Improved dye-sensitized solar cells by composite ionic liquid electrolyte incorporating layered titanium phosphate
We reported a composite electrolyte prepared by incorporating layered α-titanium phosphate (α-TiP) into a binary ionic liquid of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EmimBF 4) (volume ratio, 13:7) electrolyte. The addition of α-TiP markedly im...
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| Veröffentlicht in: | Solar energy 2010-05, Vol.84 (5), p.854-859 |
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| creator | Cheng, Ping Lan, Tian Wang, Wanjun Wu, Haixia Yang, Haijun Deng, Changsheng Dai, Xiaming Guo, Shouwu |
| description | We reported a composite electrolyte prepared by incorporating layered α-titanium phosphate (α-TiP) into a binary ionic liquid of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EmimBF
4) (volume ratio, 13:7) electrolyte. The addition of α-TiP markedly improved the photovoltaic properties of dye-sensitized solar cells (DSSCs) compared to that without α-TiP. The enhancement was explained by improved diffusion of tri-iodide
(
I
3
-
)
ions, suppressed electron recombination with
I
3
-
in the electrolyte and increased lifetime of electrons in mesoscopic TiO
2 film. |
| doi_str_mv | 10.1016/j.solener.2010.02.011 |
| format | Article |
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4) (volume ratio, 13:7) electrolyte. The addition of α-TiP markedly improved the photovoltaic properties of dye-sensitized solar cells (DSSCs) compared to that without α-TiP. The enhancement was explained by improved diffusion of tri-iodide
(
I
3
-
)
ions, suppressed electron recombination with
I
3
-
in the electrolyte and increased lifetime of electrons in mesoscopic TiO
2 film.</description><identifier>ISSN: 0038-092X</identifier><identifier>EISSN: 1471-1257</identifier><identifier>DOI: 10.1016/j.solener.2010.02.011</identifier><identifier>CODEN: SRENA4</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Composite ionic liquid electrolyte ; Composite ionic liquid electrolytes ; DIFFUSION ; DYES ; Electrical engineering. Electrical power engineering ; ELECTROLYTES ; ELECTRONS ; Energy ; Equipments, installations and applications ; Exact sciences and technology ; FLUOROBORATES ; IODINE IONS ; Ions ; Layered α-titanium phosphate ; LIFETIME ; LIQUIDS ; Materials ; Natural energy ; ORGANIC IODINE COMPOUNDS ; Phosphates ; Photovoltaic cells ; Photovoltaic conversion ; PHOTOVOLTAIC EFFECT ; Photovoltaic performance ; RECOMBINATION ; SOLAR CELLS ; Solar cells. Photoelectrochemical cells ; SOLAR ENERGY ; Titanium ; TITANIUM OXIDES ; TITANIUM PHOSPHATES ; TITANIUM-ALPHA</subject><ispartof>Solar energy, 2010-05, Vol.84 (5), p.854-859</ispartof><rights>2010 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright Pergamon Press Inc. May 2010</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-e072e0c786143f2e7e07ee57690909812d394dad39a872597343ddae92e00cb3</citedby><cites>FETCH-LOGICAL-c435t-e072e0c786143f2e7e07ee57690909812d394dad39a872597343ddae92e00cb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.solener.2010.02.011$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3548,27922,27923,45993</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22611553$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/21318386$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Cheng, Ping</creatorcontrib><creatorcontrib>Lan, Tian</creatorcontrib><creatorcontrib>Wang, Wanjun</creatorcontrib><creatorcontrib>Wu, Haixia</creatorcontrib><creatorcontrib>Yang, Haijun</creatorcontrib><creatorcontrib>Deng, Changsheng</creatorcontrib><creatorcontrib>Dai, Xiaming</creatorcontrib><creatorcontrib>Guo, Shouwu</creatorcontrib><title>Improved dye-sensitized solar cells by composite ionic liquid electrolyte incorporating layered titanium phosphate</title><title>Solar energy</title><description>We reported a composite electrolyte prepared by incorporating layered α-titanium phosphate (α-TiP) into a binary ionic liquid of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EmimBF
