Understanding Mercury Transformations in Coal-Fired Power Plants: Evaluation of Homogeneous Hg Oxidation Mechanisms

Homogeneous mercury oxidation mechanisms described by Niksa and Qiu, and three theoretical mercury oxidation reaction rate constants developed by Wilcox were evaluated for their predictions of the extent of mercury oxidation under coal combustion conditions. Predictions were compared to results from...

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Veröffentlicht in:	Environmental science & technology 2007-11, Vol.41 (22), p.7870-7875
Hauptverfasser:	Krishnakumar, Balaji, Helble, Joseph J
Format:	Artikel
Sprache:	eng
Schlagworte:	01 COAL, LIGNITE, AND PEAT Air Pollutants - analysis Air Pollution Applied sciences Atmospheric pollution BENCH-SCALE EXPERIMENTS CHEMICAL REACTION KINETICS CHLORINE Chlorine - chemistry COAL Coal-fired power plants Combustion and energy production Environmental Monitoring - methods Environmental Pollution Environmental science Exact sciences and technology FLUE GAS FORECASTING FOSSIL-FUEL POWER PLANTS HYDROCHLORIC ACID MERCURY Mercury - analysis Models, Chemical OXIDATION Oxygen - chemistry Oxygen - metabolism Pollution Pollution sources. Measurement results Power Plants Reproducibility of Results SULFUR DIOXIDE Temperature Time Factors
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