Absolute Rate Expressions for Hydrogen Atom Abstraction from Molybdenum Hydrides by Carbon-Centered Radicals

A new family of basis rate expressions for hydrogen atom abstraction by primary, secondary, and tertiary alkyl radicals in dodecane and benzyl radical in benzene from the molybdenum hydride Cp*Mo(CO)3H and for reactions of a primary alkyl radical with CpMo(CO)3H in dodecane are reported (Cp* = η5-pe...

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Veröffentlicht in:	Journal of the American Chemical Society 1999-10, Vol.121 (42), p.9824-9830
Hauptverfasser:	Franz, James A, Linehan, John C, Birnbaum, Jerome C, Hicks, Kenneth W, Alnajjar, M. S
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY ALKYL RADICALS BENZYL RADICALS HYDROGEN HYDROGEN TRANSFER HYDROGENATION KINETICS MOLYBDENUM HYDRIDES
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