4) (volume ratio, 13:7) electrolyte. The addition of α-TiP markedly improved the photovoltaic properties of dye-sensitized solar cells (DSSCs) compared to that without α-TiP. The enhancement was explained by improved diffusion of tri-iodide
(
I
3
-
)
ions, suppressed electron recombination with
I
3
-
in the electrolyte and increased lifetime of electrons in mesoscopic TiO
2 film.</description><subject>Applied sciences</subject><subject>Composite ionic liquid electrolyte</subject><subject>Composite ionic liquid electrolytes</subject><subject>DIFFUSION</subject><subject>DYES</subject><subject>Electrical engineering. Electrical power engineering</subject><subject>ELECTROLYTES</subject><subject>ELECTRONS</subject><subject>Energy</subject><subject>Equipments, installations and applications</subject><subject>Exact sciences and technology</subject><subject>FLUOROBORATES</subject><subject>IODINE IONS</subject><subject>Ions</subject><subject>Layered α-titanium phosphate</subject><subject>LIFETIME</subject><subject>LIQUIDS</subject><subject>Materials</subject><subject>Natural energy</subject><subject>ORGANIC IODINE COMPOUNDS</subject><subject>Phosphates</subject><subject>Photovoltaic cells</subject><subject>Photovoltaic conversion</subject><subject>PHOTOVOLTAIC EFFECT</subject><subject>Photovoltaic performance</subject><subject>RECOMBINATION</subject><subject>SOLAR CELLS</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>SOLAR ENERGY</subject><subject>Titanium</subject><subject>TITANIUM OXIDES</subject><subject>TITANIUM PHOSPHATES</subject><subject>TITANIUM-ALPHA</subject><issn>0038-092X</issn><issn>1471-1257</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFUcFqGzEQFaGBuGk_obC09LiORtpd7Z5KCWkTCPSSQ29Ckca1jCxtJDmw-fqOsem1CCQ0896bxzzGPgFfA4fhZrcuKWDEvBacalysOcAFW0GnoAXRq3dsxbkcWz6J31fsfSk7zkHBqFYsP-znnF7RNW7BtmAsvvo3-pKkyY3FEErzvDQ27edEPWx8it42wb8cvGswoK05heXYiDblOWVTffzTBLNgJp3qq4n-sG_mbSrz1lT8wC43JhT8eH6v2dOPu6fb-_bx18-H2--Pre1kX1vkSiC3ahygkxuBigqIvRomTmcE4eTUOUO3GZXoJyU76ZzBiVjcPstr9uUkm0r1uljybrc2xUiOtQAJoxwHQn0-oWgLLwcsVe_SIUfypYUENXAaRaD-BLI5lZJxo-fs9yYvGrg-RqB3-hyBPkagudAUAfG-nsVNsSZssonWl39kIQaAvpeE-3bCIa3j1ZMK2cVo0fl8dOuS_8-kv2lyoOQ</recordid><startdate>20100501</startdate><enddate>20100501</enddate><creator>Cheng, Ping</creator><creator>Lan, Tian</creator><creator>Wang, Wanjun</creator><creator>Wu, Haixia</creator><creator>Yang, Haijun</creator><creator>Deng, Changsheng</creator><creator>Dai, Xiaming</creator><creator>Guo, Shouwu</creator><general>Elsevier Ltd</general><general>Elsevier</general><general>Pergamon Press Inc</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>SOI</scope><scope>OTOTI</scope></search><sort><creationdate>20100501</creationdate><title>Improved dye-sensitized solar cells by composite ionic liquid electrolyte incorporating layered titanium phosphate</title><author>Cheng, Ping ; Lan, Tian ; Wang, Wanjun ; Wu, Haixia ; Yang, Haijun ; Deng, Changsheng ; Dai, Xiaming ; Guo, Shouwu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-e072e0c786143f2e7e07ee57690909812d394dad39a872597343ddae92e00cb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Composite ionic liquid electrolyte</topic><topic>Composite ionic liquid electrolytes</topic><topic>DIFFUSION</topic><topic>DYES</topic><topic>Electrical