Luminescent zinc and cadmium complexes incorporating 1,3,5-benzenetricarboxylate and a protonated kinked organodiimine: From a hydrogen-bonded layer motif to thermally robust two-dimensional coordination polymers

Hydrothermal treatment of zinc chloride, 1,3,5-benzenetricarboxylic acid (H 3BTC), and 4,4′-dipyridylamine (dpa) afforded two different complexes depending on reaction conditions, which were characterized by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. Under acidi...

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Veröffentlicht in:	Journal of solid state chemistry 2007-06, Vol.180 (6), p.1852-1862
Hauptverfasser:	Braverman, Maxwell A., Supkowski, Ronald M., LaDuca, Robert L.
Format:	Artikel
Sprache:	eng
Schlagworte:	ABSORPTION SPECTROSCOPY Benzenetricarboxylate Cadmium CADMIUM COMPLEXES CADMIUM NITRATES Condensed matter: structure, mechanical and thermal properties Coordination polymer Cross-disciplinary physics: materials science rheology Crystal structure CRYSTALLOGRAPHY Dipyridylamine Exact sciences and technology HYDROTHERMAL SYNTHESIS IMINES INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LAYERS LIGANDS LUMINESCENCE Materials science MONOCLINIC LATTICES MONOCRYSTALS MORPHOLOGY Organic compounds Other materials Physics POLYMERS Single-crystal and powder diffraction Specific materials Structure of solids and liquids crystallography Structure of specific crystalline solids THERMAL GRAVIMETRIC ANALYSIS Thermogravimetric analysis ULTRAVIOLET RADIATION VISIBLE RADIATION X-RAY DIFFRACTION X-ray diffraction and scattering Zinc ZINC CHLORIDES ZINC COMPLEXES
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