Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups
Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photor...
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Veröffentlicht in: | Journal of applied physics 2009-10, Vol.106 (7), p.073505-073505-5 |
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creator | Emoto, Akira Matsumoto, Taro Yamashita, Ayumi Shioda, Tatsutoshi Ono, Hiroshi Kawatsuki, Nobuhiro |
description | Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photoreaction between the cinnamic acid groups and subsequent annealing induce the reorientation of peripheral molecules without cross-linking along the cross-linked groups. Long bistolane mesogenic moiety exhibits large birefringence in comparison with a biphenyl mesogenic moiety, the value of the induced birefringence in the bistolane mesogenic liquid crystalline (LC) polymer is strongly dependent on both the grating constant and the wavelength of the reconstruction light. |
doi_str_mv | 10.1063/1.3234385 |
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The polarized ultraviolet light causes the axis-selective photoreaction between the cinnamic acid groups and subsequent annealing induce the reorientation of peripheral molecules without cross-linking along the cross-linked groups. Long bistolane mesogenic moiety exhibits large birefringence in comparison with a biphenyl mesogenic moiety, the value of the induced birefringence in the bistolane mesogenic liquid crystalline (LC) polymer is strongly dependent on both the grating constant and the wavelength of the reconstruction light.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.3234385</identifier><identifier>CODEN: JAPIAU</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>ANNEALING ; AROMATICS ; BIPHENYL ; BIREFRINGENCE ; CARBOXYLIC ACIDS ; CHEMICAL REACTIONS ; CHEMISTRY ; CINNAMIC ACID ; CROSS-LINKING ; CRYSTALS ; ELECTROMAGNETIC RADIATION ; FLUIDS ; HEAT TREATMENTS ; HOLOGRAPHY ; HYDROCARBONS ; INTERFERENCE ; LIQUID CRYSTALS ; LIQUIDS ; MATERIALS SCIENCE ; MOLECULES ; MONOCARBOXYLIC ACIDS ; ORGANIC ACIDS ; ORGANIC COMPOUNDS ; PHOTOCHEMISTRY ; POLARIZATION ; POLYMERIZATION ; POLYMERS ; RADIATIONS ; REFRACTION ; ULTRAVIOLET RADIATION ; WAVELENGTHS</subject><ispartof>Journal of applied physics, 2009-10, Vol.106 (7), p.073505-073505-5</ispartof><rights>2009 American Institute of Physics</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-96214ff4707e4c3fac5ab0b9249b26be802696119fbf5b736352ac0acc9118283</citedby><cites>FETCH-LOGICAL-c377t-96214ff4707e4c3fac5ab0b9249b26be802696119fbf5b736352ac0acc9118283</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/jap/article-lookup/doi/10.1063/1.3234385$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>230,314,780,784,794,885,1559,4511,27923,27924,76255,76261</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/21361862$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Emoto, Akira</creatorcontrib><creatorcontrib>Matsumoto, Taro</creatorcontrib><creatorcontrib>Yamashita, Ayumi</creatorcontrib><creatorcontrib>Shioda, Tatsutoshi</creatorcontrib><creatorcontrib>Ono, Hiroshi</creatorcontrib><creatorcontrib>Kawatsuki, Nobuhiro</creatorcontrib><title>Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups</title><title>Journal of applied physics</title><description>Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photoreaction between the cinnamic acid groups and subsequent annealing induce the reorientation of peripheral molecules without cross-linking along the cross-linked groups. Long bistolane mesogenic moiety exhibits large birefringence in comparison with a biphenyl mesogenic moiety, the value of the induced birefringence in the bistolane mesogenic liquid crystalline (LC) polymer is strongly dependent on both the grating constant and the wavelength of the reconstruction light.