engineering. Electrical power engineering</topic><topic>ELECTROLYTES</topic><topic>ELECTRONS</topic><topic>Energy</topic><topic>Equipments, installations and applications</topic><topic>Exact sciences and technology</topic><topic>FLUOROBORATES</topic><topic>IODINE IONS</topic><topic>Ions</topic><topic>Layered α-titanium phosphate</topic><topic>LIFETIME</topic><topic>LIQUIDS</topic><topic>Materials</topic><topic>Natural energy</topic><topic>ORGANIC IODINE COMPOUNDS</topic><topic>Phosphates</topic><topic>Photovoltaic cells</topic><topic>Photovoltaic conversion</topic><topic>PHOTOVOLTAIC EFFECT</topic><topic>Photovoltaic performance</topic><topic>RECOMBINATION</topic><topic>SOLAR CELLS</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>SOLAR ENERGY</topic><topic>Titanium</topic><topic>TITANIUM OXIDES</topic><topic>TITANIUM PHOSPHATES</topic><topic>TITANIUM-ALPHA</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Ping</creatorcontrib><creatorcontrib>Lan, Tian</creatorcontrib><creatorcontrib>Wang, Wanjun</creatorcontrib><creatorcontrib>Wu, Haixia</creatorcontrib><creatorcontrib>Yang, Haijun</creatorcontrib><creatorcontrib>Deng, Changsheng</creatorcontrib><creatorcontrib>Dai, Xiaming</creatorcontrib><creatorcontrib>Guo, Shouwu</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><collection>OSTI.GOV</collection><jtitle>Solar energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Ping</au><au>Lan, Tian</au><au>Wang, Wanjun</au><au>Wu, Haixia</au><au>Yang, Haijun</au><au>Deng, Changsheng</au><au>Dai, Xiaming</au><au>Guo, Shouwu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improved dye-sensitized solar cells by composite ionic liquid electrolyte incorporating layered titanium phosphate</atitle><jtitle>Solar energy</jtitle><date>2010-05-01</date><risdate>2010</risdate><volume>84</volume><issue>5</issue><spage>854</spage><epage>859</epage><pages>854-859</pages><issn>0038-092X</issn><eissn>1471-1257</eissn><coden>SRENA4</coden><abstract>We reported a composite electrolyte prepared by incorporating layered α-titanium phosphate (α-TiP) into a binary ionic liquid of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methylimidazolium tetrafluoroborate (EmimBF
4) (volume ratio, 13:7) electrolyte. The addition of α-TiP markedly improved the photovoltaic properties of dye-sensitized solar cells (DSSCs) compared to that without α-TiP. The enhancement was explained by improved diffusion of tri-iodide
(
I
3
-
)
ions, suppressed electron recombination with
I
3
-
in the electrolyte and increased lifetime of electrons in mesoscopic TiO
2 film.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.solener.2010.02.011</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0038-092X |
| ispartof | Solar energy, 2010-05, Vol.84 (5), p.854-859 |
| issn | 0038-092X 1471-1257 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Applied sciences Composite ionic liquid electrolyte Composite ionic liquid electrolytes DIFFUSION DYES Electrical engineering. Electrical power engineering ELECTROLYTES ELECTRONS Energy Equipments, installations and applications Exact sciences and technology FLUOROBORATES IODINE IONS Ions Layered α-titanium phosphate LIFETIME LIQUIDS Materials Natural energy ORGANIC IODINE COMPOUNDS Phosphates Photovoltaic cells Photovoltaic conversion PHOTOVOLTAIC EFFECT Photovoltaic performance RECOMBINATION SOLAR CELLS Solar cells. Photoelectrochemical cells SOLAR ENERGY Titanium TITANIUM OXIDES TITANIUM PHOSPHATES TITANIUM-ALPHA |
| title | Improved dye-sensitized solar cells by composite ionic liquid electrolyte incorporating layered titanium phosphate |
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