Increasing the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) by ultraviolet irradiation

The effects of ultraviolet (UV) irradiation on the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT:PSS) have been investigated in this study. Spectroscopic methods [x-ray photoelectron spectroscopy and Raman spectroscopy ( 532 nm excitation)] and electric...

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Veröffentlicht in:Applied physics letters 2007-08, Vol.91 (9), p.092127-092127-3
Hauptverfasser: Lin, Yow-Jon, Yang, Fu-Ming, Huang, Chi-Yen, Chou, Wei-Yang, Chang, Jay, Lien, Yi-Chun
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container_end_page 092127-3
container_issue 9
container_start_page 092127
container_title Applied physics letters
container_volume 91
creator Lin, Yow-Jon
Yang, Fu-Ming
Huang, Chi-Yen
Chou, Wei-Yang
Chang, Jay
Lien, Yi-Chun
description The effects of ultraviolet (UV) irradiation on the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT:PSS) have been investigated in this study. Spectroscopic methods [x-ray photoelectron spectroscopy and Raman spectroscopy ( 532 nm excitation)] and electrical conductivity measurements were used to characterize the electrical conducting polymer PEDOT:PSS prepared by UV irradiation. The authors found that UV irradiation could lead to an increase in the work function and the enhancement of electrical conductivity of PEDOT:PSS, resulting from a decrease in the number of the charge-trapping-related defects and the formation of linear or expanded-coil conformation.
doi_str_mv 10.1063/1.2777147
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subjects DOPED MATERIALS
ELECTRIC CONDUCTIVITY
HETEROCYCLIC COMPOUNDS
IRRADIATION
MATERIALS SCIENCE
ORGANIC SEMICONDUCTORS
POLYMERS
RAMAN SPECTRA
RAMAN SPECTROSCOPY
SULFONATES
ULTRAVIOLET RADIATION
WORK FUNCTIONS
X-RAY PHOTOELECTRON SPECTROSCOPY
title Increasing the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) by ultraviolet irradiation
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