Electron scattering on stored mononucleotide anions

Collisions between electrons and deprotonated mononucleotides, AMP and UMP, were studied at the electrostatic storage ring ELISA where the two anions were stored with a 1/e lifetime of 13.5 s. It is found that the threshold energy for electron-induced reactions leading to production of neutral fragm...

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Veröffentlicht in:Physical review. A, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2004-08, Vol.70 (2), Article 020701
Hauptverfasser: Bluhme, H., Jensen, M. J., Nielsen, S. Brøndsted, Pedersen, U. V., Seiersen, K., Svendsen, A., Andersen, L. H.
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container_title Physical review. A, Atomic, molecular, and optical physics
container_volume 70
creator Bluhme, H.
Jensen, M. J.
Nielsen, S. Brøndsted
Pedersen, U. V.
Seiersen, K.
Svendsen, A.
Andersen, L. H.
description Collisions between electrons and deprotonated mononucleotides, AMP and UMP, were studied at the electrostatic storage ring ELISA where the two anions were stored with a 1/e lifetime of 13.5 s. It is found that the threshold energy for electron-induced reactions leading to production of neutral fragments is as high as about 12 eV for both species. The high threshold is explained within the context of a classical reaction model, applicable for atomic anions, and a high electron-binding energy of about 5 eV for the two mononucleotides. There is no evidence in the cross sections for formation of short-lived doubly charged anions.
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subjects AMP
ANIONS
ATOMIC AND MOLECULAR PHYSICS
BINDING ENERGY
BIOPHYSICS
CHEMICAL BONDS
CROSS SECTIONS
DISSOCIATION
DNA
ELECTRON-MOLECULE COLLISIONS
ELECTRONS
EV RANGE
LIFETIME
SCATTERING
STORAGE RINGS
THRESHOLD ENERGY
title Electron scattering on stored mononucleotide anions
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