Preparation of hollow carbon nanospheres at low temperature via new reaction route
Hollow carbon nanospheres were obtained at 200 °C via a new reaction route, by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. The products were characterized with X-ray diffraction pattern, transmission electron microscope, high-resolution tr...
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| Veröffentlicht in: | Journal of solid state chemistry 2005-03, Vol.178 (3), p.908-911 |
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| container_end_page | 911 |
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| container_issue | 3 |
| container_start_page | 908 |
| container_title | Journal of solid state chemistry |
| container_volume | 178 |
| creator | Ni, Youbao Shao, Mingwang Tong, Yanhua Qian, Guixiang Wei, Xianwen |
| description | Hollow carbon nanospheres were obtained at 200
°C via a new reaction route, by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. The products were characterized with X-ray diffraction pattern, transmission electron microscope, high-resolution transmission electron microscope images and Raman spectrum. The reaction conditions are easy to be maintained and controlled. They may provide a new method to produce other carbonaceous materials. A possible mechanism of reaction was proposed.
C
2
Cl
6
+
Mg
⟶
AlCl
3
C
+
MgCl
2
.
Hollow carbon nanospheres are prepared at 200
°C for 12
h by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. A possible mechanism of the formation is proposed under experimental results. |
| doi_str_mv | 10.1016/j.jssc.2004.12.008 |
| format | Article |
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°C via a new reaction route, by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. The products were characterized with X-ray diffraction pattern, transmission electron microscope, high-resolution transmission electron microscope images and Raman spectrum. The reaction conditions are easy to be maintained and controlled. They may provide a new method to produce other carbonaceous materials. A possible mechanism of reaction was proposed.
C
2
Cl
6
+
Mg
⟶
AlCl
3
C
+
MgCl
2
.
Hollow carbon nanospheres are prepared at 200
°C for 12
h by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. A possible mechanism of the formation is proposed under experimental results.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/j.jssc.2004.12.008</identifier><identifier>CODEN: JSSCBI</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>ALUMINIUM CHLORIDES ; CARBON ; CARBONACEOUS MATERIALS ; Chemical synthesis ; Chemical synthesis methods ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Grignard reagent ; GRIGNARD REAGENTS ; Hollow carbon nanospheres ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MAGNESIUM ; Materials science ; Methods of nanofabrication ; Nanostructure ; NANOSTRUCTURES ; Physics ; RAMAN SPECTRA ; SYNTHESIS ; TRANSMISSION ELECTRON MICROSCOPY ; X-RAY DIFFRACTION</subject><ispartof>Journal of solid state chemistry, 2005-03, Vol.178 (3), p.908-911</ispartof><rights>2004 Elsevier Inc.</rights><rights>2005 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-5f6604f95b9565b4f3dc8e9b3326845498f14106b7c466bcba10e9d6828ac3033</citedby><cites>FETCH-LOGICAL-c358t-5f6604f95b9565b4f3dc8e9b3326845498f14106b7c466bcba10e9d6828ac3033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022459604006474$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16654437$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/20725852$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ni, Youbao</creatorcontrib><creatorcontrib>Shao, Mingwang</creatorcontrib><creatorcontrib>Tong, Yanhua</creatorcontrib><creatorcontrib>Qian, Guixiang</creatorcontrib><creatorcontrib>Wei, Xianwen</creatorcontrib><title>Preparation of hollow carbon nanospheres at low temperature via new reaction route</title><title>Journal of solid state chemistry</title><description>Hollow carbon nanospheres were obtained at 200
°C via a new reaction route, by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. The products were characterized with X-ray diffraction pattern, transmission electron microscope, high-resolution transmission electron microscope images and Raman spectrum. The reaction conditions are easy to be maintained and controlled. They may provide a new method to produce other carbonaceous materials. A possible mechanism of reaction was proposed.
C
2
Cl
6
+
Mg
⟶
AlCl
3
C
+
MgCl
2
.
