Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene
Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN 3, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L) 2(H 2O) 2]·3H 2O ( 1), [Cd 3(L) 5(OH)] ( 2) and [Ag 2(L) 2] ( 3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analys...
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| creator | Su, Zhi Xu, Jing Huang, Yong-Qing Okamura, Taka-aki Liu, Guang-Xiang Bai, Zheng-Shuai Chen, Man-Sheng Chen, Shui-Sheng Sun, Wei-Yin |
| description | Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN
3, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L)
2(H
2O)
2]·3H
2O (
1), [Cd
3(L)
5(OH)] (
2) and [Ag
2(L)
2] (
3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analysis revealed that
1 has 1D hinged-chain structure containing 24-membered ring with a Cd···Cd intra-chain distance of 13.18
Å, while
2 is 1D ladder-like chain with Cd
3O core. However, the complex
3 is a 3D 4-connected framework with Schläfli symbol of (4
2·6
3·8)(4
3·6
2·8). The L
− ligand was found to show four different coordination modes in
1–
3, as 2-, 3- and 4-connector, respectively. The results indicate that the coordination modes of the ligand and metal centers with different coordination geometry have great influence on the structures of the complexes. In addition, the photoluminescence of the complexes were studied in the solid state at room temperature.
Three novel coordination polymers were obtained with in situ ligand formation through Sharpless's [3+2] reaction. The structure and luminescence properties of the complexes were investigated. |
| doi_str_mv | 10.1016/j.jssc.2009.03.010 |
| format | Article |
| fullrecord | <record><control><sourceid>elsevier_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_21370429</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022459609001200</els_id><sourcerecordid>S0022459609001200</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-d23e6e47900225314a6814e30a9929608f6cd50467c556668c9fbda2fa63a1503</originalsourceid><addsrcrecordid>eNp9kcGKFDEQhhtRcFx9AU8NIszCpq2kO5kOeFkWVwcWPKjgLWTT1U6GdDIk6dHZ1_FF7eyIR0-hUt__VxV_Vb2m0FCg4t2-2adkGgYgG2gboPCkWlGQnGyY-P60WgEwRjouxfPqRUp7AEp5362q319OPu8w2XRVpxxnk-eItfZDPbo5REwGvcE6jLUPR3S10cNk52m93V4-Usm6I8b1UpkwHRz-wlT_tHlXW7_08lw7--PRLcRJZxt8saJkzUnGHPVDcCd3STqytpMdSkkoObkJ8275v0f_gB5fVs9G7RK--vteVN9uP3y9-UTuPn_c3lzfEdPyPpOBtSiw28hyK29pp0VPO2xBS8mkgH4UZuDQiY3hXAjRGzneD5qNWrSacmgvqjdn35CyVcnYjGZngvdosmK03UDH5EKxM2ViSCniqA7RTjqeFAVVwlB7VcJQJQwFrVrCWERvz6KDTka7MWpvbPqnZFTQTlK6cO_PHC53Hi3GskZJYLCxbDEE-78xfwCriaBo</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene</title><source>Elsevier ScienceDirect Journals</source><creator>Su, Zhi ; Xu, Jing ; Huang, Yong-Qing ; Okamura, Taka-aki ; Liu, Guang-Xiang ; Bai, Zheng-Shuai ; Chen, Man-Sheng ; Chen, Shui-Sheng ; Sun, Wei-Yin</creator><creatorcontrib>Su, Zhi ; Xu, Jing ; Huang, Yong-Qing ; Okamura, Taka-aki ; Liu, Guang-Xiang ; Bai, Zheng-Shuai ; Chen, Man-Sheng ; Chen, Shui-Sheng ; Sun, Wei-Yin</creatorcontrib><description>Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN
3, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L)
2(H
2O)
2]·3H
2O (
1), [Cd
3(L)
5(OH)] (
2) and [Ag
2(L)
2] (
3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analysis revealed that
1 has 1D hinged-chain structure containing 24-membered ring with a Cd···Cd intra-chain distance of 13.18
Å, while
2 is 1D ladder-like chain with Cd
3O core. However, the complex
3 is a 3D 4-connected framework with Schläfli symbol of (4
2·6
3·8)(4
3·6
2·8). The L
− ligand was found to show four different coordination modes in
1–
3, as 2-, 3- and 4-connector, respectively. The results indicate that the coordination modes of the ligand and metal centers with different coordination geometry have great influence on the structures of the complexes. In addition, the photoluminescence of the complexes were studied in the solid state at room temperature.
