Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses
Two series of metal iodide doped chalcohalide glasses (100-2x)GeS{sub 2}.xGa{sub 2}S{sub 3}.xPbI{sub 2} (0{
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| Veröffentlicht in: | Journal of solid state chemistry 2007-01, Vol.180 (1) |
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| container_title | Journal of solid state chemistry |
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| creator | Guo Haitao Tao Haizheng Gu Shaoxuan Zheng Xiaolin Zhai Yanbo Chu Saisai Zhao Xiujian Wang Shufeng Gong Qihuang |
| description | Two series of metal iodide doped chalcohalide glasses (100-2x)GeS{sub 2}.xGa{sub 2}S{sub 3}.xPbI{sub 2} (0{ |
| format | Article |
| fullrecord | <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_21015643</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>21015643</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_210156433</originalsourceid><addsrcrecordid>eNqNjbsKwjAUQIMoWB__cME5kMS22ll8bYKCbhKTWxsJifTGQcR_18EPcDlnOXA6LJOiKvhMlacuy4RQiudFVfbZgOgmhJTFPM_Y8dC41nLQwQKhicHy2FpsId6TM9pDiMG7gLp16QmxhjXyteZ7vrtsX_S4gHqDabQ38QtnEa5eEyGNWK_WnnD885BNVsvDYsMjJXcm4xKa5rsLaNJZSSGLMp9O_6s-BhpCYA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses</title><source>Elsevier ScienceDirect Journals</source><creator>Guo Haitao ; Tao Haizheng ; Gu Shaoxuan ; Zheng Xiaolin ; Zhai Yanbo ; Chu Saisai ; Zhao Xiujian ; Wang Shufeng ; Gong Qihuang</creator><creatorcontrib>Guo Haitao ; Tao Haizheng ; Gu Shaoxuan ; Zheng Xiaolin ; Zhai Yanbo ; Chu Saisai ; Zhao Xiujian ; Wang Shufeng ; Gong Qihuang</creatorcontrib><description>Two series of metal iodide doped chalcohalide glasses (100-2x)GeS{sub 2}.xGa{sub 2}S{sub 3}.xPbI{sub 2} (0{<=}x{<=}20) and (100-x)(0.8GeS{sub 2}.0.2Ga{sub 2}S{sub 3}).xPbI{sub 2} (0{<=}x{<=}15) were prepared and characterized. The microstructure of these glasses has been studied by Raman scattering spectra. Utilizing femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm, a largest third-order nonlinearity {chi} {sup (3)} of 2.07x10{sup -13} esu was obtained for the 90GeS{sub 2}.5Ga{sub 2}S{sub 3}.5PbI{sub 2} glass, and it decreases with the addition of PbI{sub 2} in both two series. After thermally poled, second-harmonic generation (SHG) has been observed in these glasses according to Maker fringe method and a large second-order nonlinearity {chi} {sup (2)} as well as 4 pm/V was obtained for the 70GeS{sub 2}.15Ga{sub 2}S{sub 3}.15PbI{sub 2} glass. The variations of {chi} {sup (2)} and {chi} {sup (3)} on glass composition are ascribed to the evolution of micro-structural units in glass. These novel chalcohalide glasses would be expected to be the promising candidate materials for nonlinear optical devices. - Graphical abstract: Second-harmonic generation (SHG) has been observed from thermally poled Ge-Ga-S-PbI{sub 2} glasses by utilizing Maker fringe method. Ultrafast third-order nonlinear optical responses of these glasses have been measured by using femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><language>eng</language><publisher>United States</publisher><subject>DOPED MATERIALS ; GALLIUM COMPOUNDS ; GERMANIUM SULFIDES ; GLASS ; HARMONIC GENERATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; KERR EFFECT ; LEAD IODIDES ; MICROSTRUCTURE ; RAMAN EFFECT ; SPECTRA ; TIME RESOLUTION</subject><ispartof>Journal of solid state chemistry, 2007-01, Vol.180 (1)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/21015643$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Guo Haitao</creatorcontrib><creatorcontrib>Tao Haizheng</creatorcontrib><creatorcontrib>Gu Shaoxuan</creatorcontrib><creatorcontrib>Zheng Xiaolin</creatorcontrib><creatorcontrib>Zhai Yanbo</creatorcontrib><creatorcontrib>Chu Saisai</creatorcontrib><creatorcontrib>Zhao Xiujian</creatorcontrib><creatorcontrib>Wang Shufeng</creatorcontrib><creatorcontrib>Gong Qihuang</creatorcontrib><title>Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses</title><title>Journal of solid state chemistry</title><description>Two series of metal iodide doped chalcohalide glasses (100-2x)GeS{sub 2}.xGa{sub 2}S{sub 3}.xPbI{sub 2} (0{<=}x{<=}20) and (100-x)(0.8GeS{sub 2}.0.2Ga{sub 2}S{sub 3}).xPbI{sub 2} (0{<=}x{<=}15) were prepared and characterized. The microstructure of these glasses has been studied by Raman scattering spectra. Utilizing femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm, a largest third-order nonlinearity {chi} {sup (3)} of 2.07x10{sup -13} esu was obtained for the 90GeS{sub 2}.5Ga{sub 2}S{sub 3}.5PbI{sub 2} glass, and it decreases with the addition of PbI{sub 2} in both two series. After thermally poled, second-harmonic generation (SHG) has been observed in these glasses according to Maker fringe method and a large second-order nonlinearity {chi} {sup (2)} as well as 4 pm/V was obtained for the 70GeS{sub 2}.15Ga{sub 2}S{sub 3}.15PbI{sub 2} glass. The variations of {chi} {sup (2)} and {chi} {sup (3)} on glass composition are ascribed to the evolution of micro-structural units in glass. These novel chalcohalide glasses would be expected to be the promising candidate materials for nonlinear optical devices. - Graphical abstract: Second-harmonic generation (SHG) has been observed from thermally poled Ge-Ga-S-PbI{sub 2} glasses by utilizing Maker fringe method. Ultrafast third-order nonlinear optical responses of these glasses have been measured by using femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm.