Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O
The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){...
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| Veröffentlicht in: | Journal of solid state chemistry 2010-06, Vol.183 (6) |
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| container_title | Journal of solid state chemistry |
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| creator | Eda, Kazuo Kato, Yasuyuki Ohshiro, Yu Sugitani, Takamitu Whittingham, M. Stanley |
| description | The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){sup o}. Its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. Under hydrothermal conditions the hydrate turned directly into {alpha}-NiMoO{sub 4} above 483 K, giving nanorods thinner than the crystallites of the mother hydrate. On the other hand, it turned into Anderson type of polyoxomolybdate via a solid-solution process in a molybdate solution at room temperature. - Graphical abstract: NiMoO{sub 4}.nH{sub 2}O crystallized in the triclinic system with space group P-1, and its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. |
| doi_str_mv | 10.1016/j.jssc.2010.04.009 |
| format | Article |
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Stanley</creator><creatorcontrib>Eda, Kazuo ; Kato, Yasuyuki ; Ohshiro, Yu ; Sugitani, Takamitu ; Whittingham, M. Stanley</creatorcontrib><description>The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){sup o}. Its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. Under hydrothermal conditions the hydrate turned directly into {alpha}-NiMoO{sub 4} above 483 K, giving nanorods thinner than the crystallites of the mother hydrate. On the other hand, it turned into Anderson type of polyoxomolybdate via a solid-solution process in a molybdate solution at room temperature. - Graphical abstract: NiMoO{sub 4}.nH{sub 2}O crystallized in the triclinic system with space group P-1, and its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2010.04.009</identifier><language>eng</language><publisher>United States</publisher><subject>CHEMICAL COMPOSITION ; CRYSTAL LATTICES ; CRYSTAL STRUCTURE ; DISPERSIONS ; HOMOGENEOUS MIXTURES ; HYDRATES ; HYDROTHERMAL SYNTHESIS ; MIXTURES ; MOLYBDATES ; MOLYBDENUM COMPOUNDS ; NANOSCIENCE AND NANOTECHNOLOGY ; NANOSTRUCTURES ; OXYGEN COMPOUNDS ; REFRACTORY METAL COMPOUNDS ; SOLID SOLUTIONS ; SOLUTIONS ; SPACE GROUPS ; SYMMETRY GROUPS ; SYNTHESIS ; TEMPERATURE RANGE ; TEMPERATURE RANGE 0273-0400 K ; TEMPERATURE RANGE 0400-1000 K ; TRANSITION ELEMENT COMPOUNDS ; TRICLINIC LATTICES</subject><ispartof>Journal of solid state chemistry, 2010-06, Vol.183 (6)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/21421519$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Eda, Kazuo</creatorcontrib><creatorcontrib>Kato, Yasuyuki</creatorcontrib><creatorcontrib>Ohshiro, Yu</creatorcontrib><creatorcontrib>Sugitani, Takamitu</creatorcontrib><creatorcontrib>Whittingham, M. Stanley</creatorcontrib><title>Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O</title><title>Journal of solid state chemistry</title><description>The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){sup o}. Its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. Under hydrothermal conditions the hydrate turned directly into {alpha}-NiMoO{sub 4} above 483 K, giving nanorods thinner than the crystallites of the mother hydrate. On the other hand, it turned into Anderson type of polyoxomolybdate via a solid-solution process in a molybdate solution at room temperature. - Graphical abstract: NiMoO{sub 4}.nH{sub 2}O crystallized in the triclinic system with space group P-1, and its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O.