Crystal structure of Rb{sub 2}[GeO{sub 2}(OH){sub 2}].2H{sub 2}O
Single crystals of Rb{sub 2}[GeO{sub 2}(OH){sub 2}] . 2H{sub 2}O are studied by X-ray diffraction. The crystals belong to the orthorhombic system, sp. gr. Pna2{sub 1}, a = 13.523(6) A, b = 8.143(4) A, c = 13.407(6) A, Z = 8, R{sub 1} = 0.0506. In [GeO{sub 2}(OH){sub 2}]{sup 2-} anions, the Ge-O dist...
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| Veröffentlicht in: | Crystallography reports 2006-05, Vol.51 (3) |
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| container_title | Crystallography reports |
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| creator | Troyanov, S. I. Kostrikin, A. V. Spiridonov, F. M. Zaitsev, B. E. Tarasova, S. V. Kosenkova, O. V. |
| description | Single crystals of Rb{sub 2}[GeO{sub 2}(OH){sub 2}] . 2H{sub 2}O are studied by X-ray diffraction. The crystals belong to the orthorhombic system, sp. gr. Pna2{sub 1}, a = 13.523(6) A, b = 8.143(4) A, c = 13.407(6) A, Z = 8, R{sub 1} = 0.0506. In [GeO{sub 2}(OH){sub 2}]{sup 2-} anions, the Ge-O distances (1.71-1.73(1) A) are shorter than the Ge-OH distances (1.76-1.80(1) A). Anions are linked to each other by pairs of hydrogen bonds to form infinite chains. The chains are linked by hydrogen bonds involving water molecules to form a 3D structure. The assignment of the bands in the IR spectrum of the compound under study is performed. |
| doi_str_mv | 10.1134/S1063774506030096 |
| format | Article |
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V.</creatorcontrib><creatorcontrib>Spiridonov, F. M.</creatorcontrib><creatorcontrib>Zaitsev, B. E.</creatorcontrib><creatorcontrib>Tarasova, S. V.</creatorcontrib><creatorcontrib>Kosenkova, O. V.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Crystallography reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Troyanov, S. I.</au><au>Kostrikin, A. V.</au><au>Spiridonov, F. M.</au><au>Zaitsev, B. E.</au><au>Tarasova, S. V.</au><au>Kosenkova, O. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of Rb{sub 2}[GeO{sub 2}(OH){sub 2}].2H{sub 2}O</atitle><jtitle>Crystallography reports</jtitle><date>2006-05-15</date><risdate>2006</risdate><volume>51</volume><issue>3</issue><issn>1063-7745</issn><eissn>1562-689X</eissn><abstract>Single crystals of Rb{sub 2}[GeO{sub 2}(OH){sub 2}] . 2H{sub 2}O are studied by X-ray diffraction. The crystals belong to the orthorhombic system, sp. gr. Pna2{sub 1}, a = 13.523(6) A, b = 8.143(4) A, c = 13.407(6) A, Z = 8, R{sub 1} = 0.0506. In [GeO{sub 2}(OH){sub 2}]{sup 2-} anions, the Ge-O distances (1.71-1.73(1) A) are shorter than the Ge-OH distances (1.76-1.80(1) A). Anions are linked to each other by pairs of hydrogen bonds to form infinite chains. The chains are linked by hydrogen bonds involving water molecules to form a 3D structure. The assignment of the bands in the IR spectrum of the compound under study is performed.</abstract><cop>United States</cop><doi>10.1134/S1063774506030096</doi></addata></record> |
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| subjects | CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY GERMANIUM OXIDES INFRARED SPECTRA MONOCRYSTALS ORTHORHOMBIC LATTICES RUBIDIUM COMPOUNDS X-RAY DIFFRACTION |
| title | Crystal structure of Rb{sub 2}[GeO{sub 2}(OH){sub 2}].2H{sub 2}O |
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