Hydrothermal syntheses, crystal structures and properties of 0-D, 1-D and 2-D organic-inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [alpha-BW{sub 12}O{sub 40}]{sup 5-} and transition-metal complexes

Three novel organic-inorganic hybrid borotungstates {l_brace}[Ni(phen){sub 2}(H{sub 2}O)]{sub 2}H(alpha-BW{sub 12}O{sub 40}){r_brace}.4H{sub 2}O (1), [Cu{sup I}(2,2'-bipy)(4,4'-bipy){sub 0.5}]{sub 2}{l_brace}[Cu{sup I}(2,2'-bipy)]{sub 2}Cu{sup I}(4,4'-bipy){sub 2} (alpha-BW{sub 1...

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