Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x)
Benzyl-substituted tin chalcogenides (Bn 3Sn) 2S (1) and (Bn 3Sn) 2Se (2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of (1) and elemental selenium produce solid solutions of the formula Sn(S xSe 1−x). Co...
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| Veröffentlicht in: | Materials research bulletin 1999-11, Vol.34 (14), p.2327-2332 |
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| creator | Boudjouk, Philip Remington, Michael P. Seidler, Dean J. Jarabek, Bryan R. Grier, Dean G. Very, Brian E. Jarabek, Raquel L. McCarthy, Gregory J. |
| description | Benzyl-substituted tin chalcogenides (Bn
3Sn)
2S
(1) and (Bn
3Sn)
2Se
(2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of
(1) and elemental selenium produce solid solutions of the formula Sn(S
xSe
1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates. |
| doi_str_mv | 10.1016/S0025-5408(00)00152-5 |
| format | Article |
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3Sn)
2S
(1) and (Bn
3Sn)
2Se
(2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of
(1) and elemental selenium produce solid solutions of the formula Sn(S
xSe
1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates.</description><identifier>ISSN: 0025-5408</identifier><identifier>EISSN: 1873-4227</identifier><identifier>DOI: 10.1016/S0025-5408(00)00152-5</identifier><identifier>CODEN: MRBUAC</identifier><language>eng</language><publisher>London: Elsevier Ltd</publisher><subject>A. chalcogenides ; A. inorganic compounds ; A. semiconductors ; B. chemical synthesis ; CHALCOGENIDES ; Chemistry ; D. X-ray diffraction ; Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) ; Exact sciences and technology ; Inorganic chemistry and origins of life ; MATERIALS SCIENCE ; Preparations and properties ; PYROLYSIS ; SYNTHESIS ; TEMPERATURE RANGE 0400-1000 K ; TIN SELENIDES ; TIN SULFIDES ; X-RAY DIFFRACTION</subject><ispartof>Materials research bulletin, 1999-11, Vol.34 (14), p.2327-2332</ispartof><rights>1999 Elsevier Science Ltd</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-ca4c715adbbc2e0c2c6592759a161d06a7ce88d425f0a64e3458a13d76d8c4be3</citedby><cites>FETCH-LOGICAL-c364t-ca4c715adbbc2e0c2c6592759a161d06a7ce88d425f0a64e3458a13d76d8c4be3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0025-5408(00)00152-5$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1349293$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/20075666$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Boudjouk, Philip</creatorcontrib><creatorcontrib>Remington, Michael P.</creatorcontrib><creatorcontrib>Seidler, Dean J.</creatorcontrib><creatorcontrib>Jarabek, Bryan R.</creatorcontrib><creatorcontrib>Grier, Dean G.</creatorcontrib><creatorcontrib>Very, Brian E.</creatorcontrib><creatorcontrib>Jarabek, Raquel L.</creatorcontrib><creatorcontrib>McCarthy, Gregory J.</creatorcontrib><creatorcontrib>North Dakota State Univ., Fargo, ND (US)</creatorcontrib><title>Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x)</title><title>Materials research bulletin</title><description>Benzyl-substituted tin chalcogenides (Bn
3Sn)
2S
(1) and (Bn
3Sn)
2Se
(2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of
(1) and elemental selenium produce solid solutions of the formula Sn(S
xSe
1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates.</description><subject>A. chalcogenides</subject><subject>A. inorganic compounds</subject><subject>A. semiconductors</subject><subject>B. chemical synthesis</subject><subject>CHALCOGENIDES</subject><subject>Chemistry</subject><subject>D. X-ray diffraction</subject><subject>Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...)</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>MATERIALS SCIENCE</subject><subject>Preparations and properties</subject><subject>PYROLYSIS</subject><subject>SYNTHESIS</subject><subject>TEMPERATURE RANGE 0400-1000 K</subject><subject>TIN SELENIDES</subject><subject>TIN SULFIDES</subject><subject>X-RAY DIFFRACTION</subject><issn>0025-5408</issn><issn>1873-4227</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNqFkM2KVDEQhYMo2I4-ghDQxczijpXc_NxeiQz-QYOL1nVIV-oykdtJk6S12yeYtY_ok3h7WnTppoqC71SdOow9F3AtQJhXawCpO61guAS4AhBadvoBW4jB9p2S0j5ki7_IY_ak1q8AoAZrFyyu8nfeaLuj4tu-EMfc7Y4lT8caK88jv6WD31D6cZxCbDHV_TTGQNynwCtNlOJ-ez1P3E-NSvKNeMn7ubbM1-lyzQ9rEr_ufh6unrJHo58qPfvTL9iXd28_33zoVp_ef7x5s-qwN6p16BVaoX3YbFASoESjl9LqpRdGBDDeIg1DUFKP4I2iXunBiz5YEwZUG-ov2Ivz3lxbdBVjI7zFnBJhcxLAamPMTOkzhSXXWmh0uxK3vhydAHdK1d2n6k6ROQB3n6rTs-7lWbfzFf00Fp8w1n_iXi3lsp-x12eM5k-_RSonI5SQQiwnHyHH_xz6DQeljTU</recordid><startdate>19991101</startdate><enddate>19991101</enddate><creator>Boudjouk, Philip</creator><creator>Remington, Michael P.