Three novel coordination polymers were obtained with in situ ligand formation through Sharpless's [3+2] reaction. The structure and luminescence properties of the complexes were investigated.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2009.03.010</identifier><identifier>CODEN: JSSCBI</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>AROMATICS ; AZIDES ; CADMIUM COMPLEXES ; Cadmium(II) complex ; COMPLEXES ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; CRYSTAL STRUCTURE ; EMISSION ; Exact sciences and technology ; FLUORESCENCE ; HYDROCARBONS ; HYDROTHERMAL SYNTHESIS ; In situ ligand synthesis ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; LUMINESCENCE ; Materials science ; NITROGEN COMPOUNDS ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; ORGANIC COMPOUNDS ; Other materials ; PHOTOLUMINESCENCE ; PHOTON EMISSION ; Physics ; POLYMERS ; SILVER COMPLEXES ; Silver(I) complex ; Solid organic materials ; Specific materials ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; SYNTHESIS ; TEMPERATURE RANGE ; TEMPERATURE RANGE 0273-0400 K ; Tetrazole ; TRANSITION ELEMENT COMPLEXES</subject><ispartof>Journal of solid state chemistry, 2009-06, Vol.182 (6), p.1417-1423</ispartof><rights>2009 Elsevier Inc.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-d23e6e47900225314a6814e30a9929608f6cd50467c556668c9fbda2fa63a1503</citedby><cites>FETCH-LOGICAL-c358t-d23e6e47900225314a6814e30a9929608f6cd50467c556668c9fbda2fa63a1503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2009.03.010$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,778,782,883,3539,27907,27908,45978</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21614911$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/21370429$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Su, Zhi</creatorcontrib><creatorcontrib>Xu, Jing</creatorcontrib><creatorcontrib>Huang, Yong-Qing</creatorcontrib><creatorcontrib>Okamura, Taka-aki</creatorcontrib><creatorcontrib>Liu, Guang-Xiang</creatorcontrib><creatorcontrib>Bai, Zheng-Shuai</creatorcontrib><creatorcontrib>Chen, Man-Sheng</creatorcontrib><creatorcontrib>Chen, Shui-Sheng</creatorcontrib><creatorcontrib>Sun, Wei-Yin</creatorcontrib><title>Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene</title><title>Journal of solid state chemistry</title><description>Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN
3, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L)
2(H
2O)
2]·3H
2O (
1), [Cd
3(L)
5(OH)] (
2) and [Ag
2(L)
2] (
3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analysis revealed that
1 has 1D hinged-chain structure containing 24-membered ring with a Cd···Cd intra-chain distance of 13.18
Å, while
2 is 1D ladder-like chain with Cd
3O core. However, the complex
3 is a 3D 4-connected framework with Schläfli symbol of (4
2·6
3·8)(4
3·6
2·8). The L
− ligand was found to show four different coordination modes in
1–
3, as 2-, 3- and 4-connector, respectively. The results indicate that the coordination modes of the ligand and metal centers with different coordination geometry have great influence on the structures of the complexes. In addition, the photoluminescence of the complexes were studied in the solid state at room temperature.
