Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition

Fe x Cu 100 − x metastable alloys were prepared by pulsed electrodeposition for 5 < x < 85 . The Fe-rich alloys crystallize in the bcc structure of α -Fe and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys ( x > 50 ) are reminiscent o...

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Veröffentlicht in:Journal of applied physics 2009-11, Vol.106 (9), p.093907-093907-6
Hauptverfasser: Noce, R. D., Gomes, O. D. M., de Magalhães, S. D., Wolf, W., Guimarães, R. B., de Castro, A. C., Pires, M. J. M., Macedo, W. A. A., Givord, D., Barthem, V. M. T. S.
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container_end_page 093907-6
container_issue 9
container_start_page 093907
container_title Journal of applied physics
container_volume 106
creator Noce, R. D.
Gomes, O. D. M.
de Magalhães, S. D.
Wolf, W.
Guimarães, R. B.
de Castro, A. C.
Pires, M. J. M.
Macedo, W. A. A.
Givord, D.
Barthem, V. M. T. S.
description Fe x Cu 100 − x metastable alloys were prepared by pulsed electrodeposition for 5 < x < 85 . The Fe-rich alloys crystallize in the bcc structure of α -Fe and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys ( x > 50 ) are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys ( x ≤ 30 ) , the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the x = 10 alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances.
doi_str_mv 10.1063/1.3253725
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D. ; Gomes, O. D. M. ; de Magalhães, S. D. ; Wolf, W. ; Guimarães, R. B. ; de Castro, A. C. ; Pires, M. J. M. ; Macedo, W. A. A. ; Givord, D. ; Barthem, V. M. T. S.</creator><creatorcontrib>Noce, R. D. ; Gomes, O. D. M. ; de Magalhães, S. D. ; Wolf, W. ; Guimarães, R. B. ; de Castro, A. C. ; Pires, M. J. M. ; Macedo, W. A. A. ; Givord, D. ; Barthem, V. M. T. S.</creatorcontrib><description>Fe x Cu 100 − x metastable alloys were prepared by pulsed electrodeposition for 5 &lt; x &lt; 85 . The Fe-rich alloys crystallize in the bcc structure of α -Fe and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys ( x &gt; 50 ) are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys ( x ≤ 30 ) , the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the x = 10 alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. 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The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys ( x ≤ 30 ) , the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the x = 10 alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. 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S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition</atitle><jtitle>Journal of applied physics</jtitle><date>2009-11-01</date><risdate>2009</risdate><volume>106</volume><issue>9</issue><spage>093907</spage><epage>093907-6</epage><pages>093907-093907-6</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>Fe x Cu 100 − x metastable alloys were prepared by pulsed electrodeposition for 5 &lt; x &lt; 85 . The Fe-rich alloys crystallize in the bcc structure of α -Fe and the Fe-poor ones in the fcc structure of Cu. The magnetic properties of the ferromagnetic Fe-rich alloys ( x &gt; 50 ) are reminiscent of those observed in Fe-Cu alloys prepared by other methods. The Curie temperature decreases regularly with decreasing x. In the Fe-poor alloys ( x ≤ 30 ) , the observed properties indicate that Fe-rich clusters form within a Cu-rich matrix. In the x = 10 alloy, the Fe clusters are found to be superparamagnetic at room temperature, but a superferromagnetic order develops below a critical temperature of about 120 K. It is suggested that the intercluster coupling is mediated by Ruderman-Kittel-Kasuya-Yosida interactions which are predominantly positive due to the very short intercluster distances.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><doi>10.1063/1.3253725</doi></addata></record>
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1089-7550
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source AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection
subjects ALLOY SYSTEMS
ALLOYS
BCC LATTICES
BINARY ALLOY SYSTEMS
Condensed Matter
COPPER ALLOYS
CRITICAL TEMPERATURE
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CUBIC LATTICES
CURIE POINT
DEPOSITION
ELECTRODEPOSITION
ELECTROLYSIS
ELEMENTS
FCC LATTICES
FERROMAGNETIC MATERIALS
IRON
IRON ALLOYS
IRON-ALPHA
LYSIS
MAGNETIC MATERIALS
MAGNETIC PROPERTIES
MAGNETISM
MATERIALS
MATERIALS SCIENCE
METALS
PHYSICAL PROPERTIES
Physics
SUPERPARAMAGNETISM
SURFACE COATING
TEMPERATURE RANGE
TEMPERATURE RANGE 0273-0400 K
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT ALLOYS
TRANSITION ELEMENTS
TRANSITION TEMPERATURE
title Magnetic properties of Fe-Cu alloys prepared by pulsed electrodeposition
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