</creator><creator>Seidler, Dean J.</creator><creator>Jarabek, Bryan R.</creator><creator>Grier, Dean G.</creator><creator>Very, Brian E.</creator><creator>Jarabek, Raquel L.</creator><creator>McCarthy, Gregory J.</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19991101</creationdate><title>Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x)</title><author>Boudjouk, Philip ; Remington, Michael P. ; Seidler, Dean J. ; Jarabek, Bryan R. ; Grier, Dean G. ; Very, Brian E. ; Jarabek, Raquel L. ; McCarthy, Gregory J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-ca4c715adbbc2e0c2c6592759a161d06a7ce88d425f0a64e3458a13d76d8c4be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>A. chalcogenides</topic><topic>A. inorganic compounds</topic><topic>A. semiconductors</topic><topic>B. chemical synthesis</topic><topic>CHALCOGENIDES</topic><topic>Chemistry</topic><topic>D. X-ray diffraction</topic><topic>Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...)</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>MATERIALS SCIENCE</topic><topic>Preparations and properties</topic><topic>PYROLYSIS</topic><topic>SYNTHESIS</topic><topic>TEMPERATURE RANGE 0400-1000 K</topic><topic>TIN SELENIDES</topic><topic>TIN SULFIDES</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boudjouk, Philip</creatorcontrib><creatorcontrib>Remington, Michael P.</creatorcontrib><creatorcontrib>Seidler, Dean J.</creatorcontrib><creatorcontrib>Jarabek, Bryan R.</creatorcontrib><creatorcontrib>Grier, Dean G.</creatorcontrib><creatorcontrib>Very, Brian E.</creatorcontrib><creatorcontrib>Jarabek, Raquel L.</creatorcontrib><creatorcontrib>McCarthy, Gregory J.</creatorcontrib><creatorcontrib>North Dakota State Univ., Fargo, ND (US)</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Materials research bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boudjouk, Philip</au><au>Remington, Michael P.</au><au>Seidler, Dean J.</au><au>Jarabek, Bryan R.</au><au>Grier, Dean G.</au><au>Very, Brian E.</au><au>Jarabek, Raquel L.</au><au>McCarthy, Gregory J.</au><aucorp>North Dakota State Univ., Fargo, ND (US)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x)</atitle><jtitle>Materials research bulletin</jtitle><date>1999-11-01</date><risdate>1999</risdate><volume>34</volume><issue>14</issue><spage>2327</spage><epage>2332</epage><pages>2327-2332</pages><issn>0025-5408</issn><eissn>1873-4227</eissn><coden>MRBUAC</coden><abstract>Benzyl-substituted tin chalcogenides (Bn
3Sn)
2S
(1) and (Bn
3Sn)
2Se
(2) yield polycrystalline-phase pure SnS and SnSe in good ceramic yields when pyrolyzed with S and Se, respectively, at 275°C. Heating mixtures of
(1) and elemental selenium produce solid solutions of the formula Sn(S
xSe
1−x). Combustion analysis showed less than 1% residual carbon in all ceramic products. This methodology allows the complete conversion of tin to tin chalcogenides and eliminates the need to synthesize organosulfur and organoselenium intermediates.</abstract><cop>London</cop><cop>Amsterdam</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0025-5408(00)00152-5</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0025-5408 |
| ispartof | Materials research bulletin, 1999-11, Vol.34 (14), p.2327-2332 |
| issn | 0025-5408 1873-4227 |
| language | eng |
| recordid | cdi_osti_scitechconnect_20075666 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | A. chalcogenides A. inorganic compounds A. semiconductors B. chemical synthesis CHALCOGENIDES Chemistry D. X-ray diffraction Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) Exact sciences and technology Inorganic chemistry and origins of life MATERIALS SCIENCE Preparations and properties PYROLYSIS SYNTHESIS TEMPERATURE RANGE 0400-1000 K TIN SELENIDES TIN SULFIDES X-RAY DIFFRACTION |
| title | Low temperature co-pyrolysis of hexabenzylditinsulfide and selenium. an alternate route to Sn(S xSe1−x) |
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