Three novel coordination polymers were obtained with in situ ligand formation through Sharpless's [3+2] reaction. The structure and luminescence properties of the complexes were investigated.</description><subject>AROMATICS</subject><subject>AZIDES</subject><subject>CADMIUM COMPLEXES</subject><subject>Cadmium(II) complex</subject><subject>COMPLEXES</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>CRYSTAL STRUCTURE</subject><subject>EMISSION</subject><subject>Exact sciences and technology</subject><subject>FLUORESCENCE</subject><subject>HYDROCARBONS</subject><subject>HYDROTHERMAL SYNTHESIS</subject><subject>In situ ligand synthesis</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LUMINESCENCE</subject><subject>Materials science</subject><subject>NITROGEN COMPOUNDS</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>ORGANIC COMPOUNDS</subject><subject>Other materials</subject><subject>PHOTOLUMINESCENCE</subject><subject>PHOTON EMISSION</subject><subject>Physics</subject><subject>POLYMERS</subject><subject>SILVER COMPLEXES</subject><subject>Silver(I) complex</subject><subject>Solid organic materials</subject><subject>Specific materials</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>SYNTHESIS</subject><subject>TEMPERATURE RANGE</subject><subject>TEMPERATURE RANGE 0273-0400 K</subject><subject>Tetrazole</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kcGKFDEQhhtRcFx9AU8NIszCpq2kO5kOeFkWVwcWPKjgLWTT1U6GdDIk6dHZ1_FF7eyIR0-hUt__VxV_Vb2m0FCg4t2-2adkGgYgG2gboPCkWlGQnGyY-P60WgEwRjouxfPqRUp7AEp5362q319OPu8w2XRVpxxnk-eItfZDPbo5REwGvcE6jLUPR3S10cNk52m93V4-Usm6I8b1UpkwHRz-wlT_tHlXW7_08lw7--PRLcRJZxt8saJkzUnGHPVDcCd3STqytpMdSkkoObkJ8275v0f_gB5fVs9G7RK--vteVN9uP3y9-UTuPn_c3lzfEdPyPpOBtSiw28hyK29pp0VPO2xBS8mkgH4UZuDQiY3hXAjRGzneD5qNWrSacmgvqjdn35CyVcnYjGZngvdosmK03UDH5EKxM2ViSCniqA7RTjqeFAVVwlB7VcJQJQwFrVrCWERvz6KDTka7MWpvbPqnZFTQTlK6cO_PHC53Hi3GskZJYLCxbDEE-78xfwCriaBo</recordid><startdate>20090601</startdate><enddate>20090601</enddate><creator>Su, Zhi</creator><creator>Xu, Jing</creator><creator>Huang, Yong-Qing</creator><creator>Okamura, Taka-aki</creator><creator>Liu, Guang-Xiang</creator><creator>Bai, Zheng-Shuai</creator><creator>Chen, Man-Sheng</creator><creator>Chen, Shui-Sheng</creator><creator>Sun, Wei-Yin</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20090601</creationdate><title>Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene</title><author>Su, Zhi ; Xu, Jing ; Huang, Yong-Qing ; Okamura, Taka-aki ; Liu, Guang-Xiang ; Bai, Zheng-Shuai ; Chen, Man-Sheng ; Chen, Shui-Sheng ; Sun, Wei-Yin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-d23e6e47900225314a6814e30a9929608f6cd50467c556668c9fbda2fa63a1503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>AROMATICS</topic><topic>AZIDES</topic><topic>CADMIUM COMPLEXES</topic><topic>Cadmium(II) complex</topic><topic>COMPLEXES</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>CRYSTAL STRUCTURE</topic><topic>EMISSION</topic><topic>Exact sciences and technology</topic><topic>FLUORESCENCE</topic><topic>HYDROCARBONS</topic><topic>HYDROTHERMAL SYNTHESIS</topic><topic>In situ ligand synthesis</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LUMINESCENCE</topic><topic>Materials science</topic><topic>NITROGEN COMPOUNDS</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>ORGANIC COMPOUNDS</topic><topic>Other materials</topic><topic>PHOTOLUMINESCENCE</topic><topic>PHOTON EMISSION</topic><topic>Physics</topic><topic>POLYMERS</topic><topic>SILVER COMPLEXES</topic><topic>Silver(I) complex</topic><topic>Solid organic materials</topic><topic>Specific