Application of the Self-Assembled Monolayer (SAM) Model to Dithiophosphate and Dithiocarbamate Engine Wear Inhibitors
In previous studies of dithiophosphate [DTP = S2P(OR)2] wear inhibitors bound to an oxidized iron surface, we found that the cohesive energy of the self-assembled monolayers (SAM) for DTP molecules with various organic R groups correlates with the wear inhibition observed in full engine experiments....
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Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2000-03, Vol.104 (11), p.2508-2524 |
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