</description><subject>CHEMICAL COMPOSITION</subject><subject>CRYSTAL LATTICES</subject><subject>CRYSTAL STRUCTURE</subject><subject>DISPERSIONS</subject><subject>HOMOGENEOUS MIXTURES</subject><subject>HYDRATES</subject><subject>HYDROTHERMAL SYNTHESIS</subject><subject>MIXTURES</subject><subject>MOLYBDATES</subject><subject>MOLYBDENUM COMPOUNDS</subject><subject>NANOSCIENCE AND NANOTECHNOLOGY</subject><subject>NANOSTRUCTURES</subject><subject>OXYGEN COMPOUNDS</subject><subject>REFRACTORY METAL COMPOUNDS</subject><subject>SOLID SOLUTIONS</subject><subject>SOLUTIONS</subject><subject>SPACE GROUPS</subject><subject>SYMMETRY GROUPS</subject><subject>SYNTHESIS</subject><subject>TEMPERATURE RANGE</subject><subject>TEMPERATURE RANGE 0273-0400 K</subject><subject>TEMPERATURE RANGE 0400-1000 K</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>TRICLINIC LATTICES</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqNjE9rwjAYxsOYsE73BXYK7Gqz941pteeheFEP8-BNahrXlC6BvOmgDL_7qoydd_o9_3gYe0YQCJi_NqIh0kLCEIASAMUdSxCKLJ3L_HDPEgApU5UV-QN7JGoAELOFStjHe-9ibcjSlOvQUyxbTjF0OnbBTHnpqj87NNq7LxPIesf9mW8t__Rtf6rKaHjdV-HKrd343Td1J64uwq1vSl52EzY6ly2Zp1-O2ctquX9bp56iPZK20eh6uHdGx6NEJTHDYva_1Q-tBU-y</recordid><startdate>20100615</startdate><enddate>20100615</enddate><creator>Eda, Kazuo</creator><creator>Kato, Yasuyuki</creator><creator>Ohshiro, Yu</creator><creator>Sugitani, Takamitu</creator><creator>Whittingham, M. Stanley</creator><scope>OTOTI</scope></search><sort><creationdate>20100615</creationdate><title>Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O</title><author>Eda, Kazuo ; Kato, Yasuyuki ; Ohshiro, Yu ; Sugitani, Takamitu ; Whittingham, M. 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Stanley</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eda, Kazuo</au><au>Kato, Yasuyuki</au><au>Ohshiro, Yu</au><au>Sugitani, Takamitu</au><au>Whittingham, M. Stanley</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2010-06-15</date><risdate>2010</risdate><volume>183</volume><issue>6</issue><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>The synthesis and crystal structure of NiMoO{sub 4}.nH{sub 2}O were investigated. The hydrate crystallized in the triclinic system with space group P-1, Z=4 with unit cell parameters of a=6.7791(2) A, b=6.8900(2) A, c=9.2486(2) A, {alpha}=76.681(2){sup o}, {beta}=83.960(2){sup o}, {gamma}=74.218(2){sup o}. Its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O. Under hydrothermal conditions the hydrate turned directly into {alpha}-NiMoO{sub 4} above 483 K, giving nanorods thinner than the crystallites of the mother hydrate. On the other hand, it turned into Anderson type of polyoxomolybdate via a solid-solution process in a molybdate solution at room temperature. - Graphical abstract: NiMoO{sub 4}.nH{sub 2}O crystallized in the triclinic system with space group P-1, and its ideal chemical composition was NiMoO{sub 4}.3/4H{sub 2}O rather than NiMoO{sub 4}.1H{sub 2}O.</abstract><cop>United States</cop><doi>10.1016/j.jssc.2010.04.009</doi></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | CHEMICAL COMPOSITION CRYSTAL LATTICES CRYSTAL STRUCTURE DISPERSIONS HOMOGENEOUS MIXTURES HYDRATES HYDROTHERMAL SYNTHESIS MIXTURES MOLYBDATES MOLYBDENUM COMPOUNDS NANOSCIENCE AND NANOTECHNOLOGY NANOSTRUCTURES OXYGEN COMPOUNDS REFRACTORY METAL COMPOUNDS SOLID SOLUTIONS SOLUTIONS SPACE GROUPS SYMMETRY GROUPS SYNTHESIS TEMPERATURE RANGE TEMPERATURE RANGE 0273-0400 K TEMPERATURE RANGE 0400-1000 K TRANSITION ELEMENT COMPOUNDS TRICLINIC LATTICES |
| title | Synthesis, crystal structure, and structural conversion of Ni molybdate hydrate NiMoO{sub 4}.nH{sub 2}O |
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