Syntheses, structures and luminescence properties of lanthanide coordination polymers with helical character

A series of lanthanide coordination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4), H 2ip=isophthalic acid, im=imidazole] and [Y 2(ip) 3(H 2O) 2] n · nH 2O (5), have been synthesized and characterized by elemental analyses, infrared (IR), ultraviolet-visible-near infrare...

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Veröffentlicht in:Journal of solid state chemistry 2008-08, Vol.181 (8), p.2099-2107
Hauptverfasser: Zhou, Rui-Sha, Cui, Xiao-Bing, Song, Jiang-Feng, Xu, Xiao-Yu, Xu, Ji-Qing, Wang, Tie-Gang
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container_end_page 2107
container_issue 8
container_start_page 2099
container_title Journal of solid state chemistry
container_volume 181
creator Zhou, Rui-Sha
Cui, Xiao-Bing
Song, Jiang-Feng
Xu, Xiao-Yu
Xu, Ji-Qing
Wang, Tie-Gang
description A series of lanthanide coordination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4), H 2ip=isophthalic acid, im=imidazole] and [Y 2(ip) 3(H 2O) 2] n · nH 2O (5), have been synthesized and characterized by elemental analyses, infrared (IR), ultraviolet-visible-near infrared (UV-Vis-NIR) and single-crystal X-ray diffraction analyses. The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 features a 2-D network making of two different kinds of quadruple-helical chains. Compounds 2 and 3 present the characteristic emissions of Pr(III) and Nd(III) ions in NIR region, respectively. Compound 4 shows sensitized luminescence of Dy(III) ions in visible region. A series of lanthanide coodination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4)] and [Y 2(ip) 3(H 2O) 2] n · nH 2O ( 5), have been reported. The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 displays a 2-D network making of two kinds of quadruple-helical chains. [Display omitted]
doi_str_mv 10.1016/j.jssc.2008.05.011
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The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 features a 2-D network making of two different kinds of quadruple-helical chains. Compounds 2 and 3 present the characteristic emissions of Pr(III) and Nd(III) ions in NIR region, respectively. Compound 4 shows sensitized luminescence of Dy(III) ions in visible region. A series of lanthanide coodination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4)] and [Y 2(ip) 3(H 2O) 2] n · nH 2O ( 5), have been reported. The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 displays a 2-D network making of two kinds of quadruple-helical chains. 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The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 features a 2-D network making of two different kinds of quadruple-helical chains. Compounds 2 and 3 present the characteristic emissions of Pr(III) and Nd(III) ions in NIR region, respectively. Compound 4 shows sensitized luminescence of Dy(III) ions in visible region. A series of lanthanide coodination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4)] and [Y 2(ip) 3(H 2O) 2] n · nH 2O ( 5), have been reported. The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 displays a 2-D network making of two kinds of quadruple-helical chains. 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The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 features a 2-D network making of two different kinds of quadruple-helical chains. Compounds 2 and 3 present the characteristic emissions of Pr(III) and Nd(III) ions in NIR region, respectively. Compound 4 shows sensitized luminescence of Dy(III) ions in visible region. A series of lanthanide coodination polymers, (Him) n [ Ln(ip) 2(H 2O)] n [Ln=La( 1), Pr( 2), Nd( 3) and Dy( 4)] and [Y 2(ip) 3(H 2O) 2] n · nH 2O ( 5), have been reported. The isostructural compounds 1– 4 possess 3-D structures with three different kinds of channels. Compound 5 displays a 2-D network making of two kinds of quadruple-helical chains. [Display omitted]</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2008.05.011</doi><tpages>9</tpages></addata></record>
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subjects Condensed matter: structure, mechanical and thermal properties
COORDINATION NUMBER
Cross-disciplinary physics: materials science
rheology
DYSPROSIUM COMPLEXES
Exact sciences and technology
Hydrothermal syntheses
HYDROTHERMAL SYNTHESIS
IMIDAZOLES
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
Isophthalate
Lanthanides
LANTHANUM COMPLEXES
LUMINESCENCE
Materials science
Materials synthesis
materials processing
MONOCRYSTALS
NEODYMIUM COMPLEXES
Organic compounds
Other materials
Physics
POLYMERS
PROMETHIUM COMPLEXES
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Topology
X-RAY DIFFRACTION
title Syntheses, structures and luminescence properties of lanthanide coordination polymers with helical character
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