Hollow carbon nanospheres are prepared at 200
°C for 12
h by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. A possible mechanism of the formation is proposed under experimental results.</description><subject>ALUMINIUM CHLORIDES</subject><subject>CARBON</subject><subject>CARBONACEOUS MATERIALS</subject><subject>Chemical synthesis</subject><subject>Chemical synthesis methods</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Grignard reagent</subject><subject>GRIGNARD REAGENTS</subject><subject>Hollow carbon nanospheres</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MAGNESIUM</subject><subject>Materials science</subject><subject>Methods of nanofabrication</subject><subject>Nanostructure</subject><subject>NANOSTRUCTURES</subject><subject>Physics</subject><subject>RAMAN SPECTRA</subject><subject>SYNTHESIS</subject><subject>TRANSMISSION ELECTRON MICROSCOPY</subject><subject>X-RAY DIFFRACTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AU8F8dg6SZNsCl5k8R8sKKLgLaTZKZvSbUrS3cVvb2sFb54GZn5v5s0j5JJCRoHKmzqrY7QZA-AZZRmAOiIzCoVIF0x-HpMZAGMpF4U8JWcx1gCUCsVn5O01YGeC6Z1vE18lG980_pBYE8qh0ZrWx26DAWNi-mSc9LjtcOB3AZO9M0mLhySgsT8Lgt_1eE5OKtNEvPitc_LxcP--fEpXL4_Py7tVanOh-lRUUgKvClEWQoqSV_naKizKPGdSccELVVFOQZYLy6UsbWkoYLGWiiljc8jzObma9vrYOx2t69FurG9btL1msGBCCTZQbKJs8DEGrHQX3NaEL01Bj9npWo_Z6TE7TZkeshtE15OoM9GapgqmtS7-KaUUnOeLgbudOBz-3DsMow1sLa5dGF2svfvvzDcj1YTp</recordid><startdate>20050301</startdate><enddate>20050301</enddate><creator>Ni, Youbao</creator><creator>Shao, Mingwang</creator><creator>Tong, Yanhua</creator><creator>Qian, Guixiang</creator><creator>Wei, Xianwen</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20050301</creationdate><title>Preparation of hollow carbon nanospheres at low temperature via new reaction route</title><author>Ni, Youbao ; Shao, Mingwang ; Tong, Yanhua ; Qian, Guixiang ; Wei, Xianwen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-5f6604f95b9565b4f3dc8e9b3326845498f14106b7c466bcba10e9d6828ac3033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>ALUMINIUM CHLORIDES</topic><topic>CARBON</topic><topic>CARBONACEOUS MATERIALS</topic><topic>Chemical synthesis</topic><topic>Chemical synthesis methods</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Grignard reagent</topic><topic>GRIGNARD REAGENTS</topic><topic>Hollow carbon nanospheres</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MAGNESIUM</topic><topic>Materials science</topic><topic>Methods of nanofabrication</topic><topic>Nanostructure</topic><topic>NANOSTRUCTURES</topic><topic>Physics</topic><topic>RAMAN SPECTRA</topic><topic>SYNTHESIS</topic><topic>TRANSMISSION ELECTRON MICROSCOPY</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ni, Youbao</creatorcontrib><creatorcontrib>Shao, Mingwang</creatorcontrib><creatorcontrib>Tong, Yanhua</creatorcontrib><creatorcontrib>Qian, Guixiang</creatorcontrib><creatorcontrib>Wei, Xianwen</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ni, Youbao</au><au>Shao, Mingwang</au><au>Tong, Yanhua</au><au>Qian, Guixiang</au><au>Wei, Xianwen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of hollow carbon nanospheres at low temperature via new reaction route</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2005-03-01</date><risdate>2005</risdate><volume>178</volume><issue>3</issue><spage>908</spage><epage>911</epage><pages>908-911</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><coden>JSSCBI</coden><abstract>Hollow carbon nanospheres were obtained at 200
°C via a new reaction route, by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. The products were characterized with X-ray diffraction pattern, transmission electron microscope, high-resolution transmission electron microscope images and Raman spectrum. The reaction conditions are easy to be maintained and controlled. They may provide a new method to produce other carbonaceous materials. A possible mechanism of reaction was proposed.
C
2
Cl
6
+
Mg
⟶
AlCl
3
C
+
MgCl
2
.
Hollow carbon nanospheres are prepared at 200
°C for 12
h by using magnesium, hexachloroethane and aluminum trichloride as starting materials and benzene as solvent. A possible mechanism of the formation is proposed under experimental results.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1016/j.jssc.2004.12.008</doi><tpages>4</tpages></addata></record> |
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| ispartof | Journal of solid state chemistry, 2005-03, Vol.178 (3), p.908-911 |
| issn | 0022-4596 1095-726X |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | ALUMINIUM CHLORIDES CARBON CARBONACEOUS MATERIALS Chemical synthesis Chemical synthesis methods Cross-disciplinary physics: materials science rheology Exact sciences and technology Grignard reagent GRIGNARD REAGENTS Hollow carbon nanospheres INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MAGNESIUM Materials science Methods of nanofabrication Nanostructure NANOSTRUCTURES Physics RAMAN SPECTRA SYNTHESIS TRANSMISSION ELECTRON MICROSCOPY X-RAY DIFFRACTION |
| title | Preparation of hollow carbon nanospheres at low temperature via new reaction route |
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