Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition
Fe x Cu 100 − x metastable alloys were prepared by pulsed electrodeposition for 5 < x < 85 . The Fe-rich alloys crystallize in the bcc structure of α -Fe and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys ( x > 50 ) are reminiscent o...
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Veröffentlicht in: | Journal of applied physics 2009-11, Vol.106 (9), p.093907-093907-6 |
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container_title | Journal of applied physics |
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creator | Noce, R. D. Gomes, O. D. M. de Magalhães, S. D. Wolf, W. Guimarães, R. B. de Castro, A. C. Pires, M. J. M. Macedo, W. A. A. Givord, D. Barthem, V. M. T. S. |
description | Fe
x
Cu
100
−
x
metastable alloys were prepared by pulsed electrodeposition for
5
<
x
<
85
. The Fe-rich alloys crystallize in the bcc structure of
α
-Fe
and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys
(
x
>
50
)
are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys
(
x
≤
30
)
, the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the
x
=
10
alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances. |
doi_str_mv | 10.1063/1.3253725 |
format | Article |
fullrecord | <record><control><sourceid>hal_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_21361909</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_00439601v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c411t-d3fdd64fb99b3d82afcb149ead3f33602e8ccee7e43b56a28739f475e3b8d4433</originalsourceid><addsrcrecordid>eNp1kD1PwzAQhi0EEqUw8A8iMTGk-HLOhweGqqItUhELzJbjXKhRiCM7Req_J1ELnZjudO9zXy9jt8BnwDN8gBkmKeZJesYmwAsZ52nKz9mE8wTiQubykl2F8Mk5QIFywtYv-qOl3pqo864j31sKkaujJcWLXaSbxu3DIFGnPVVRuY-6XROGjBoyvXcVdS7Y3rr2ml3UepBujnHK3pdPb4t1vHldPS_mm9gIgD6usK6qTNSllCVWRaJrU4KQpAcBMeMJFcYQ5SSwTDOdFDnKWuQpYVlUQiBO2d1hrgu9VcHYnszWuLYd7lEJYAaSy4G6P1Bb3ajO2y_t98ppq9bzjRprnAuUGYdvOLHGuxA81X8NwNVoqgJ1NHVgHw_suFiPf_8P_zqrTs7iD8vWfeI</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition</title><source>AIP Journals Complete</source><source>AIP Digital Archive</source><source>Alma/SFX Local Collection</source><creator>Noce, R. D. ; Gomes, O. D. M. ; de Magalhães, S. D. ; Wolf, W. ; Guimarães, R. B. ; de Castro, A. C. ; Pires, M. J. M. ; Macedo, W. A. A. ; Givord, D. ; Barthem, V. M. T. S.</creator><creatorcontrib>Noce, R. D. ; Gomes, O. D. M. ; de Magalhães, S. D. ; Wolf, W. ; Guimarães, R. B. ; de Castro, A. C. ; Pires, M. J. M. ; Macedo, W. A. A. ; Givord, D. ; Barthem, V. M. T. S.</creatorcontrib><description>Fe
x
Cu
100
−
x
metastable alloys were prepared by pulsed electrodeposition for
5
<
x
<
85
. The Fe-rich alloys crystallize in the bcc structure of
α
-Fe
and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys
(
x
>
50
)
are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys
(
x
≤
30
)
, the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the
x
=
10
alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.3253725</identifier><identifier>CODEN: JAPIAU</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>ALLOY SYSTEMS ; ALLOYS ; BCC LATTICES ; BINARY ALLOY SYSTEMS ; Condensed Matter ; COPPER ALLOYS ; CRITICAL TEMPERATURE ; CRYSTAL LATTICES ; CRYSTAL STRUCTURE ; CUBIC LATTICES ; CURIE POINT ; DEPOSITION ; ELECTRODEPOSITION ; ELECTROLYSIS ; ELEMENTS ; FCC LATTICES ; FERROMAGNETIC MATERIALS ; IRON ; IRON ALLOYS ; IRON-ALPHA ; LYSIS ; MAGNETIC MATERIALS ; MAGNETIC PROPERTIES ; MAGNETISM ; MATERIALS ; MATERIALS SCIENCE ; METALS ; PHYSICAL PROPERTIES ; Physics ; SUPERPARAMAGNETISM ; SURFACE COATING ; TEMPERATURE RANGE ; TEMPERATURE RANGE 0273-0400 K ; THERMODYNAMIC PROPERTIES ; TRANSITION ELEMENT ALLOYS ; TRANSITION ELEMENTS ; TRANSITION TEMPERATURE</subject><ispartof>Journal of applied physics, 2009-11, Vol.106 (9), p.093907-093907-6</ispartof><rights>2009 American Institute of