Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups

Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photor...

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Veröffentlicht in:Journal of applied physics 2009-10, Vol.106 (7), p.073505-073505-5
Hauptverfasser: Emoto, Akira, Matsumoto, Taro, Yamashita, Ayumi, Shioda, Tatsutoshi, Ono, Hiroshi, Kawatsuki, Nobuhiro
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container_end_page 073505-5
container_issue 7
container_start_page 073505
container_title Journal of applied physics
container_volume 106
creator Emoto, Akira
Matsumoto, Taro
Yamashita, Ayumi
Shioda, Tatsutoshi
Ono, Hiroshi
Kawatsuki, Nobuhiro
description Polarization gratings with large birefringence are formed in photoreactive polymer liquid crystals with bistolane moiety and terminal cinnamic acid moiety by the use of polarized ultraviolet interference light and subsequent annealing. The polarized ultraviolet light causes the axis-selective photoreaction between the cinnamic acid groups and subsequent annealing induce the reorientation of peripheral molecules without cross-linking along the cross-linked groups. Long bistolane mesogenic moiety exhibits large birefringence in comparison with a biphenyl mesogenic moiety, the value of the induced birefringence in the bistolane mesogenic liquid crystalline (LC) polymer is strongly dependent on both the grating constant and the wavelength of the reconstruction light.
doi_str_mv 10.1063/1.3234385
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source AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection
subjects ANNEALING
AROMATICS
BIPHENYL
BIREFRINGENCE
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHEMISTRY
CINNAMIC ACID
CROSS-LINKING
CRYSTALS
ELECTROMAGNETIC RADIATION
FLUIDS
HEAT TREATMENTS
HOLOGRAPHY
HYDROCARBONS
INTERFERENCE
LIQUID CRYSTALS
LIQUIDS
MATERIALS SCIENCE
MOLECULES
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
PHOTOCHEMISTRY
POLARIZATION
POLYMERIZATION
POLYMERS
RADIATIONS
REFRACTION
ULTRAVIOLET RADIATION
WAVELENGTHS
title Large birefringence and polarization holographic gratings formed in photocross-linkable polymer liquid crystals comprising bistolane mesogenic side groups
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