Lanthanide oxalatophosphonates with two- and three-dimensional structures

Reactions of lanthanide nitrate, oxalate sodium and 2-pyridylmethylphosphonic acid (2-pmpH 2) under hydrothermal conditions result in five new lanthanide oxalatophosphonates with two types of structures. Compounds [ Ln 4(ox) 5(2-pmpH) 2(H 2O) 7]·5H 2O [ Ln 3+=Gd ( 1), Tb ( 2), Dy ( 3); ox 2−=C 2O 4...

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Veröffentlicht in:	Journal of solid state chemistry 2010-05, Vol.183 (5), p.1159-1164
Hauptverfasser:	Yang, Ting-Hai, Cao, Deng-Ke, Li, Yi-Zhi, Zheng, Li-Min
Format:	Artikel
Sprache:	eng
Schlagworte:	2-pyridylmethylphosphonic acid CARBOXYLIC ACID SALTS Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE Double layer Dysprosium DYSPROSIUM COMPOUNDS EMISSION Exact sciences and technology GADOLINIUM COMPOUNDS Lanthanide oxalatophosphonate Lanthanides LAYERS LUMINESCENCE MAGNETIC PROPERTIES Magnetic property MATERIALS SCIENCE NITRATES NITROGEN COMPOUNDS Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC PHOSPHORUS COMPOUNDS OXALATES OXYGEN COMPOUNDS PHOSPHONIC ACIDS PHOTON EMISSION PHYSICAL PROPERTIES Physics RARE EARTH COMPOUNDS Sodium Solid state Structure of solids and liquids crystallography Structure of specific crystalline solids TERBIUM COMPOUNDS
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