Syntheses of the new compounds NaBi{sub 6}O{sub 9}X (X = Br, I) and the mixed systems Na{sub 0.77(3)}K{sub 0.23(3)}Bi{sub 6}O{sub 9}I, Rb{sub 0.91(3)}K{sub 0.05(1)}Na{sub 0.04(2)}Bi{sub 6}O{sub 9}Br and Rb{sub 0.89(4)}K{sub 0.05(1)}Na{sub 0.06(3)}Bi{sub 6}O{sub 9}I
The new compounds NaBi{sub 6}O{sub 9}X (X = Br, I) were synthesized. Attempts to synthesize the analogous RbBi{sub 6}O{sub 9}X (X = Br, I) compounds yielded mixed systems with about 10% of the Rb atoms replaced by Na and K atoms. Another mixed system, Na{sub 0.77(3)}K{sub 0.23(3)}Bi{sub 6}O{sub 9}I,...
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| Veröffentlicht in: | Materials research bulletin 2007-08, Vol.42 (8) |
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| creator | Keller, Egbert Kraemer, Volker Meyer, Clemens A. |
| description | The new compounds NaBi{sub 6}O{sub 9}X (X = Br, I) were synthesized. Attempts to synthesize the analogous RbBi{sub 6}O{sub 9}X (X = Br, I) compounds yielded mixed systems with about 10% of the Rb atoms replaced by Na and K atoms. Another mixed system, Na{sub 0.77(3)}K{sub 0.23(3)}Bi{sub 6}O{sub 9}I, was obtained incidentally. The corresponding ABi{sub 6}O{sub 9}X compounds with X = Cl or A = Cs could not be obtained. The influence of A and X on the size of the ABi{sub 6}O{sub 9}X unit cell is discussed. |
| doi_str_mv | 10.1016/j.materresbull.2006.11.044 |
| format | Article |
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Attempts to synthesize the analogous RbBi{sub 6}O{sub 9}X (X = Br, I) compounds yielded mixed systems with about 10% of the Rb atoms replaced by Na and K atoms. Another mixed system, Na{sub 0.77(3)}K{sub 0.23(3)}Bi{sub 6}O{sub 9}I, was obtained incidentally. The corresponding ABi{sub 6}O{sub 9}X compounds with X = Cl or A = Cs could not be obtained. The influence of A and X on the size of the ABi{sub 6}O{sub 9}X unit cell is discussed.</abstract><cop>United States</cop><doi>10.1016/j.materresbull.2006.11.044</doi></addata></record> |
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| issn | 0025-5408 1873-4227 |
| language | eng |
| recordid | cdi_osti_scitechconnect_21000677 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | BISMUTH OXIDES CHEMICAL PREPARATION CRYSTALS HALIDES IODINE COMPOUNDS MATERIALS SCIENCE SODIUM OXIDES X-RAY DIFFRACTION |
| title | Syntheses of the new compounds NaBi{sub 6}O{sub 9}X (X = Br, I) and the mixed systems Na{sub 0.77(3)}K{sub 0.23(3)}Bi{sub 6}O{sub 9}I, Rb{sub 0.91(3)}K{sub 0.05(1)}Na{sub 0.04(2)}Bi{sub 6}O{sub 9}Br and Rb{sub 0.89(4)}K{sub 0.05(1)}Na{sub 0.06(3)}Bi{sub 6}O{sub 9}I |
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