Infrared absorption and electron paramagnetic resonance studies of vinyl radical in noble-gas matrices

Vinyl radicals produced by annealing-induced reaction of mobilized hydrogen atoms with acetylene molecules in solid noble-gas matrices (Ar, Kr, and Xe) were characterized by Fourier transform infrared and electron paramagnetic resonance (EPR) spectroscopies. The hydrogen atoms were generated from ac...

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Veröffentlicht in:	The Journal of chemical physics 2005-08, Vol.123 (6), p.64318-64318
Hauptverfasser:	Tanskanen, Hanna, Khriachtchev, Leonid, Räsänen, Markku, Feldman, Vladimir I, Sukhov, Fedor F, Orlov, Aleksei Yu, Tyurin, Daniil A
Format:	Artikel
Sprache:	eng
Schlagworte:	ABSORPTION ACETYLENE ANNEALING ATOM-MOLECULE COLLISIONS CARBON 13 DENSITY FUNCTIONAL METHOD DEUTERIUM ELECTRON SPIN RESONANCE FOURIER TRANSFORMATION HYDROGEN INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRRADIATION ISOTOPE EFFECTS ISOTOPIC EXCHANGE PHOTOLYSIS RARE GASES SPECTROSCOPY VIBRATIONAL STATES VINYL RADICALS
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