Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies

Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies

The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 2000-02, Vol.112 (5), p.2082-2094
Hauptverfasser: Cho, Minhaeng, Blank, David A., Sung, Jaeyoung, Park, Kisam, Hahn, Sangjoon, Fleming, Graham R.
Format: Artikel
Sprache:eng
Schlagworte:
ATOMIC AND MOLECULAR PHYSICS
COHERENT SCATTERING
NONLINEAR OPTICS
POLARIZATION
RAMAN SPECTROSCOPY
THEORETICAL DATA
VIBRATIONAL STATES
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 2094
container_issue 5
container_start_page 2082
container_title The Journal of chemical physics
container_volume 112
creator Cho, Minhaeng
Blank, David A.
Sung, Jaeyoung
Park, Kisam
Hahn, Sangjoon
Fleming, Graham R.
description The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the case of the seventh-order Raman scattering, there are 34 possible cascading processes contributing to the seventh-order Raman scattering signal, and they are classified as χ(5)×χ(3)- and χ(3)×χ(3)×χ(3)-types depending on the involved low-order nonlinear optical processes. Due to the complicated interference among these polarization fields, it may not be possible to experimentally measure the pure seventh-order Raman scattering signal without contamination from the cascaded contributions.
doi_str_mv 10.1063/1.480777
format Article
fullrecord <record><control><sourceid>crossref_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_20215179</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1063_1_480777</sourcerecordid><originalsourceid>FETCH-LOGICAL-c353t-23372e55e3df8286b3730c09f6bbe884c898103b46014a9a13907a550c58296e3</originalsourceid><addsrcrecordid>eNotkE1LAzEQhoMoWKvgTwh48bJ1stnNx1GK1kJBED0v2ezERrZJSaLQf-_WehpmeHh55yHklsGCgeAPbNEokFKekRkDpSspNJyTGUDNKi1AXJKrnL8AgMm6mZG0DiX5kL2l1mRrBh8-qY3HY_9dfAyZlkjLFqnzrmwrasJAM_5gmJaYBkwUR7QlxeCtGccDjc5VCXMMJhT6ZnYm0Lz_I7KNe4_5mlw4M2a8-Z9z8vH89L58qTavq_XycVNZ3vJS1ZzLGtsW-eBUrUTPJQcL2om-R6Uaq7RiwPtGAGuMNoxrkKZtwbaq1gL5nNydcmMuvsvWF7Tb6bUwlenqyUfLpJ6o-xNlp4I5oev2ye9MOnQMuqPRjnUno_wXGSBo-w</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies</title><source>AIP Journals Complete</source><source>AIP Digital Archive</source><creator>Cho, Minhaeng ; Blank, David A. ; Sung, Jaeyoung ; Park, Kisam ; Hahn, Sangjoon ; Fleming, Graham R.</creator><creatorcontrib>Cho, Minhaeng ; Blank, David A. ; Sung, Jaeyoung ; Park, Kisam ; Hahn, Sangjoon ; Fleming, Graham R.</creatorcontrib><description>The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the case of the seventh-order Raman scattering, there are 34 possible cascading processes contributing to the seventh-order Raman scattering signal, and they are classified as χ(5)×χ(3)- and χ(3)×χ(3)×χ(3)-types depending on the involved low-order nonlinear optical processes. Due to the complicated interference among these polarization fields, it may not be possible to experimentally measure the pure seventh-order Raman scattering signal without contamination from the cascaded contributions.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.480777</identifier><language>eng</language><publisher>United States</publisher><subject>ATOMIC AND MOLECULAR PHYSICS ; COHERENT SCATTERING ; NONLINEAR OPTICS ; POLARIZATION ; RAMAN SPECTROSCOPY ; THEORETICAL DATA ; VIBRATIONAL STATES</subject><ispartof>The Journal of chemical physics, 2000-02, Vol.112 (5), p.2082-2094</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-23372e55e3df8286b3730c09f6bbe884c898103b46014a9a13907a550c58296e3</citedby><cites>FETCH-LOGICAL-c353t-23372e55e3df8286b3730c09f6bbe884c898103b46014a9a13907a550c58296e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/20215179$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Cho, Minhaeng</creatorcontrib><creatorcontrib>Blank, David A.</creatorcontrib><creatorcontrib>Sung, Jaeyoung</creatorcontrib><creatorcontrib>Park, Kisam</creatorcontrib><creatorcontrib>Hahn, Sangjoon</creatorcontrib><creatorcontrib>Fleming, Graham R.</creatorcontrib><title>Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies</title><title>The Journal of chemical physics</title><description>The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the case of the seventh-order Raman scattering, there are 34 possible cascading processes contributing to the seventh-order Raman scattering signal, and they are classified as χ(5)×χ(3)- and χ(3)×χ(3)×χ(3)-types depending on the involved low-order nonlinear optical processes. Due to the complicated interference among these polarization fields, it may not be possible to experimentally measure the pure seventh-order Raman scattering signal without contamination from the cascaded contributions.