Photofragment translational spectroscopy of propargyl radicals at 248 nm

The photodissociation of propargyl radical, C 3 H 3 , and its perdeuterated isotopolog was investigated using photofragment translational spectroscopy. Propargyl radicals were produced by 193 nm photolysis of allene entrained in a molecular beam expansion and then photodissociated at 248 nm . Photof...

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Veröffentlicht in:	The Journal of chemical physics 2008-03, Vol.128 (11), p.114303-114303-8
Hauptverfasser:	Goncher, Scott J., Moore, David T., Sveum, Niels E., Neumark, Daniel M.
Format:	Artikel
Sprache:	eng
Schlagworte:	ALLENE ATOMIC AND MOLECULAR PHYSICS BRANCHING RATIO DISSOCIATION ENERGY SPECTRA GROUND STATES HYDROGEN INTERNAL CONVERSION IONIZATION MASS SPECTROMETERS MOLECULAR BEAMS PHOTOLYSIS PROPARGYL RADICALS TIME-OF-FLIGHT METHOD
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