materials</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>SYNTHESIS</topic><topic>TEMPERATURE RANGE</topic><topic>TEMPERATURE RANGE 0273-0400 K</topic><topic>Tetrazole</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Su, Zhi</creatorcontrib><creatorcontrib>Xu, Jing</creatorcontrib><creatorcontrib>Huang, Yong-Qing</creatorcontrib><creatorcontrib>Okamura, Taka-aki</creatorcontrib><creatorcontrib>Liu, Guang-Xiang</creatorcontrib><creatorcontrib>Bai, Zheng-Shuai</creatorcontrib><creatorcontrib>Chen, Man-Sheng</creatorcontrib><creatorcontrib>Chen, Shui-Sheng</creatorcontrib><creatorcontrib>Sun, Wei-Yin</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Su, Zhi</au><au>Xu, Jing</au><au>Huang, Yong-Qing</au><au>Okamura, Taka-aki</au><au>Liu, Guang-Xiang</au><au>Bai, Zheng-Shuai</au><au>Chen, Man-Sheng</au><au>Chen, Shui-Sheng</au><au>Sun, Wei-Yin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2009-06-01</date><risdate>2009</risdate><volume>182</volume><issue>6</issue><spage>1417</spage><epage>1423</epage><pages>1417-1423</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><coden>JSSCBI</coden><abstract>Hydrothermal reactions of cadmium(II) or silver(I) salt, NaN
3, 4-(imidazol-1-ylmethyl)benzonitrile (IBN) yield three coordination complexes, [Cd(L)
2(H
2O)
2]·3H
2O (
1), [Cd
3(L)
5(OH)] (
2) and [Ag
2(L)
2] (
3) where HL=1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene. The crystal structure analysis revealed that
1 has 1D hinged-chain structure containing 24-membered ring with a Cd···Cd intra-chain distance of 13.18
Å, while
2 is 1D ladder-like chain with Cd
3O core. However, the complex
3 is a 3D 4-connected framework with Schläfli symbol of (4
2·6
3·8)(4
3·6
2·8). The L
− ligand was found to show four different coordination modes in
1–
3, as 2-, 3- and 4-connector, respectively. The results indicate that the coordination modes of the ligand and metal centers with different coordination geometry have great influence on the structures of the complexes. In addition, the photoluminescence of the complexes were studied in the solid state at room temperature.
Three novel coordination polymers were obtained with in situ ligand formation through Sharpless's [3+2] reaction. The structure and luminescence properties of the complexes were investigated.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2009.03.010</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4596 |
| ispartof | Journal of solid state chemistry, 2009-06, Vol.182 (6), p.1417-1423 |
| issn | 0022-4596 1095-726X |
| language | eng |
| recordid | cdi_osti_scitechconnect_21370429 |
| source | Elsevier ScienceDirect Journals |
| subjects | AROMATICS AZIDES CADMIUM COMPLEXES Cadmium(II) complex COMPLEXES Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology CRYSTAL STRUCTURE EMISSION Exact sciences and technology FLUORESCENCE HYDROCARBONS HYDROTHERMAL SYNTHESIS In situ ligand synthesis INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LUMINESCENCE Materials science NITROGEN COMPOUNDS Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ORGANIC COMPOUNDS Other materials PHOTOLUMINESCENCE PHOTON EMISSION Physics POLYMERS SILVER COMPLEXES Silver(I) complex Solid organic materials Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TEMPERATURE RANGE TEMPERATURE RANGE 0273-0400 K Tetrazole TRANSITION ELEMENT COMPLEXES |
| title | Synthesis, structure and fluorescence of novel cadmium(II) and silver(I) complexes with in situ ligand formation of 1-(5-tetrazolyl)-4-(imidazol-1-ylmethyl)benzene |
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