Magnetization study of nanograined pure and Mn-doped ZnO films: Formation of a ferromagnetic grain-boundary foam

In order to elucidate room-temperature (RT) ferromagnetism (FM) in ZnO, we have analyzed a multitude of experimental publications with respect to the ratio of grain-boundary (GB) area to grain volume. FM only appears if this ratio exceeds a certain threshold value s{sub th}. Based on these important...

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Veröffentlicht in:Physical review. B, Condensed matter and materials physics Condensed matter and materials physics, 2009-05, Vol.79 (20), Article 205206
Hauptverfasser: Straumal, Boris B., Mazilkin, Andrei A., Protasova, Svetlana G., Myatiev, Ata A., Straumal, Petr B., Schütz, Gisela, van Aken, Peter A., Goering, Eberhard, Baretzky, Brigitte
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container_issue 20
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container_title Physical review. B, Condensed matter and materials physics
container_volume 79
creator Straumal, Boris B.
Mazilkin, Andrei A.
Protasova, Svetlana G.
Myatiev, Ata A.
Straumal, Petr B.
Schütz, Gisela
van Aken, Peter A.
Goering, Eberhard
Baretzky, Brigitte
description In order to elucidate room-temperature (RT) ferromagnetism (FM) in ZnO, we have analyzed a multitude of experimental publications with respect to the ratio of grain-boundary (GB) area to grain volume. FM only appears if this ratio exceeds a certain threshold value s{sub th}. Based on these important results nanograined pure and Mn-doped ZnO films have been prepared, which reveal reproducible RT FM and magnetization proportional to the film thickness, even for pure ZnO films. Our findings strongly suggest that grain boundaries and related vacancies are the intrinsic origin for RT ferromagnetism.
doi_str_mv 10.1103/PhysRevB.79.205206
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source American Physical Society Journals
subjects CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTALS
DOPED MATERIALS
FERROMAGNETIC MATERIALS
FERROMAGNETISM
GRAIN BOUNDARIES
MAGNETIZATION
MANGANESE
MANGANESE ADDITIONS
NANOSTRUCTURES
TEMPERATURE RANGE 0273-0400 K
THICKNESS
VACANCIES
ZINC OXIDES
title Magnetization study of nanograined pure and Mn-doped ZnO films: Formation of a ferromagnetic grain-boundary foam
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