Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe═NR Bond Cooperativity: A Strategy for pKa-Dictated Regioselective Transposition of C═C Double Bonds

Transition metal catalyzed alkene double bond transposition usually involves metal hydride intermediates. Despite significant advances in the design of catalysts that dictate product selectivity, control over substrate selectivity is less advanced and transition metal catalysts that selectively tran...

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Veröffentlicht in:	Journal of the American Chemical Society 2023-06, Vol.145 (22), p.11978-11987
Hauptverfasser:	Gao, Yafei, Li, Xuelian, Stevens, Jeremiah E, Tang, Hao, Smith, Jeremy M
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Hydrocarbons INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Iron Ligands Reaction mechanisms
Online-Zugang:	Volltext
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