Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine
In this paper, treatment of N-ethyl-benzo[f]quinolium (ebq) iodide and CuI with excess KI afforded an unusual coordination polymer [(ebq) 2(Cu 3I 4)(CuI 2)] n ( 1). 1 crystallizes in tetragonal system, space group P4(2) bc with cell parameters of a = 23.2040 ( 6 ) Å , c = 6.7393 ( 3 ) Å , V = 3628.6...
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| Veröffentlicht in: | Journal of solid state chemistry 2006-05, Vol.179 (5), p.1415-1420 |
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| creator | Li, Hao-Hong Chen, Zhi-Rong Li, Jun-Qian Zhan, Hong-Bing Zhang, Wen-Xuan Huang, Chang-Cang Ma, Cheng Zhao, Bin |
| description | In this paper, treatment of
N-ethyl-benzo[f]quinolium (ebq) iodide and CuI with excess KI afforded an unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1).
1 crystallizes in tetragonal system, space group
P4(2)
bc with cell parameters of
a
=
23.2040
(
6
)
Å
,
c
=
6.7393
(
3
)
Å
,
V
=
3628.6
(
2
)
Å
3
,
Z
=
8
,
D
c
=
2.622
g
/
c
3
,
R
1
=
0.0447
and
w
R
2
=
0.0974
. A highly interesting feature of
1 is its presence of mixed types of chains [
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. Furthermore, IR, EA, UV–Vis, thermal analysis and optical limiting measurements were adopted to characterize polymer
1. The optical limiting experiment shows that the present polymer exhibits a large optical limiting capacity.
An unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1) has been synthesized and characterized. A highly interesting feature of
1 is its presence of mixed types of chains [
(
C
u
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. The optical limiting experiments show that the present polymer exhibits a large optical limiting capacity. |
| doi_str_mv | 10.1016/j.jssc.2006.01.075 |
| format | Article |
| fullrecord | <record><control><sourceid>elsevier_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_20785005</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022459606000661</els_id><sourcerecordid>S0022459606000661</sourcerecordid><originalsourceid>FETCH-LOGICAL-c358t-ea3fe965f5941834974f05717961e61b7cad13316b73baa897083428a6eaa4063</originalsourceid><addsrcrecordid>eNp9kMGKFDEQhhtRcFx9AU8BERS2eyvdnaQbvMii68KCBxW8hUy6slNDT9Ik2cW5efbqG_okppkFb56SwPdX_vqq6iWHhgOXF_tmn5JtWgDZAG9AiUfVhsMoatXK74-rDUDb1r0Y5dPqWUp7AM7F0G-qX1-OPu8wUTpnKcc7m-8iMuMnFpZM1sxspgNl8rcMnUObWXDMMB_ucWbkQ7w1nuyfn78fbmx33Eaa2BLm4wEjs8FnQ37NH-gHTszuyjOtU2xYFoxvrt9eUJjI4_PqiTNzwhcP51n17eOHr5ef6pvPV9eX729q24kh12g6h6MUTow9H7p-VL0DobgaJUfJt8qaiXcdl1vVbY0ZRgWFagcj0ZgeZHdWvTrNDSmTTpYy2l3p6ct2ugU1CABRqPZE2RhSiuj0Eulg4lFz0Ktzvderc70618B1cV5Cr0-hxaTizkXjLaV_SaUGPoqhcO9OHJY97wnjWgO9xYni2mIK9L9v_gJtNppN</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Li, Hao-Hong ; Chen, Zhi-Rong ; Li, Jun-Qian ; Zhan, Hong-Bing ; Zhang, Wen-Xuan ; Huang, Chang-Cang ; Ma, Cheng ; Zhao, Bin</creator><creatorcontrib>Li, Hao-Hong ; Chen, Zhi-Rong ; Li, Jun-Qian ; Zhan, Hong-Bing ; Zhang, Wen-Xuan ; Huang, Chang-Cang ; Ma, Cheng ; Zhao, Bin</creatorcontrib><description>In this paper, treatment of
N-ethyl-benzo[f]quinolium (ebq) iodide and CuI with excess KI afforded an unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1).
