Isotopic Studies of Methane Oxidation Pathways on PdO Catalysts

Mechanistic details of CH4 oxidation were examined on PdO/ZrO2 catalysts using isotopic tracer methods and measurements of kinetic isotope effects. Normal kinetic isotope effects were observed using CH4/O2 and CD4/O2 reactant mixtures. The (kH/kD) ratio was between 2.6 and 2.5, and it decreased slig...

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Veröffentlicht in:	Journal of catalysis 1999-11, Vol.188 (1), p.132-139
Hauptverfasser:	Au-Yeung, Jacky, Chen, Kaidong, Bell, Alexis T., Iglesia, Enrique
Format:	Artikel
Sprache:	eng
Schlagworte:	03 NATURAL GAS ADVANCED PROPULSION SYSTEMS Catalysis CATALYTIC CONVERTERS CATALYTIC EFFECTS Catalytic reactions CHEMICAL REACTION KINETICS Chemistry Exact sciences and technology General and physical chemistry ISOTOPIC EXCHANGE METHANE OXIDATION PALLADIUM OXIDES Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ZIRCONIUM OXIDES
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