Ultrafast infrared studies of the reaction mechanism of silicon-hydrogen bond activation by {eta}{sup 5}-CpV(CO){sub 4}

The photochemical Si-H bond activation reaction by the group VB, d{sup 4} organometallic compound {eta}{sup 5}-CpV(CO){sub 4} (Cp = C{sub 5}H{sub 5}) has been studied in neat triethylsilane under ambient conditions. The spectral evolutions of the metal-bonded CO stretching bands were monitored from...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1999-12, Vol.103 (49)
Hauptverfasser:	Snee, P.T., Yang, H., Kotz, K.T., Payne, C.K., Harris, C.B.
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY CARBONYLS CHEMICAL REACTION KINETICS ORGANOMETALLIC COMPOUNDS OXIDATION PHOTOCHEMICAL REACTIONS REACTION INTERMEDIATES SILANES VANADIUM
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!