1 crystallizes in tetragonal system, space group
P4(2)
bc with cell parameters of
a
=
23.2040
(
6
)
Å
,
c
=
6.7393
(
3
)
Å
,
V
=
3628.6
(
2
)
Å
3
,
Z
=
8
,
D
c
=
2.622
g
/
c
3
,
R
1
=
0.0447
and
w
R
2
=
0.0974
. A highly interesting feature of
1 is its presence of mixed types of chains [
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. Furthermore, IR, EA, UV–Vis, thermal analysis and optical limiting measurements were adopted to characterize polymer
1. The optical limiting experiment shows that the present polymer exhibits a large optical limiting capacity.
An unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1) has been synthesized and characterized. A highly interesting feature of
1 is its presence of mixed types of chains [
(
C
u
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. The optical limiting experiments show that the present polymer exhibits a large optical limiting capacity.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2006.01.075</identifier><identifier>CODEN: JSSCBI</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>CATIONS ; Condensed matter: structure, mechanical and thermal properties ; Coordination polymers ; COPPER COMPLEXES ; COPPER IODIDES ; copper(I) iodide ; Cross-disciplinary physics: materials science; rheology ; CRYSTAL LATTICES ; Exact sciences and technology ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; Materials science ; Methods of nanofabrication ; optical limiting effect ; organic–inorganic hybrid ; Physics ; POLYMERS ; POTASSIUM IODIDES ; Self-assembly ; SPACE GROUPS ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; SYNTHESIS ; THERMAL ANALYSIS</subject><ispartof>Journal of solid state chemistry, 2006-05, Vol.179 (5), p.1415-1420</ispartof><rights>2006 Elsevier Inc.</rights><rights>2007 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-ea3fe965f5941834974f05717961e61b7cad13316b73baa897083428a6eaa4063</citedby><cites>FETCH-LOGICAL-c358t-ea3fe965f5941834974f05717961e61b7cad13316b73baa897083428a6eaa4063</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jssc.2006.01.075$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17781958$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/20785005$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Hao-Hong</creatorcontrib><creatorcontrib>Chen, Zhi-Rong</creatorcontrib><creatorcontrib>Li, Jun-Qian</creatorcontrib><creatorcontrib>Zhan, Hong-Bing</creatorcontrib><creatorcontrib>Zhang, Wen-Xuan</creatorcontrib><creatorcontrib>Huang, Chang-Cang</creatorcontrib><creatorcontrib>Ma, Cheng</creatorcontrib><creatorcontrib>Zhao, Bin</creatorcontrib><title>Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine</title><title>Journal of solid state chemistry</title><description>In this paper, treatment of
N-ethyl-benzo[f]quinolium (ebq) iodide and CuI with excess KI afforded an unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1).
1 crystallizes in tetragonal system, space group
P4(2)
bc with cell parameters of
a
=
23.2040
(
6
)
Å
,
c
=
6.7393
(
3
)
Å
,
V
=
3628.6
(
2
)
Å
3
,
Z
=
8
,
D
c
=
2.622
g
/
c
3
,
R
1
=
0.0447
and
w
R
2
=
0.0974
. A highly interesting feature of
1 is its presence of mixed types of chains [
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. Furthermore, IR, EA, UV–Vis, thermal analysis and optical limiting measurements were adopted to characterize polymer
1. The optical limiting experiment shows that the present polymer exhibits a large optical limiting capacity.
An unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1) has been synthesized and characterized. A highly interesting feature of
1 is its presence of mixed types of chains [
(
C
u
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. The optical limiting experiments show that the present polymer exhibits a large optical limiting capacity.</description><subject>CATIONS</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Coordination polymers</subject><subject>COPPER COMPLEXES</subject><subject>COPPER IODIDES</subject><subject>copper(I) iodide</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>CRYSTAL LATTICES</subject><subject>Exact sciences and technology</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Materials science</subject><subject>Methods of nanofabrication</subject><subject>optical limiting effect</subject><subject>organic–inorganic hybrid</subject><subject>Physics</subject><subject>POLYMERS</subject><subject>POTASSIUM IODIDES</subject><subject>Self-assembly</subject><subject>SPACE GROUPS</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>SYNTHESIS</subject><subject>THERMAL