</description><subject>ANNEALING</subject><subject>AROMATICS</subject><subject>BIPHENYL</subject><subject>BIREFRINGENCE</subject><subject>CARBOXYLIC ACIDS</subject><subject>CHEMICAL REACTIONS</subject><subject>CHEMISTRY</subject><subject>CINNAMIC ACID</subject><subject>CROSS-LINKING</subject><subject>CRYSTALS</subject><subject>ELECTROMAGNETIC RADIATION</subject><subject>FLUIDS</subject><subject>HEAT TREATMENTS</subject><subject>HOLOGRAPHY</subject><subject>HYDROCARBONS</subject><subject>INTERFERENCE</subject><subject>LIQUID CRYSTALS</subject><subject>LIQUIDS</subject><subject>MATERIALS SCIENCE</subject><subject>MOLECULES</subject><subject>MONOCARBOXYLIC ACIDS</subject><subject>ORGANIC ACIDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>PHOTOCHEMISTRY</subject><subject>POLARIZATION</subject><subject>POLYMERIZATION</subject><subject>POLYMERS</subject><subject>RADIATIONS</subject><subject>REFRACTION</subject><subject>ULTRAVIOLET RADIATION</subject><subject>WAVELENGTHS</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kLtOBCEYhYnRxHW18A1IrCxm5TI3CgtjvCWb2GhNgIEddAZGYIv1UXxa2UtjYfU3339OzgfAJUYLjGp6gxeU0JK21RGYYdSyoqkqdAxmCBFctKxhp-Asxg-EMG4pm4GfpQgrDaUN2gTrVtopDYXr4OQHEey3SNY72PvBr4KYeqtgvimDERofRt1B6-DU--RV8DEWg3WfQg56-78ZdYCD_VrbDqqwiUkMESo_TsHGnJBLY8otTsNRR5-rc3q0nc4Vfj3Fc3Bi8oe-ONw5eH98eLt_LpavTy_3d8tC0aZJBasJLo0pG9ToUlEjVCUkkoyUTJJa6haRmtUYMyNNJRta04oIhYRSLDsgLZ2Dq32uj8nyqGzSqlfeOa0SJ5jWuK1Jpq731G5ntsXzjFGEDceIb9VzzA_qM3u7Z7dhO4P_wzv__I9_-gv9-I98</recordid><startdate>20091001</startdate><enddate>20091001</enddate><creator>Emoto, Akira</creator><creator>Matsumoto, Taro</creator><creator>Yamashita, Ayumi</creator><creator>Shioda, Tatsutoshi</creator><creator>Ono, Hiroshi</creator><creator>Kawatsuki, Nobuhiro</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20091001</creationdate><title>Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups</title><author>Emoto, Akira ; Matsumoto, Taro ; Yamashita, Ayumi ; Shioda, Tatsutoshi ; Ono, Hiroshi ; Kawatsuki, Nobuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-96214ff4707e4c3fac5ab0b9249b26be802696119fbf5b736352ac0acc9118283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>ANNEALING</topic><topic>AROMATICS</topic><topic>BIPHENYL</topic><topic>BIREFRINGENCE</topic><topic>CARBOXYLIC ACIDS</topic><topic>CHEMICAL REACTIONS</topic><topic>CHEMISTRY</topic><topic>CINNAMIC ACID</topic><topic>CROSS-LINKING</topic><topic>CRYSTALS</topic><topic>ELECTROMAGNETIC RADIATION</topic><topic>FLUIDS</topic><topic>HEAT TREATMENTS</topic><topic>HOLOGRAPHY</topic><topic>HYDROCARBONS</topic><topic>INTERFERENCE</topic><topic>LIQUID CRYSTALS</topic><topic>LIQUIDS</topic><topic>MATERIALS SCIENCE</topic><topic>MOLECULES</topic><topic>MONOCARBOXYLIC ACIDS</topic><topic>ORGANIC ACIDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>PHOTOCHEMISTRY</topic><topic>POLARIZATION</topic><topic>POLYMERIZATION</topic><topic>POLYMERS</topic><topic>RADIATIONS</topic><topic>REFRACTION</topic><topic>ULTRAVIOLET RADIATION</topic><topic>WAVELENGTHS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Emoto, Akira</creatorcontrib><creatorcontrib>Matsumoto, Taro</creatorcontrib><creatorcontrib>Yamashita, Ayumi</creatorcontrib><creatorcontrib>Shioda, Tatsutoshi</creatorcontrib><creatorcontrib>Ono, Hiroshi</creatorcontrib><creatorcontrib>Kawatsuki, Nobuhiro</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Emoto, Akira</au><au>Matsumoto, Taro</au><au>Yamashita, Ayumi</au><au>Shioda, Tatsutoshi</au><au>Ono, Hiroshi</au><au>Kawatsuki, Nobuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups</atitle><jtitle>Journal of applied physics</jtitle><date>2009-10-01</date><risdate>2009</risdate><volume>106</volume><issue>7</issue><spage>073505</spage><epage>073505-5</epage><pages>073505-073505-5</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photoreaction between the cinnamic acid groups and subsequent annealing induce the reorientation of peripheral molecules without cross-linking along the cross-linked groups. Long bistolane mesogenic moiety exhibits large birefringence in comparison with a biphenyl mesogenic moiety, the value of the induced birefringence in the bistolane mesogenic liquid crystalline (LC) polymer is strongly dependent on both the grating constant and the wavelength of the reconstruction light.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><doi>10.1063/1.3234385</doi></addata></record> |
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subjects | ANNEALING AROMATICS BIPHENYL BIREFRINGENCE CARBOXYLIC ACIDS CHEMICAL REACTIONS CHEMISTRY CINNAMIC ACID CROSS-LINKING CRYSTALS ELECTROMAGNETIC RADIATION FLUIDS HEAT TREATMENTS HOLOGRAPHY HYDROCARBONS INTERFERENCE LIQUID CRYSTALS LIQUIDS MATERIALS SCIENCE MOLECULES MONOCARBOXYLIC ACIDS ORGANIC ACIDS ORGANIC COMPOUNDS PHOTOCHEMISTRY POLARIZATION POLYMERIZATION POLYMERS RADIATIONS REFRACTION ULTRAVIOLET RADIATION WAVELENGTHS |
title | Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups |
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