</description><subject>DOPED MATERIALS</subject><subject>GALLIUM COMPOUNDS</subject><subject>GERMANIUM SULFIDES</subject><subject>GLASS</subject><subject>HARMONIC GENERATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>KERR EFFECT</subject><subject>LEAD IODIDES</subject><subject>MICROSTRUCTURE</subject><subject>RAMAN EFFECT</subject><subject>SPECTRA</subject><subject>TIME RESOLUTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqNjbsKwjAUQIMoWB__cME5kMS22ll8bYKCbhKTWxsJifTGQcR_18EPcDlnOXA6LJOiKvhMlacuy4RQiudFVfbZgOgmhJTFPM_Y8dC41nLQwQKhicHy2FpsId6TM9pDiMG7gLp16QmxhjXyteZ7vrtsX_S4gHqDabQ38QtnEa5eEyGNWK_WnnD885BNVsvDYsMjJXcm4xKa5rsLaNJZSSGLMp9O_6s-BhpCYA</recordid><startdate>20070115</startdate><enddate>20070115</enddate><creator>Guo Haitao</creator><creator>Tao Haizheng</creator><creator>Gu Shaoxuan</creator><creator>Zheng Xiaolin</creator><creator>Zhai Yanbo</creator><creator>Chu Saisai</creator><creator>Zhao Xiujian</creator><creator>Wang Shufeng</creator><creator>Gong Qihuang</creator><scope>OTOTI</scope></search><sort><creationdate>20070115</creationdate><title>Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses</title><author>Guo Haitao ; Tao Haizheng ; Gu Shaoxuan ; Zheng Xiaolin ; Zhai Yanbo ; Chu Saisai ; Zhao Xiujian ; Wang Shufeng ; Gong Qihuang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_210156433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>DOPED MATERIALS</topic><topic>GALLIUM COMPOUNDS</topic><topic>GERMANIUM SULFIDES</topic><topic>GLASS</topic><topic>HARMONIC GENERATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>KERR EFFECT</topic><topic>LEAD IODIDES</topic><topic>MICROSTRUCTURE</topic><topic>RAMAN EFFECT</topic><topic>SPECTRA</topic><topic>TIME RESOLUTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo Haitao</creatorcontrib><creatorcontrib>Tao Haizheng</creatorcontrib><creatorcontrib>Gu Shaoxuan</creatorcontrib><creatorcontrib>Zheng Xiaolin</creatorcontrib><creatorcontrib>Zhai Yanbo</creatorcontrib><creatorcontrib>Chu Saisai</creatorcontrib><creatorcontrib>Zhao Xiujian</creatorcontrib><creatorcontrib>Wang Shufeng</creatorcontrib><creatorcontrib>Gong Qihuang</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo Haitao</au><au>Tao Haizheng</au><au>Gu Shaoxuan</au><au>Zheng Xiaolin</au><au>Zhai Yanbo</au><au>Chu Saisai</au><au>Zhao Xiujian</au><au>Wang Shufeng</au><au>Gong Qihuang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2007-01-15</date><risdate>2007</risdate><volume>180</volume><issue>1</issue><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>Two series of metal iodide doped chalcohalide glasses (100-2x)GeS{sub 2}.xGa{sub 2}S{sub 3}.xPbI{sub 2} (0{<=}x{<=}20) and (100-x)(0.8GeS{sub 2}.0.2Ga{sub 2}S{sub 3}).xPbI{sub 2} (0{<=}x{<=}15) were prepared and characterized. The microstructure of these glasses has been studied by Raman scattering spectra. Utilizing femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm, a largest third-order nonlinearity {chi} {sup (3)} of 2.07x10{sup -13} esu was obtained for the 90GeS{sub 2}.5Ga{sub 2}S{sub 3}.5PbI{sub 2} glass, and it decreases with the addition of PbI{sub 2} in both two series. After thermally poled, second-harmonic generation (SHG) has been observed in these glasses according to Maker fringe method and a large second-order nonlinearity {chi} {sup (2)} as well as 4 pm/V was obtained for the 70GeS{sub 2}.15Ga{sub 2}S{sub 3}.15PbI{sub 2} glass. The variations of {chi} {sup (2)} and {chi} {sup (3)} on glass composition are ascribed to the evolution of micro-structural units in glass. These novel chalcohalide glasses would be expected to be the promising candidate materials for nonlinear optical devices. - Graphical abstract: Second-harmonic generation (SHG) has been observed from thermally poled Ge-Ga-S-PbI{sub 2} glasses by utilizing Maker fringe method. Ultrafast third-order nonlinear optical responses of these glasses have been measured by using femtosecond time-resolved optical Kerr effect (OKE) technique at the wavelength of 820 nm.</abstract><cop>United States</cop></addata></record> |
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| subjects | DOPED MATERIALS GALLIUM COMPOUNDS GERMANIUM SULFIDES GLASS HARMONIC GENERATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KERR EFFECT LEAD IODIDES MICROSTRUCTURE RAMAN EFFECT SPECTRA TIME RESOLUTION |
| title | Third- and second-order optical nonlinearity of Ge-Ga-S-PbI{sub 2} chalcohalide glasses |
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