Physics</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c411t-d3fdd64fb99b3d82afcb149ead3f33602e8ccee7e43b56a28739f475e3b8d4433</citedby><cites>FETCH-LOGICAL-c411t-d3fdd64fb99b3d82afcb149ead3f33602e8ccee7e43b56a28739f475e3b8d4433</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/jap/article-lookup/doi/10.1063/1.3253725$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>230,314,776,780,790,881,1553,4498,27901,27902,76353,76359</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00439601$$DView record in HAL$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/21361909$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Noce, R. D.</creatorcontrib><creatorcontrib>Gomes, O. D. M.</creatorcontrib><creatorcontrib>de Magalhães, S. D.</creatorcontrib><creatorcontrib>Wolf, W.</creatorcontrib><creatorcontrib>Guimarães, R. B.</creatorcontrib><creatorcontrib>de Castro, A. C.</creatorcontrib><creatorcontrib>Pires, M. J. M.</creatorcontrib><creatorcontrib>Macedo, W. A. A.</creatorcontrib><creatorcontrib>Givord, D.</creatorcontrib><creatorcontrib>Barthem, V. M. T. S.</creatorcontrib><title>Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition</title><title>Journal of applied physics</title><description>Fe
x
Cu
100
−
x
metastable alloys were prepared by pulsed electrodeposition for
5
<
x
<
85
. The Fe-rich alloys crystallize in the bcc structure of
α
-Fe
and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys
(
x
>
50
)
are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys
(
x
≤
30
)
, the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the
x
=
10
alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances.</description><subject>ALLOY SYSTEMS</subject><subject>ALLOYS</subject><subject>BCC LATTICES</subject><subject>BINARY ALLOY SYSTEMS</subject><subject>Condensed Matter</subject><subject>COPPER ALLOYS</subject><subject>CRITICAL TEMPERATURE</subject><subject>CRYSTAL LATTICES</subject><subject>CRYSTAL STRUCTURE</subject><subject>CUBIC LATTICES</subject><subject>CURIE POINT</subject><subject>DEPOSITION</subject><subject>ELECTRODEPOSITION</subject><subject>ELECTROLYSIS</subject><subject>ELEMENTS</subject><subject>FCC LATTICES</subject><subject>FERROMAGNETIC MATERIALS</subject><subject>IRON</subject><subject>IRON ALLOYS</subject><subject>IRON-ALPHA</subject><subject>LYSIS</subject><subject>MAGNETIC MATERIALS</subject><subject>MAGNETIC PROPERTIES</subject><subject>MAGNETISM</subject><subject>MATERIALS</subject><subject>MATERIALS SCIENCE</subject><subject>METALS</subject><subject>PHYSICAL PROPERTIES</subject><subject>Physics</subject><subject>SUPERPARAMAGNETISM</subject><subject>SURFACE COATING</subject><subject>TEMPERATURE RANGE</subject><subject>TEMPERATURE RANGE 0273-0400 K</subject><subject>THERMODYNAMIC PROPERTIES</subject><subject>TRANSITION ELEMENT ALLOYS</subject><subject>TRANSITION ELEMENTS</subject><subject>TRANSITION TEMPERATURE</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAQhi0EEqUw8A8iMTGk-HLOhweGqqItUhELzJbjXKhRiCM7Req_J1ELnZjudO9zXy9jt8BnwDN8gBkmKeZJesYmwAsZ52nKz9mE8wTiQubykl2F8Mk5QIFywtYv-qOl3pqo864j31sKkaujJcWLXaSbxu3DIFGnPVVRuY-6XROGjBoyvXcVdS7Y3rr2ml3UepBujnHK3pdPb4t1vHldPS_mm9gIgD6usK6qTNSllCVWRaJrU4KQpAcBMeMJFcYQ5SSwTDOdFDnKWuQpYVlUQiBO2d1hrgu9VcHYnszWuLYd7lEJYAaSy4G6P1Bb3ajO2y_t98ppq9bzjRprnAuUGYdvOLHGuxA81X8NwNVoqgJ1NHVgHw_suFiPf_8P_zqrTs7iD8vWfeI</recordid><startdate>20091101</startdate><enddate>20091101</enddate><creator>Noce, R. D.</creator><creator>Gomes, O. D. M.</creator><creator>de Magalhães, S. D.</creator><creator>Wolf, W.</creator><creator>Guimarães, R. B.</creator><creator>de Castro, A. C.</creator><creator>Pires, M. J. M.</creator><creator>Macedo, W. A. A.</creator><creator>Givord, D.</creator><creator>Barthem, V. M. T. S.</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>OTOTI</scope></search><sort><creationdate>20091101</creationdate><title>Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition</title><author>Noce, R. D. ; Gomes, O. D. M. ; de Magalhães, S. D. ; Wolf, W. ; Guimarães, R. B. ; de Castro, A. C. ; Pires, M. J. M. ; Macedo, W. A. A. ; Givord, D. ; Barthem, V. M. T. