Divergent Stabilities of Tetravalent Cerium, Uranium, and Neptunium Imidophosphorane Complexes

The study of the redox chemistry of mid‐actinides (U−Pu) has historically relied on cerium as a model, due to the accessibility of trivalent and tetravalent oxidation states for these ions. Recently, dramatic shifts of lanthanide 4+/3+ non‐aqueous redox couples have been established within a homolep...

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Veröffentlicht in:	Angewandte Chemie 2023-08, Vol.135 (34), p.n/a
Hauptverfasser:	Otte, Kaitlyn S., Niklas, Julie E., Studvick, Chad M., Boggiano, Andrew C., Bacsa, John, Popov, Ivan A., La Pierre, Henry S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Actinides Cerium Chemistry Coordination Chemistry Density Functional Theory Electrochemistry Ligand Design Ligands Molecular orbitals Neptunium Oxidation Redox properties Uranium
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