Effects of focal volume and spatial inhomogeneity on uncertainty in single-aerosol laser-induced breakdown spectroscopy measurements

Particle location with respect to the plasma volume and the focal volume of the collection optics is identified as an important source of uncertainty in single-aerosol laser-induced breakdown spectroscopy (LIBS) measurements. Two sets of optics were used to image different regions of a LIBS plasma a...

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Veröffentlicht in:Applied physics letters 2005-07, Vol.87 (1)
Hauptverfasser: Lithgow, G. A., Buckley, S. G.
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description Particle location with respect to the plasma volume and the focal volume of the collection optics is identified as an important source of uncertainty in single-aerosol laser-induced breakdown spectroscopy (LIBS) measurements. Two sets of optics were used to image different regions of a LIBS plasma and simultaneously collect spectra from single particles. Strong variation and lack of correlation between the two measurement channels suggest that emission from a single particle is localized within the plasma. Measurement precision and detection efficiency were improved by imaging a larger plasma region, thus integrating the spatially distributed signal.
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1077-3118
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source AIP Journals Complete; AIP Digital Archive
subjects 70 PLASMA PHYSICS AND FUSION TECHNOLOGY
AEROSOLS
BREAKDOWN
CORRELATIONS
LASERS
OPTICS
PARTICLES
PLASMA
PLASMA DIAGNOSTICS
PLASMA PRODUCTION
SPECTROSCOPY
title Effects of focal volume and spatial inhomogeneity on uncertainty in single-aerosol laser-induced breakdown spectroscopy measurements
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