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c411t-d3fdd64fb99b3d82afcb149ead3f33602e8ccee7e43b56a28739f475e3b8d4433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>ALLOY SYSTEMS</topic><topic>ALLOYS</topic><topic>BCC LATTICES</topic><topic>BINARY ALLOY SYSTEMS</topic><topic>Condensed Matter</topic><topic>COPPER ALLOYS</topic><topic>CRITICAL TEMPERATURE</topic><topic>CRYSTAL LATTICES</topic><topic>CRYSTAL STRUCTURE</topic><topic>CUBIC LATTICES</topic><topic>CURIE POINT</topic><topic>DEPOSITION</topic><topic>ELECTRODEPOSITION</topic><topic>ELECTROLYSIS</topic><topic>ELEMENTS</topic><topic>FCC LATTICES</topic><topic>FERROMAGNETIC MATERIALS</topic><topic>IRON</topic><topic>IRON ALLOYS</topic><topic>IRON-ALPHA</topic><topic>LYSIS</topic><topic>MAGNETIC MATERIALS</topic><topic>MAGNETIC PROPERTIES</topic><topic>MAGNETISM</topic><topic>MATERIALS</topic><topic>MATERIALS SCIENCE</topic><topic>METALS</topic><topic>PHYSICAL PROPERTIES</topic><topic>Physics</topic><topic>SUPERPARAMAGNETISM</topic><topic>SURFACE COATING</topic><topic>TEMPERATURE RANGE</topic><topic>TEMPERATURE RANGE 0273-0400 K</topic><topic>THERMODYNAMIC PROPERTIES</topic><topic>TRANSITION ELEMENT ALLOYS</topic><topic>TRANSITION ELEMENTS</topic><topic>TRANSITION TEMPERATURE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noce, R. D.</creatorcontrib><creatorcontrib>Gomes, O. D. M.</creatorcontrib><creatorcontrib>de Magalhães, S. D.</creatorcontrib><creatorcontrib>Wolf, W.</creatorcontrib><creatorcontrib>Guimarães, R. B.</creatorcontrib><creatorcontrib>de Castro, A. C.</creatorcontrib><creatorcontrib>Pires, M. J. M.</creatorcontrib><creatorcontrib>Macedo, W. A. A.</creatorcontrib><creatorcontrib>Givord, D.</creatorcontrib><creatorcontrib>Barthem, V. M. T. S.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noce, R. D.</au><au>Gomes, O. D. M.</au><au>de Magalhães, S. D.</au><au>Wolf, W.</au><au>Guimarães, R. B.</au><au>de Castro, A. C.</au><au>Pires, M. J. M.</au><au>Macedo, W. A. A.</au><au>Givord, D.</au><au>Barthem, V. M. T. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition</atitle><jtitle>Journal of applied physics</jtitle><date>2009-11-01</date><risdate>2009</risdate><volume>106</volume><issue>9</issue><spage>093907</spage><epage>093907-6</epage><pages>093907-093907-6</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>Fe
x
Cu
100
−
x
metastable alloys were prepared by pulsed electrodeposition for
5
<
x
<
85
. The Fe-rich alloys crystallize in the bcc structure of
α
-Fe
and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys
(
x
>
50
)
are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys
(
x
≤
30
)
, the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the
x
=
10
alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><doi>10.1063/1.3253725</doi></addata></record> |
fulltext | fulltext |
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ispartof | Journal of applied physics, 2009-11, Vol.106 (9), p.093907-093907-6 |
issn | 0021-8979 1089-7550 |
language | eng |
recordid | cdi_osti_scitechconnect_21361909 |
source | AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection |
subjects | ALLOY SYSTEMS ALLOYS BCC LATTICES BINARY ALLOY SYSTEMS Condensed Matter COPPER ALLOYS CRITICAL TEMPERATURE CRYSTAL LATTICES CRYSTAL STRUCTURE CUBIC LATTICES CURIE POINT DEPOSITION ELECTRODEPOSITION ELECTROLYSIS ELEMENTS FCC LATTICES FERROMAGNETIC MATERIALS IRON IRON ALLOYS IRON-ALPHA LYSIS MAGNETIC MATERIALS MAGNETIC PROPERTIES MAGNETISM MATERIALS MATERIALS SCIENCE METALS PHYSICAL PROPERTIES Physics SUPERPARAMAGNETISM SURFACE COATING TEMPERATURE RANGE TEMPERATURE RANGE 0273-0400 K THERMODYNAMIC PROPERTIES TRANSITION ELEMENT ALLOYS TRANSITION ELEMENTS TRANSITION TEMPERATURE |
title | Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition |
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