Reaction mechanism and kinetics of the NCN+NO reaction: comparison of theory and experiment

The rate constants for the NCN + NO reaction have been measured by laser photolysis/laser-induced fluorescence technique in the temperature range of 254-353 K in the presence of He (40-600 Torr) and N2 (30-528 Torr) buffer gases. The NCN radical was produced from the photodissociation of NCN3 at 193...

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Veröffentlicht in:	The Journal of chemical physics 2005-05, Vol.122 (18), p.184321-184321
Hauptverfasser:	Huang, Chih-Liang, Tseng, Shiang Yang, Wang, Tzu Yi, Wang, Niann S, Xu, Z F, Lin, M C
Format:	Artikel
Sprache:	eng
Schlagworte:	AZIDES COMPARATIVE EVALUATIONS DISSOCIATION DYE LASERS FLUORESCENCE FRAGMENTATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOMERS MOLECULE-MOLECULE COLLISIONS NITROUS OXIDE PHOTOLUMINESCENCE PHOTOLYSIS POTENTIAL ENERGY PRESSURE DEPENDENCE RADICALS REACTION KINETICS TEMPERATURE DEPENDENCE TEMPERATURE RANGE 0065-0273 K TEMPERATURE RANGE 0273-0400 K
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