDES ARGON CHALCOGENIDES CHARGED PARTICLES Chromite CHROMITES Chromium CHROMIUM COMPOUNDS CRYSTAL LATTICES CRYSTAL STRUCTURE DISPERSIONS ELECTROLYTES ELECTROMAGNETIC RADIATION ELEMENTS FLUIDS GASES HCP LATTICES HEXAGONAL LATTICES HOMOGENEOUS MIXTURES HYDRATES HYDRATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IONIZING RADIATIONS IONS Layered structure LAYERS MIXTURES NONMETALS OXIDES OXYGEN COMPOUNDS Phases Prismatic coordination Prisms RADIATIONS RARE GASES Rietveld method Sodium SODIUM COMPOUNDS SODIUM IONS Solid electrolyte SOLID ELECTROLYTES SOLID SOLUTIONS SOLUTIONS SOLVATION TRANSITION ELEMENT COMPOUNDS TRIGONAL LATTICES X RADIATION
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