</description><subject>ATOMIC AND MOLECULAR PHYSICS</subject><subject>COHERENT SCATTERING</subject><subject>NONLINEAR OPTICS</subject><subject>POLARIZATION</subject><subject>RAMAN SPECTROSCOPY</subject><subject>THEORETICAL DATA</subject><subject>VIBRATIONAL STATES</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNotkE1LAzEQhoMoWKvgTwh48bJ1stnNx1GK1kJBED0v2ezERrZJSaLQf-_WehpmeHh55yHklsGCgeAPbNEokFKekRkDpSspNJyTGUDNKi1AXJKrnL8AgMm6mZG0DiX5kL2l1mRrBh8-qY3HY_9dfAyZlkjLFqnzrmwrasJAM_5gmJaYBkwUR7QlxeCtGccDjc5VCXMMJhT6ZnYm0Lz_I7KNe4_5mlw4M2a8-Z9z8vH89L58qTavq_XycVNZ3vJS1ZzLGtsW-eBUrUTPJQcL2om-R6Uaq7RiwPtGAGuMNoxrkKZtwbaq1gL5nNydcmMuvsvWF7Tb6bUwlenqyUfLpJ6o-xNlp4I5oev2ye9MOnQMuqPRjnUno_wXGSBo-w</recordid><startdate>20000201</startdate><enddate>20000201</enddate><creator>Cho, Minhaeng</creator><creator>Blank, David A.</creator><creator>Sung, Jaeyoung</creator><creator>Park, Kisam</creator><creator>Hahn, Sangjoon</creator><creator>Fleming, Graham R.</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>20000201</creationdate><title>Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies</title><author>Cho, Minhaeng ; Blank, David A. ; Sung, Jaeyoung ; Park, Kisam ; Hahn, Sangjoon ; Fleming, Graham R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-23372e55e3df8286b3730c09f6bbe884c898103b46014a9a13907a550c58296e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>ATOMIC AND MOLECULAR PHYSICS</topic><topic>COHERENT SCATTERING</topic><topic>NONLINEAR OPTICS</topic><topic>POLARIZATION</topic><topic>RAMAN SPECTROSCOPY</topic><topic>THEORETICAL DATA</topic><topic>VIBRATIONAL STATES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cho, Minhaeng</creatorcontrib><creatorcontrib>Blank, David A.</creatorcontrib><creatorcontrib>Sung, Jaeyoung</creatorcontrib><creatorcontrib>Park, Kisam</creatorcontrib><creatorcontrib>Hahn, Sangjoon</creatorcontrib><creatorcontrib>Fleming, Graham R.</creatorcontrib><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cho, Minhaeng</au><au>Blank, David A.</au><au>Sung, Jaeyoung</au><au>Park, Kisam</au><au>Hahn, Sangjoon</au><au>Fleming, Graham R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies</atitle><jtitle>The Journal of chemical physics</jtitle><date>2000-02-01</date><risdate>2000</risdate><volume>112</volume><issue>5</issue><spage>2082</spage><epage>2094</epage><pages>2082-2094</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>The cascading polarization contributing to the femtosecond fifth- and seventh-order coherent Raman scattering processes is obtained in terms of the third- and fifth-order Raman response functions. It is found that four cascading processes contribute to the fifth-order Raman scattering signal. In the case of the seventh-order Raman scattering, there are 34 possible cascading processes contributing to the seventh-order Raman scattering signal, and they are classified as χ(5)×χ(3)- and χ(3)×χ(3)×χ(3)-types depending on the involved low-order nonlinear optical processes. Due to the complicated interference among these polarization fields, it may not be possible to experimentally measure the pure seventh-order Raman scattering signal without contamination from the cascaded contributions.</abstract><cop>United States</cop><doi>10.1063/1.480777</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2000-02, Vol.112 (5), p.2082-2094
issn 0021-9606
1089-7690
language eng
recordid cdi_osti_scitechconnect_20215179
source AIP Journals Complete; AIP Digital Archive
subjects ATOMIC AND MOLECULAR PHYSICS
COHERENT SCATTERING
NONLINEAR OPTICS
POLARIZATION
RAMAN SPECTROSCOPY
THEORETICAL DATA
VIBRATIONAL STATES
title Intrinsic cascading contributions to the fifth- and seventh-order electronically off-resonant Raman spectroscopies
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T10%3A12%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Intrinsic%20cascading%20contributions%20to%20the%20fifth-%20and%20seventh-order%20electronically%20off-resonant%20Raman%20spectroscopies&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Cho,%20Minhaeng&rft.date=2000-02-01&rft.volume=112&rft.issue=5&rft.spage=2082&rft.epage=2094&rft.pages=2082-2094&rft.issn=0021-9606&rft.eissn=1089-7690&rft_id=info:doi/10.1063/1.480777&rft_dat=%3Ccrossref_osti_%3E10_1063_1_480777%3C/crossref_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true