ANALYSIS</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNp9kMGKFDEQhhtRcFx9AU8BERS2eyvdnaQbvMii68KCBxW8hUy6slNDT9Ik2cW5efbqG_okppkFb56SwPdX_vqq6iWHhgOXF_tmn5JtWgDZAG9AiUfVhsMoatXK74-rDUDb1r0Y5dPqWUp7AM7F0G-qX1-OPu8wUTpnKcc7m-8iMuMnFpZM1sxspgNl8rcMnUObWXDMMB_ucWbkQ7w1nuyfn78fbmx33Eaa2BLm4wEjs8FnQ37NH-gHTszuyjOtU2xYFoxvrt9eUJjI4_PqiTNzwhcP51n17eOHr5ef6pvPV9eX729q24kh12g6h6MUTow9H7p-VL0DobgaJUfJt8qaiXcdl1vVbY0ZRgWFagcj0ZgeZHdWvTrNDSmTTpYy2l3p6ct2ugU1CABRqPZE2RhSiuj0Eulg4lFz0Ktzvderc70618B1cV5Cr0-hxaTizkXjLaV_SaUGPoqhcO9OHJY97wnjWgO9xYni2mIK9L9v_gJtNppN</recordid><startdate>20060501</startdate><enddate>20060501</enddate><creator>Li, Hao-Hong</creator><creator>Chen, Zhi-Rong</creator><creator>Li, Jun-Qian</creator><creator>Zhan, Hong-Bing</creator><creator>Zhang, Wen-Xuan</creator><creator>Huang, Chang-Cang</creator><creator>Ma, Cheng</creator><creator>Zhao, Bin</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20060501</creationdate><title>Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine</title><author>Li, Hao-Hong ; Chen, Zhi-Rong ; Li, Jun-Qian ; Zhan, Hong-Bing ; Zhang, Wen-Xuan ; Huang, Chang-Cang ; Ma, Cheng ; Zhao, Bin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-ea3fe965f5941834974f05717961e61b7cad13316b73baa897083428a6eaa4063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>CATIONS</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Coordination polymers</topic><topic>COPPER COMPLEXES</topic><topic>COPPER IODIDES</topic><topic>copper(I) iodide</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>CRYSTAL LATTICES</topic><topic>Exact sciences and technology</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Materials science</topic><topic>Methods of nanofabrication</topic><topic>optical limiting effect</topic><topic>organic–inorganic hybrid</topic><topic>Physics</topic><topic>POLYMERS</topic><topic>POTASSIUM IODIDES</topic><topic>Self-assembly</topic><topic>SPACE GROUPS</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>SYNTHESIS</topic><topic>THERMAL ANALYSIS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Hao-Hong</creatorcontrib><creatorcontrib>Chen, Zhi-Rong</creatorcontrib><creatorcontrib>Li, Jun-Qian</creatorcontrib><creatorcontrib>Zhan, Hong-Bing</creatorcontrib><creatorcontrib>Zhang, Wen-Xuan</creatorcontrib><creatorcontrib>Huang, Chang-Cang</creatorcontrib><creatorcontrib>Ma, Cheng</creatorcontrib><creatorcontrib>Zhao, Bin</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Hao-Hong</au><au>Chen, Zhi-Rong</au><au>Li, Jun-Qian</au><au>Zhan, Hong-Bing</au><au>Zhang, Wen-Xuan</au><au>Huang, Chang-Cang</au><au>Ma, Cheng</au><au>Zhao, Bin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2006-05-01</date><risdate>2006</risdate><volume>179</volume><issue>5</issue><spage>1415</spage><epage>1420</epage><pages>1415-1420</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><coden>JSSCBI</coden><abstract>In this paper, treatment of
N-ethyl-benzo[f]quinolium (ebq) iodide and CuI with excess KI afforded an unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1).
1 crystallizes in tetragonal system, space group
P4(2)
bc with cell parameters of
a
=
23.2040
(
6
)
Å
,
c
=
6.7393
(
3
)
Å
,
V
=
3628.6
(
2
)
Å
3
,
Z
=
8
,
D
c
=
2.622
g
/
c
3
,
R
1
=
0.0447
and
w
R
2
=
0.0974
. A highly interesting feature of
1 is its presence of mixed types of chains [
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. Furthermore, IR, EA, UV–Vis, thermal analysis and optical limiting measurements were adopted to characterize polymer
1. The optical limiting experiment shows that the present polymer exhibits a large optical limiting capacity.
An unusual coordination polymer [(ebq)
2(Cu
3I
4)(CuI
2)]
n
(
1) has been synthesized and characterized. A highly interesting feature of
1 is its presence of mixed types of chains [
(
C
u
3
I
4
)
n
-
and
(
CuI
2
)
n
-
chain] in one crystal lattice based on supramolecular self-assembly directed by cations. The infinite chains
(
Cu
3
I
4
)
n
-
and
(
CuI
2
)
n
-
in
1 could be described as the edge-sharing arrangement of CuI
4 tetrahedron. The optical limiting experiments show that the present polymer exhibits a large optical limiting capacity.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2006.01.075</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4596 |
| ispartof | Journal of solid state chemistry, 2006-05, Vol.179 (5), p.1415-1420 |
| issn | 0022-4596 1095-726X |
| language | eng |
| recordid | cdi_osti_scitechconnect_20785005 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | CATIONS Condensed matter: structure, mechanical and thermal properties Coordination polymers COPPER COMPLEXES COPPER IODIDES copper(I) iodide Cross-disciplinary physics: materials science rheology CRYSTAL LATTICES Exact sciences and technology INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Materials science Methods of nanofabrication optical limiting effect organic–inorganic hybrid Physics POLYMERS POTASSIUM IODIDES Self-assembly SPACE GROUPS Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS THERMAL ANALYSIS |
| title | Synthesis, structure and optical limiting effect of a novel inorganic–organic hybrid polymer containing mixed chains of copper(I)/iodine |
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